Vanadoantimonates: From discrete clusters to high dimensional aggregates

Hai Yang Guo; Xiao Zhang; Xiao Bing Cui; Qi Sheng Huo; Ji Qing Xu

doi:10.1039/c6ce00616g

Vanadoantimonates: From discrete clusters to high dimensional aggregates

Hai Yang Guo
, Xiao Zhang^*
, Xiao Bing Cui
, Qi Sheng Huo
, Ji Qing Xu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Five new vanadoantimonates [Cd(en)₃]₃[Sb₆V₁₅O₄₂(H₂O)]·8H₂O (1), [Ni(en)₃]₂[H₂Sb₆V₁₅O₄₂(H₂O)]·5H₂O (2), [Co(en)₃]₂[H₂Sb₆V₁₅O₄₂(H₂O)]·5H₂O (3), [H₄Sb₈V₁₄O₄₂(H₂O)]·5H₂O (4) and [Co(enMe)₃]₂[Sb₈V₁₄O₄₂(H₂O)]·4H₂O (5) (en = ethylenediamine, enMe = 1,2-propanediamine) have been obtained under hydrothermal conditions and characterized by IR, UV-Vis, XRD, ESR and CD spectroscopy. Compound 1 is a chiral compound constructed from [Sb₆V₁₅O₄₂(H₂O)]^6- (Sb₆V₁₅) and [Cd(en)₃]²⁺. Compounds 2 and 3 are isostructural and isomorphous. Both compounds are chiral, each of which contains a 2-D inorganic layer formed by [H₂Sb₆V₁₅O₄₂(H₂O)]^4-via V-O⋯Sb contacts. Compound 4 contains a 2-D inorganic layer formed by [H₄Sb₈V₁₄O₄₂(H₂O)], of which [H₄Sb₈V₁₄O₄₂(H₂O)] is directed by both V-O⋯Sb and Sb-O⋯Sb interactions. Compound 5 contains a 1-D zigzag chain structure formed by [Sb₈V₁₄O₄₂(H₂O)]^4- (Sb₈V₁₄) via Sb-O⋯Sb contacts.

Original language	English
Pages (from-to)	5130-5139
Number of pages	10
Journal	CrystEngComm
Volume	18
Issue number	27
DOIs	https://doi.org/10.1039/c6ce00616g
State	Published - 2016
Externally published	Yes

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@article{6c18a719ad324fbdb26de10e4350b5e4,

title = "Vanadoantimonates: From discrete clusters to high dimensional aggregates",

abstract = "Five new vanadoantimonates [Cd(en)3]3[Sb6V15O42(H2O)]·8H2O (1), [Ni(en)3]2[H2Sb6V15O42(H2O)]·5H2O (2), [Co(en)3]2[H2Sb6V15O42(H2O)]·5H2O (3), [H4Sb8V14O42(H2O)]·5H2O (4) and [Co(enMe)3]2[Sb8V14O42(H2O)]·4H2O (5) (en = ethylenediamine, enMe = 1,2-propanediamine) have been obtained under hydrothermal conditions and characterized by IR, UV-Vis, XRD, ESR and CD spectroscopy. Compound 1 is a chiral compound constructed from [Sb6V15O42(H2O)]6- (Sb6V15) and [Cd(en)3]2+. Compounds 2 and 3 are isostructural and isomorphous. Both compounds are chiral, each of which contains a 2-D inorganic layer formed by [H2Sb6V15O42(H2O)]4-via V-O⋯Sb contacts. Compound 4 contains a 2-D inorganic layer formed by [H4Sb8V14O42(H2O)], of which [H4Sb8V14O42(H2O)] is directed by both V-O⋯Sb and Sb-O⋯Sb interactions. Compound 5 contains a 1-D zigzag chain structure formed by [Sb8V14O42(H2O)]4- (Sb8V14) via Sb-O⋯Sb contacts.",

author = "Guo, \{Hai Yang\} and Xiao Zhang and Cui, \{Xiao Bing\} and Huo, \{Qi Sheng\} and Xu, \{Ji Qing\}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6ce00616g",

language = "英语",

volume = "18",

pages = "5130--5139",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "27",

}

TY - JOUR

T1 - Vanadoantimonates

T2 - From discrete clusters to high dimensional aggregates

AU - Guo, Hai Yang

AU - Zhang, Xiao

AU - Cui, Xiao Bing

AU - Huo, Qi Sheng

AU - Xu, Ji Qing

PY - 2016

Y1 - 2016

N2 - Five new vanadoantimonates [Cd(en)3]3[Sb6V15O42(H2O)]·8H2O (1), [Ni(en)3]2[H2Sb6V15O42(H2O)]·5H2O (2), [Co(en)3]2[H2Sb6V15O42(H2O)]·5H2O (3), [H4Sb8V14O42(H2O)]·5H2O (4) and [Co(enMe)3]2[Sb8V14O42(H2O)]·4H2O (5) (en = ethylenediamine, enMe = 1,2-propanediamine) have been obtained under hydrothermal conditions and characterized by IR, UV-Vis, XRD, ESR and CD spectroscopy. Compound 1 is a chiral compound constructed from [Sb6V15O42(H2O)]6- (Sb6V15) and [Cd(en)3]2+. Compounds 2 and 3 are isostructural and isomorphous. Both compounds are chiral, each of which contains a 2-D inorganic layer formed by [H2Sb6V15O42(H2O)]4-via V-O⋯Sb contacts. Compound 4 contains a 2-D inorganic layer formed by [H4Sb8V14O42(H2O)], of which [H4Sb8V14O42(H2O)] is directed by both V-O⋯Sb and Sb-O⋯Sb interactions. Compound 5 contains a 1-D zigzag chain structure formed by [Sb8V14O42(H2O)]4- (Sb8V14) via Sb-O⋯Sb contacts.

AB - Five new vanadoantimonates [Cd(en)3]3[Sb6V15O42(H2O)]·8H2O (1), [Ni(en)3]2[H2Sb6V15O42(H2O)]·5H2O (2), [Co(en)3]2[H2Sb6V15O42(H2O)]·5H2O (3), [H4Sb8V14O42(H2O)]·5H2O (4) and [Co(enMe)3]2[Sb8V14O42(H2O)]·4H2O (5) (en = ethylenediamine, enMe = 1,2-propanediamine) have been obtained under hydrothermal conditions and characterized by IR, UV-Vis, XRD, ESR and CD spectroscopy. Compound 1 is a chiral compound constructed from [Sb6V15O42(H2O)]6- (Sb6V15) and [Cd(en)3]2+. Compounds 2 and 3 are isostructural and isomorphous. Both compounds are chiral, each of which contains a 2-D inorganic layer formed by [H2Sb6V15O42(H2O)]4-via V-O⋯Sb contacts. Compound 4 contains a 2-D inorganic layer formed by [H4Sb8V14O42(H2O)], of which [H4Sb8V14O42(H2O)] is directed by both V-O⋯Sb and Sb-O⋯Sb interactions. Compound 5 contains a 1-D zigzag chain structure formed by [Sb8V14O42(H2O)]4- (Sb8V14) via Sb-O⋯Sb contacts.

UR - https://www.scopus.com/pages/publications/84979021766

U2 - 10.1039/c6ce00616g

DO - 10.1039/c6ce00616g

M3 - 文章

AN - SCOPUS:84979021766

SN - 1466-8033

VL - 18

SP - 5130

EP - 5139

JO - CrystEngComm

JF - CrystEngComm

IS - 27

ER -

Vanadoantimonates: From discrete clusters to high dimensional aggregates

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