Two new hybrid molybdenum arsenate derivative constructed from [As2Mo6O26]6- building: Synthesis, structural characterization and photocatalysis property

Xiao Zhang; Xuan Luo; Yuanling Duan; Yanping Huang; Nanxi Zhang; Liyan Zhao; Jie Wu

doi:10.1016/j.molstruc.2017.03.110

Two new hybrid molybdenum arsenate derivative constructed from [As₂Mo₆O₂₆]^6- building: Synthesis, structural characterization and photocatalysis property

Xiao Zhang^*
, Xuan Luo
, Yuanling Duan
, Yanping Huang
, Nanxi Zhang
, Liyan Zhao
, Jie Wu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Heilongjiang University
School of Life Science and Technology, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Two new inorganic-organic hybrid materials [Cu(enMe)₂]₂{(As₂Mo₆O₂₆) [Cu(enMe)₂]}·4H₂O (1) and [As₂Mo₆(OH)₂O₂₄][Cu(H₂O)₂(phen)]₂ (2) (enMe = 1,2’-propanediamine, phen = 1,10’-phenanthroline) based on [As₂Mo₆O₂₆]^6- building blocks, denoted as [As₂Mo₆], have been obtained by hydrothermal methods. 1 shows a 1-D straight chain structure constructed form [As₂Mo₆] building blocks and [Cu(enMe)₂] complexes, and then extended to 3-D supramolecular network by lattice water via hydrogen bonds interactions. 2 exhibits a new 1-D covalent ribbon with large rectangular grids formed from [As₂Mo₆] building blocks connected by [Cu(H₂O)₂(phen)] complexes, then extended into 3-D supramolecular network via hydrogen bonds and π···π interactions. In additional, the photocatalytic activity for methylene blue degradation under visible-light irradiation of 2 was investigated.

Original language	English
Pages (from-to)	245-251
Number of pages	7
Journal	Journal of Molecular Structure
Volume	1141
DOIs	https://doi.org/10.1016/j.molstruc.2017.03.110
State	Published - 5 Aug 2017
Externally published	Yes

Keywords

Crystal structure
Fluorescence
Hydrogen-bonded
Photocatalytic activity
Supramolecular network

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10.1016/j.molstruc.2017.03.110

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@article{d6357810d34e479fb3f3edfac0ce7350,

title = "Two new hybrid molybdenum arsenate derivative constructed from [As2Mo6O26]6- building: Synthesis, structural characterization and photocatalysis property",

abstract = "Two new inorganic-organic hybrid materials [Cu(enMe)2]2\{(As2Mo6O26) [Cu(enMe)2]\}·4H2O (1) and [As2Mo6(OH)2O24][Cu(H2O)2(phen)]2 (2) (enMe = 1,2{\textquoteright}-propanediamine, phen = 1,10{\textquoteright}-phenanthroline) based on [As2Mo6O26]6- building blocks, denoted as [As2Mo6], have been obtained by hydrothermal methods. 1 shows a 1-D straight chain structure constructed form [As2Mo6] building blocks and [Cu(enMe)2] complexes, and then extended to 3-D supramolecular network by lattice water via hydrogen bonds interactions. 2 exhibits a new 1-D covalent ribbon with large rectangular grids formed from [As2Mo6] building blocks connected by [Cu(H2O)2(phen)] complexes, then extended into 3-D supramolecular network via hydrogen bonds and π···π interactions. In additional, the photocatalytic activity for methylene blue degradation under visible-light irradiation of 2 was investigated.",

keywords = "Crystal structure, Fluorescence, Hydrogen-bonded, Photocatalytic activity, Supramolecular network",

author = "Xiao Zhang and Xuan Luo and Yuanling Duan and Yanping Huang and Nanxi Zhang and Liyan Zhao and Jie Wu",

note = "Publisher Copyright: {\textcopyright} 2017",

year = "2017",

month = aug,

day = "5",

doi = "10.1016/j.molstruc.2017.03.110",

language = "英语",

volume = "1141",

pages = "245--251",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Two new hybrid molybdenum arsenate derivative constructed from [As2Mo6O26]6- building

T2 - Synthesis, structural characterization and photocatalysis property

AU - Zhang, Xiao

AU - Luo, Xuan

AU - Duan, Yuanling

AU - Huang, Yanping

AU - Zhang, Nanxi

AU - Zhao, Liyan

AU - Wu, Jie

PY - 2017/8/5

Y1 - 2017/8/5

N2 - Two new inorganic-organic hybrid materials [Cu(enMe)2]2{(As2Mo6O26) [Cu(enMe)2]}·4H2O (1) and [As2Mo6(OH)2O24][Cu(H2O)2(phen)]2 (2) (enMe = 1,2’-propanediamine, phen = 1,10’-phenanthroline) based on [As2Mo6O26]6- building blocks, denoted as [As2Mo6], have been obtained by hydrothermal methods. 1 shows a 1-D straight chain structure constructed form [As2Mo6] building blocks and [Cu(enMe)2] complexes, and then extended to 3-D supramolecular network by lattice water via hydrogen bonds interactions. 2 exhibits a new 1-D covalent ribbon with large rectangular grids formed from [As2Mo6] building blocks connected by [Cu(H2O)2(phen)] complexes, then extended into 3-D supramolecular network via hydrogen bonds and π···π interactions. In additional, the photocatalytic activity for methylene blue degradation under visible-light irradiation of 2 was investigated.

AB - Two new inorganic-organic hybrid materials [Cu(enMe)2]2{(As2Mo6O26) [Cu(enMe)2]}·4H2O (1) and [As2Mo6(OH)2O24][Cu(H2O)2(phen)]2 (2) (enMe = 1,2’-propanediamine, phen = 1,10’-phenanthroline) based on [As2Mo6O26]6- building blocks, denoted as [As2Mo6], have been obtained by hydrothermal methods. 1 shows a 1-D straight chain structure constructed form [As2Mo6] building blocks and [Cu(enMe)2] complexes, and then extended to 3-D supramolecular network by lattice water via hydrogen bonds interactions. 2 exhibits a new 1-D covalent ribbon with large rectangular grids formed from [As2Mo6] building blocks connected by [Cu(H2O)2(phen)] complexes, then extended into 3-D supramolecular network via hydrogen bonds and π···π interactions. In additional, the photocatalytic activity for methylene blue degradation under visible-light irradiation of 2 was investigated.

KW - Crystal structure

KW - Fluorescence

KW - Hydrogen-bonded

KW - Photocatalytic activity

KW - Supramolecular network

UR - https://www.scopus.com/pages/publications/85016798977

U2 - 10.1016/j.molstruc.2017.03.110

DO - 10.1016/j.molstruc.2017.03.110

M3 - 文章

AN - SCOPUS:85016798977

SN - 0022-2860

VL - 1141

SP - 245

EP - 251

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

Two new hybrid molybdenum arsenate derivative constructed from [As₂Mo₆O₂₆]^6- building: Synthesis, structural characterization and photocatalysis property

Abstract

Keywords

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