UV light-mediated difunctionalization of alkenes with CF3SO2Na: Synthesis of trifluoromethyl phenanthrene and anthrone derivatives

Bing Li; Dan Fan; Chao Yang; Wujiong Xia

doi:10.1039/c6ob00912c

UV light-mediated difunctionalization of alkenes with CF₃SO₂Na: Synthesis of trifluoromethyl phenanthrene and anthrone derivatives

Bing Li
, Dan Fan
, Chao Yang
, Wujiong Xia^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

A metal-free and cost-effective protocol for UV light-mediated difunctionalization of alkenes with CF₃SO₂Na was developed. This strategy realized the direct formation of Csp³-CF₃ and C-C bonds through a proposed tandem radical cyclization process, which produced a variety of phenanthrene and anthrone derivatives in moderate yields.

Original language	English
Pages (from-to)	5293-5297
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	14
Issue number	23
DOIs	https://doi.org/10.1039/c6ob00912c
State	Published - 2016
Externally published	Yes

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title = "UV light-mediated difunctionalization of alkenes with CF3SO2Na: Synthesis of trifluoromethyl phenanthrene and anthrone derivatives",

abstract = "A metal-free and cost-effective protocol for UV light-mediated difunctionalization of alkenes with CF3SO2Na was developed. This strategy realized the direct formation of Csp3-CF3 and C-C bonds through a proposed tandem radical cyclization process, which produced a variety of phenanthrene and anthrone derivatives in moderate yields.",

author = "Bing Li and Dan Fan and Chao Yang and Wujiong Xia",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6ob00912c",

language = "英语",

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publisher = "Royal Society of Chemistry",

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T1 - UV light-mediated difunctionalization of alkenes with CF3SO2Na

T2 - Synthesis of trifluoromethyl phenanthrene and anthrone derivatives

AU - Li, Bing

AU - Fan, Dan

AU - Yang, Chao

AU - Xia, Wujiong

PY - 2016

Y1 - 2016

N2 - A metal-free and cost-effective protocol for UV light-mediated difunctionalization of alkenes with CF3SO2Na was developed. This strategy realized the direct formation of Csp3-CF3 and C-C bonds through a proposed tandem radical cyclization process, which produced a variety of phenanthrene and anthrone derivatives in moderate yields.

AB - A metal-free and cost-effective protocol for UV light-mediated difunctionalization of alkenes with CF3SO2Na was developed. This strategy realized the direct formation of Csp3-CF3 and C-C bonds through a proposed tandem radical cyclization process, which produced a variety of phenanthrene and anthrone derivatives in moderate yields.

UR - https://www.scopus.com/pages/publications/84974566749

U2 - 10.1039/c6ob00912c

DO - 10.1039/c6ob00912c

M3 - 文章

AN - SCOPUS:84974566749

SN - 1477-0520

VL - 14

SP - 5293

EP - 5297

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 23

ER -

UV light-mediated difunctionalization of alkenes with CF₃SO₂Na: Synthesis of trifluoromethyl phenanthrene and anthrone derivatives

Abstract

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