X-Ray Emission Spectroscopy of Hydrogen Bonding and Electronic Structure of Liquid Water

J. H. Guo; Y. Luo; A. Augustsson; J. E. Rubensson; C. Såthe; H. Ågren; H. Siegbahn; J. Nordgren

doi:10.1103/PhysRevLett.89.137402

X-Ray Emission Spectroscopy of Hydrogen Bonding and Electronic Structure of Liquid Water

J. H. Guo
, Y. Luo
, A. Augustsson
, J. E. Rubensson
, C. Såthe
, H. Ågren
, H. Siegbahn
, J. Nordgren

Uppsala University
KTH Royal Institute of Technology

Research output: Contribution to journal › Article › peer-review

239 Scopus citations

Abstract

We use x-ray emission spectroscopy to examine the influence of the intermolecular interaction on the local electronic structure of liquid water. By comparing x-ray emission spectra of the water molecule and liquid water, we find a strong involvement of the [Formula presented]-symmetry valence-orbital in the hydrogen bonding. The local electronic structure of water molecules, where one hydrogen bond is broken at the hydrogen site, is separately determined. Our results provide an illustration of the important potential of x-ray emission spectroscopy for elucidating basic features of liquids.

Original language	English
Journal	Physical Review Letters
Volume	89
Issue number	13
DOIs	https://doi.org/10.1103/PhysRevLett.89.137402
State	Published - 2002
Externally published	Yes

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10.1103/PhysRevLett.89.137402

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title = "X-Ray Emission Spectroscopy of Hydrogen Bonding and Electronic Structure of Liquid Water",

abstract = "We use x-ray emission spectroscopy to examine the influence of the intermolecular interaction on the local electronic structure of liquid water. By comparing x-ray emission spectra of the water molecule and liquid water, we find a strong involvement of the [Formula presented]-symmetry valence-orbital in the hydrogen bonding. The local electronic structure of water molecules, where one hydrogen bond is broken at the hydrogen site, is separately determined. Our results provide an illustration of the important potential of x-ray emission spectroscopy for elucidating basic features of liquids.",

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AU - Guo, J. H.

AU - Luo, Y.

AU - Augustsson, A.

AU - Rubensson, J. E.

AU - Såthe, C.

AU - Ågren, H.

AU - Siegbahn, H.

AU - Nordgren, J.

PY - 2002

Y1 - 2002

N2 - We use x-ray emission spectroscopy to examine the influence of the intermolecular interaction on the local electronic structure of liquid water. By comparing x-ray emission spectra of the water molecule and liquid water, we find a strong involvement of the [Formula presented]-symmetry valence-orbital in the hydrogen bonding. The local electronic structure of water molecules, where one hydrogen bond is broken at the hydrogen site, is separately determined. Our results provide an illustration of the important potential of x-ray emission spectroscopy for elucidating basic features of liquids.

AB - We use x-ray emission spectroscopy to examine the influence of the intermolecular interaction on the local electronic structure of liquid water. By comparing x-ray emission spectra of the water molecule and liquid water, we find a strong involvement of the [Formula presented]-symmetry valence-orbital in the hydrogen bonding. The local electronic structure of water molecules, where one hydrogen bond is broken at the hydrogen site, is separately determined. Our results provide an illustration of the important potential of x-ray emission spectroscopy for elucidating basic features of liquids.

UR - https://www.scopus.com/pages/publications/0037163812

U2 - 10.1103/PhysRevLett.89.137402

DO - 10.1103/PhysRevLett.89.137402

M3 - 文章

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SN - 0031-9007

VL - 89

JO - Physical Review Letters

JF - Physical Review Letters

IS - 13

ER -

X-Ray Emission Spectroscopy of Hydrogen Bonding and Electronic Structure of Liquid Water

Abstract

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