Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration

Hong Li Huang; Hang Yan; Chao Yang; Wujiong Xia

doi:10.1039/c4cc10321a

Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration

Hong Li Huang
, Hang Yan
, Chao Yang^*
, Wujiong Xia

^*Corresponding author for this work

School of Sciences

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

A photocatalytic process for selective arylalkylation of allylic alcohols with α-bromo diethyl malonate has been developed. The reaction provided a straightforward approach to synthesize α-aryl-β-alkylated ketones via unique 1,2-aryl migration. The procedure is highlighted by its operational simplicity and mild reaction conditions.

Original language	English
Pages (from-to)	4910-4913
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	23
DOIs	https://doi.org/10.1039/c4cc10321a
State	Published - 21 Mar 2015

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title = "Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration",

abstract = "A photocatalytic process for selective arylalkylation of allylic alcohols with α-bromo diethyl malonate has been developed. The reaction provided a straightforward approach to synthesize α-aryl-β-alkylated ketones via unique 1,2-aryl migration. The procedure is highlighted by its operational simplicity and mild reaction conditions.",

author = "Huang, \{Hong Li\} and Hang Yan and Chao Yang and Wujiong Xia",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = mar,

day = "21",

doi = "10.1039/c4cc10321a",

language = "英语",

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pages = "4910--4913",

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publisher = "Royal Society of Chemistry",

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T1 - Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration

AU - Huang, Hong Li

AU - Yan, Hang

AU - Yang, Chao

AU - Xia, Wujiong

PY - 2015/3/21

Y1 - 2015/3/21

N2 - A photocatalytic process for selective arylalkylation of allylic alcohols with α-bromo diethyl malonate has been developed. The reaction provided a straightforward approach to synthesize α-aryl-β-alkylated ketones via unique 1,2-aryl migration. The procedure is highlighted by its operational simplicity and mild reaction conditions.

AB - A photocatalytic process for selective arylalkylation of allylic alcohols with α-bromo diethyl malonate has been developed. The reaction provided a straightforward approach to synthesize α-aryl-β-alkylated ketones via unique 1,2-aryl migration. The procedure is highlighted by its operational simplicity and mild reaction conditions.

UR - https://www.scopus.com/pages/publications/84924363512

U2 - 10.1039/c4cc10321a

DO - 10.1039/c4cc10321a

M3 - 文章

AN - SCOPUS:84924363512

SN - 1359-7345

VL - 51

SP - 4910

EP - 4913

JO - Chemical Communications

JF - Chemical Communications

IS - 23

ER -

Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration

Abstract

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