[WS3Cu2]簇基超分子框的组装、结构及其三阶非线性光学响应

Huimin Yu; Zhikang Wang; Jie Li; Yinglin Song; Minghao Du; Jianping Lang

doi:10.11862/CJIC.20230228

[WS₃Cu₂]簇基超分子框的组装、结构及其三阶非线性光学响应

Translated title of the contribution: [WS₃Cu₂] cluster⁃based supramolecular frame: Assembly, structure, and third⁃order nonlinear optical response

Huimin Yu
, Zhikang Wang
, Jie Li
, Yinglin Song
, Minghao Du^*
, Jianping Lang^*

^*Corresponding author for this work

Soochow University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Reactions of (Et₄N) (Tp*WS₃) (A) (Tp* =hydridotris(3, 5 ‐ dimethylpyrazol ‐ 1 ‐ yl)borate) and Cu (I) salts [Cu(MeCN)₄]PF₆ with di(pyridin‐4‐yl)sulfane (L₁) or bis(4‐(pyridin‐4‐yl)phenyl)methanone (L₂) gave rise to two W/Cu/ S cluster‐based supramolecular compounds with the formula of [Tp*WS₃Cu₂(L₁)]₂(PF₆)₂·2MeCN·2CHCl₃ (1·2MeCN· 2CHCl₃) and [Tp*WS₃Cu₂(L₂) (MeCN)]₂(PF₆)₂·4MeCN (2·4MeCN), respectively. Both cluster ‐ based supramolecular compounds were structurally characterized by single ‐ crystal X ‐ ray diffraction, ¹H NMR, MS, IR, UV ‐ Vis, and elemental analysis. Single crystal X ‐ ray diffraction demonstrates that both compounds are cationic cluster ‐ based supramolecule frames with similar butterfly ‐ like cores. ¹H NMR and high ‐ resolution electrospray ionization mass spectrometry (HRESI ‐ MS) demonstrated their stability in DMF solution. In addition, the Z ‐ scan measurement reveals the third‐order nonlinear optical responses of 1·2MeCN·2CHCl₃ and 2·4MeCN were enhanced compared to that of their precursor A. CCDC: 2257638, 1·2MeCN·2CHCl₃; 2257639, 2·4MeCN.

Translated title of the contribution	[WS₃Cu₂] cluster⁃based supramolecular frame: Assembly, structure, and third⁃order nonlinear optical response
Original language	Chinese (Traditional)
Pages (from-to)	71-78
Number of pages	8
Journal	Chinese Journal of Inorganic Chemistry
Volume	40
Issue number	1
DOIs	https://doi.org/10.11862/CJIC.20230228
State	Published - 2024
Externally published	Yes

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@article{bc43f89ccc964f70b2602e0aab0cb86e,

title = "[WS3Cu2]簇基超分子框的组装、结构及其三阶非线性光学响应",

abstract = "Reactions of (Et4N) (Tp*WS3) (A) (Tp* =hydridotris(3, 5 ‐ dimethylpyrazol ‐ 1 ‐ yl)borate) and Cu (I) salts [Cu(MeCN)4]PF6 with di(pyridin‐4‐yl)sulfane (L1) or bis(4‐(pyridin‐4‐yl)phenyl)methanone (L2) gave rise to two W/Cu/ S cluster‐based supramolecular compounds with the formula of [Tp*WS3Cu2(L1)]2(PF6)2·2MeCN·2CHCl3 (1·2MeCN· 2CHCl3) and [Tp*WS3Cu2(L2) (MeCN)]2(PF6)2·4MeCN (2·4MeCN), respectively. Both cluster ‐ based supramolecular compounds were structurally characterized by single ‐ crystal X ‐ ray diffraction, 1H NMR, MS, IR, UV ‐ Vis, and elemental analysis. Single crystal X ‐ ray diffraction demonstrates that both compounds are cationic cluster ‐ based supramolecule frames with similar butterfly ‐ like cores. 1H NMR and high ‐ resolution electrospray ionization mass spectrometry (HRESI ‐ MS) demonstrated their stability in DMF solution. In addition, the Z ‐ scan measurement reveals the third‐order nonlinear optical responses of 1·2MeCN·2CHCl3 and 2·4MeCN were enhanced compared to that of their precursor A. CCDC: 2257638, 1·2MeCN·2CHCl3; 2257639, 2·4MeCN.",

keywords = "W/Cu/S clusters, supramolecular frame, third‐order nonlinear optical property",

author = "Huimin Yu and Zhikang Wang and Jie Li and Yinglin Song and Minghao Du and Jianping Lang",

year = "2024",

doi = "10.11862/CJIC.20230228",

language = "繁体中文",

volume = "40",

pages = "71--78",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "1",

}

TY - JOUR

T1 - [WS3Cu2]簇基超分子框的组装、结构及其三阶非线性光学响应

AU - Yu, Huimin

AU - Wang, Zhikang

AU - Li, Jie

AU - Song, Yinglin

AU - Du, Minghao

AU - Lang, Jianping

PY - 2024

Y1 - 2024

N2 - Reactions of (Et4N) (Tp*WS3) (A) (Tp* =hydridotris(3, 5 ‐ dimethylpyrazol ‐ 1 ‐ yl)borate) and Cu (I) salts [Cu(MeCN)4]PF6 with di(pyridin‐4‐yl)sulfane (L1) or bis(4‐(pyridin‐4‐yl)phenyl)methanone (L2) gave rise to two W/Cu/ S cluster‐based supramolecular compounds with the formula of [Tp*WS3Cu2(L1)]2(PF6)2·2MeCN·2CHCl3 (1·2MeCN· 2CHCl3) and [Tp*WS3Cu2(L2) (MeCN)]2(PF6)2·4MeCN (2·4MeCN), respectively. Both cluster ‐ based supramolecular compounds were structurally characterized by single ‐ crystal X ‐ ray diffraction, 1H NMR, MS, IR, UV ‐ Vis, and elemental analysis. Single crystal X ‐ ray diffraction demonstrates that both compounds are cationic cluster ‐ based supramolecule frames with similar butterfly ‐ like cores. 1H NMR and high ‐ resolution electrospray ionization mass spectrometry (HRESI ‐ MS) demonstrated their stability in DMF solution. In addition, the Z ‐ scan measurement reveals the third‐order nonlinear optical responses of 1·2MeCN·2CHCl3 and 2·4MeCN were enhanced compared to that of their precursor A. CCDC: 2257638, 1·2MeCN·2CHCl3; 2257639, 2·4MeCN.

AB - Reactions of (Et4N) (Tp*WS3) (A) (Tp* =hydridotris(3, 5 ‐ dimethylpyrazol ‐ 1 ‐ yl)borate) and Cu (I) salts [Cu(MeCN)4]PF6 with di(pyridin‐4‐yl)sulfane (L1) or bis(4‐(pyridin‐4‐yl)phenyl)methanone (L2) gave rise to two W/Cu/ S cluster‐based supramolecular compounds with the formula of [Tp*WS3Cu2(L1)]2(PF6)2·2MeCN·2CHCl3 (1·2MeCN· 2CHCl3) and [Tp*WS3Cu2(L2) (MeCN)]2(PF6)2·4MeCN (2·4MeCN), respectively. Both cluster ‐ based supramolecular compounds were structurally characterized by single ‐ crystal X ‐ ray diffraction, 1H NMR, MS, IR, UV ‐ Vis, and elemental analysis. Single crystal X ‐ ray diffraction demonstrates that both compounds are cationic cluster ‐ based supramolecule frames with similar butterfly ‐ like cores. 1H NMR and high ‐ resolution electrospray ionization mass spectrometry (HRESI ‐ MS) demonstrated their stability in DMF solution. In addition, the Z ‐ scan measurement reveals the third‐order nonlinear optical responses of 1·2MeCN·2CHCl3 and 2·4MeCN were enhanced compared to that of their precursor A. CCDC: 2257638, 1·2MeCN·2CHCl3; 2257639, 2·4MeCN.

KW - W/Cu/S clusters

KW - supramolecular frame

KW - third‐order nonlinear optical property

UR - https://www.scopus.com/pages/publications/85184868609

U2 - 10.11862/CJIC.20230228

DO - 10.11862/CJIC.20230228

M3 - 文章

AN - SCOPUS:85184868609

SN - 1001-4861

VL - 40

SP - 71

EP - 78

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 1

ER -

[WS₃Cu₂]簇基超分子框的组装、结构及其三阶非线性光学响应

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