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Use of colloidal upconversion nanocrystals for energy relay solar cell light harvesting in the near-infrared region

  • Chunze Yuan
  • , Guanying Chen*
  • , Paras N. Prasad
  • , Tymish Y. Ohulchanskyy
  • , Zhijun Ning
  • , Haining Tian
  • , Licheng Sun
  • , Hans Ågren
  • *Corresponding author for this work
  • KTH Royal Institute of Technology
  • School of Chemistry and Chemical Engineering, Harbin Institute of Technology
  • SUNY Buffalo

Research output: Contribution to journalArticlepeer-review

Abstract

Colloidal upconversion (UC) nanocrystals were explored as energy relay materials for dye-sensitized solar cells for the first time. The utilization of colloidal UC nanocrystals was found to significantly enhance the upconversion efficiency and improve the photocurrent of the cells for low infrared irradiation intensity. In addition, it was found that UC nanocrystals of small size favor infiltration into a TiO 2 film and bring higher relay efficiency. Finally, we found that UC nanocrystals can serve as a scattering material to increase the light absorption capability of the cells and increase the overall photocurrent of the cells under simulated sunlight irradiation.

Original languageEnglish
Pages (from-to)16709-16713
Number of pages5
JournalJournal of Materials Chemistry
Volume22
Issue number33
DOIs
StatePublished - 7 Sep 2012
Externally publishedYes

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