X-ray emission spectroscopy of hydrogen bonding and electronic structure of liquid water

A. Augustsson; J. E. Rubensson; C. Såthe; H. Ågren; H. Siegbahn; J. Nordgren; J. H. Guo; Y. Luo

X-ray emission spectroscopy of hydrogen bonding and electronic structure of liquid water

A. Augustsson
, J. E. Rubensson
, C. Såthe
, H. Ågren
, H. Siegbahn
, J. Nordgren
, J. H. Guo
, Y. Luo

Uppsala University
KTH Royal Institute of Technology

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The influence of the intermolecular interaction on the local electronic structure of liquid water was examined by the x-ray emission spectroscopy. A strong involvement of the a₁-symmetry valence-orbital in the hydrogen bonding was observed, when x-ray emission spectra of the water molecule and liquid water was compared. The determination of the local electronic structure of water molecules, where one hydrogen bond was broken at the hydrogen site was done separately. The important potential of x-ray emission spectroscopy for elucidating basic features of liquids was illustrated.

Original language	English
Article number	137402
Pages (from-to)	1374021-1374024
Number of pages	4
Journal	Physical Review Letters
Volume	89
Issue number	13
State	Published - 23 Sep 2002
Externally published	Yes

Cite this

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title = "X-ray emission spectroscopy of hydrogen bonding and electronic structure of liquid water",

abstract = "The influence of the intermolecular interaction on the local electronic structure of liquid water was examined by the x-ray emission spectroscopy. A strong involvement of the a1-symmetry valence-orbital in the hydrogen bonding was observed, when x-ray emission spectra of the water molecule and liquid water was compared. The determination of the local electronic structure of water molecules, where one hydrogen bond was broken at the hydrogen site was done separately. The important potential of x-ray emission spectroscopy for elucidating basic features of liquids was illustrated.",

author = "A. Augustsson and Rubensson, \{J. E.\} and C. S{\aa}the and H. {\AA}gren and H. Siegbahn and J. Nordgren and Guo, \{J. H.\} and Y. Luo",

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T1 - X-ray emission spectroscopy of hydrogen bonding and electronic structure of liquid water

AU - Augustsson, A.

AU - Rubensson, J. E.

AU - Såthe, C.

AU - Ågren, H.

AU - Siegbahn, H.

AU - Nordgren, J.

AU - Guo, J. H.

AU - Luo, Y.

PY - 2002/9/23

Y1 - 2002/9/23

N2 - The influence of the intermolecular interaction on the local electronic structure of liquid water was examined by the x-ray emission spectroscopy. A strong involvement of the a1-symmetry valence-orbital in the hydrogen bonding was observed, when x-ray emission spectra of the water molecule and liquid water was compared. The determination of the local electronic structure of water molecules, where one hydrogen bond was broken at the hydrogen site was done separately. The important potential of x-ray emission spectroscopy for elucidating basic features of liquids was illustrated.

AB - The influence of the intermolecular interaction on the local electronic structure of liquid water was examined by the x-ray emission spectroscopy. A strong involvement of the a1-symmetry valence-orbital in the hydrogen bonding was observed, when x-ray emission spectra of the water molecule and liquid water was compared. The determination of the local electronic structure of water molecules, where one hydrogen bond was broken at the hydrogen site was done separately. The important potential of x-ray emission spectroscopy for elucidating basic features of liquids was illustrated.

UR - https://www.scopus.com/pages/publications/84988751865

M3 - 文章

AN - SCOPUS:84988751865

SN - 0031-9007

VL - 89

SP - 1374021

EP - 1374024

JO - Physical Review Letters

JF - Physical Review Letters

IS - 13

M1 - 137402

ER -

X-ray emission spectroscopy of hydrogen bonding and electronic structure of liquid water

Abstract

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