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Unchanged thermopower enhancement at the semiconductor-metal transition in correlated FeSb2-x Tex

  • P. Sun*
  • , M. Søndergaard
  • , Y. Sun
  • , S. Johnsen
  • , B. B. Iversen
  • , F. Steglich
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Substitution of Sb in FeSb2 by less than 0.5% of Te induces a transition from a correlated semiconductor to an unconventional metal with large effective charge carrier mass m*. Spanning the entire range of the semiconductor-metal crossover, we observed an almost constant enhancement of the measured thermopower compared to that estimated by the classical theory of electron diffusion. Using the latter for a quantitative description one has to employ an enhancement factor of 10-30. Our observations point to the importance of electron-electron correlations in the thermal transport of FeSb2, and suggest a route to design thermoelectric materials for cryogenic applications.

Original languageEnglish
Article number072105
JournalApplied Physics Letters
Volume98
Issue number7
DOIs
StatePublished - 14 Feb 2011
Externally publishedYes

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