Two zinc(II) coordination complexes based on an asymmetric multidentate ligand: Syntheses, structures, selective fluorescence sensing of iron(III) ions and thermal analyses

Yaru Liu; Lan Liu; Xiao Zhang; Guorui Liang; Xuebing Gong

doi:10.1107/S205322961701717X

Two zinc(II) coordination complexes based on an asymmetric multidentate ligand: Syntheses, structures, selective fluorescence sensing of iron(III) ions and thermal analyses

Yaru Liu^*
, Lan Liu
, Xiao Zhang
, Guorui Liang
, Xuebing Gong

^*Corresponding author for this work

North University of China
School of Chemistry and Chemical Engineering, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The rational selection of ligands is vitally important in the construction of coordination complexes. Two novel ZnII complexes, namely bis(acetato-κO)-bis[1-(1H-benzotriazol-1-ylmethyl)-2-propyl-1H-imidazole-κN³]zinc(II) monohydrate, [Zn(C₁₃H₁₅N₅)₂(C₂H₃O₂)₂]κH₂O, (1), and bis(azido-κN1)bis[1-(1H-benzotriazol-1-ylmethyl)-2-propyl-1H-imidazole-κN₃]zinc(II), [Zn(C₁₃H₁₅N₅)₂(N₃)₂], (2), constructed from the asymmetric multidentate imidazole ligand, have been synthesized under mild conditions and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction analysis. Both complexes exhibit a three-dimensional supramolecular network directed by different intermolecular interactions between discrete mononuclear units. The complexes were also investigated by fluorescence and thermal analyses. The experimental results show that (1) is a promising fluorescence sensor for detecting Fe3+ ions and (2) is effective as an accelerator of the thermal decomposition of ammonium perchlorate.

Original language	English
Pages (from-to)	13-20
Number of pages	8
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	74
Issue number	1
DOIs	https://doi.org/10.1107/S205322961701717X
State	Published - Jan 2018
Externally published	Yes

Keywords

1-(benzotriazol-1-ylmethyl)-2-propylimidazole
Coordination complexes
crystal structure
fluorescence sensor
intermolecular interactions
thermal analysis

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10.1107/S205322961701717X

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@article{1429b6302fb945089d89eb9268946617,

title = "Two zinc(II) coordination complexes based on an asymmetric multidentate ligand: Syntheses, structures, selective fluorescence sensing of iron(III) ions and thermal analyses",

abstract = "The rational selection of ligands is vitally important in the construction of coordination complexes. Two novel ZnII complexes, namely bis(acetato-κO)-bis[1-(1H-benzotriazol-1-ylmethyl)-2-propyl-1H-imidazole-κN3]zinc(II) monohydrate, [Zn(C13H15N5)2(C2H3O2)2]κH2O, (1), and bis(azido-κN1)bis[1-(1H-benzotriazol-1-ylmethyl)-2-propyl-1H-imidazole-κN3]zinc(II), [Zn(C13H15N5)2(N3)2], (2), constructed from the asymmetric multidentate imidazole ligand, have been synthesized under mild conditions and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction analysis. Both complexes exhibit a three-dimensional supramolecular network directed by different intermolecular interactions between discrete mononuclear units. The complexes were also investigated by fluorescence and thermal analyses. The experimental results show that (1) is a promising fluorescence sensor for detecting Fe3+ ions and (2) is effective as an accelerator of the thermal decomposition of ammonium perchlorate.",

keywords = "1-(benzotriazol-1-ylmethyl)-2-propylimidazole, Coordination complexes, crystal structure, fluorescence sensor, intermolecular interactions, thermal analysis",

author = "Yaru Liu and Lan Liu and Xiao Zhang and Guorui Liang and Xuebing Gong",

note = "Publisher Copyright: {\textcopyright} 2018 International Union of Crystallography.",

year = "2018",

month = jan,

doi = "10.1107/S205322961701717X",

language = "英语",

volume = "74",

pages = "13--20",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "1",

}

Two zinc(II) coordination complexes based on an asymmetric multidentate ligand: Syntheses, structures, selective fluorescence sensing of iron(III) ions and thermal analyses. / Liu, Yaru; Liu, Lan; Zhang, Xiao et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 74, No. 1, 01.2018, p. 13-20.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Two zinc(II) coordination complexes based on an asymmetric multidentate ligand

T2 - Syntheses, structures, selective fluorescence sensing of iron(III) ions and thermal analyses

AU - Liu, Yaru

AU - Liu, Lan

AU - Zhang, Xiao

AU - Liang, Guorui

AU - Gong, Xuebing

PY - 2018/1

Y1 - 2018/1

N2 - The rational selection of ligands is vitally important in the construction of coordination complexes. Two novel ZnII complexes, namely bis(acetato-κO)-bis[1-(1H-benzotriazol-1-ylmethyl)-2-propyl-1H-imidazole-κN3]zinc(II) monohydrate, [Zn(C13H15N5)2(C2H3O2)2]κH2O, (1), and bis(azido-κN1)bis[1-(1H-benzotriazol-1-ylmethyl)-2-propyl-1H-imidazole-κN3]zinc(II), [Zn(C13H15N5)2(N3)2], (2), constructed from the asymmetric multidentate imidazole ligand, have been synthesized under mild conditions and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction analysis. Both complexes exhibit a three-dimensional supramolecular network directed by different intermolecular interactions between discrete mononuclear units. The complexes were also investigated by fluorescence and thermal analyses. The experimental results show that (1) is a promising fluorescence sensor for detecting Fe3+ ions and (2) is effective as an accelerator of the thermal decomposition of ammonium perchlorate.

AB - The rational selection of ligands is vitally important in the construction of coordination complexes. Two novel ZnII complexes, namely bis(acetato-κO)-bis[1-(1H-benzotriazol-1-ylmethyl)-2-propyl-1H-imidazole-κN3]zinc(II) monohydrate, [Zn(C13H15N5)2(C2H3O2)2]κH2O, (1), and bis(azido-κN1)bis[1-(1H-benzotriazol-1-ylmethyl)-2-propyl-1H-imidazole-κN3]zinc(II), [Zn(C13H15N5)2(N3)2], (2), constructed from the asymmetric multidentate imidazole ligand, have been synthesized under mild conditions and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction analysis. Both complexes exhibit a three-dimensional supramolecular network directed by different intermolecular interactions between discrete mononuclear units. The complexes were also investigated by fluorescence and thermal analyses. The experimental results show that (1) is a promising fluorescence sensor for detecting Fe3+ ions and (2) is effective as an accelerator of the thermal decomposition of ammonium perchlorate.

KW - 1-(benzotriazol-1-ylmethyl)-2-propylimidazole

KW - Coordination complexes

KW - crystal structure

KW - fluorescence sensor

KW - intermolecular interactions

KW - thermal analysis

UR - https://www.scopus.com/pages/publications/85040174481

U2 - 10.1107/S205322961701717X

DO - 10.1107/S205322961701717X

M3 - 文章

C2 - 29303492

AN - SCOPUS:85040174481

SN - 0108-2701

VL - 74

SP - 13

EP - 20

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 1

ER -

Two zinc(II) coordination complexes based on an asymmetric multidentate ligand: Syntheses, structures, selective fluorescence sensing of iron(III) ions and thermal analyses

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