Two cobalt(II) one-dimensional ribbon of rings polymers: Syntheses, structures and non-linear optical properties

Linke Li; Haiyan Yang; Yinglin Song; Hongwei Hou; Yaoting Fan

doi:10.1016/j.ica.2006.01.031

Two cobalt(II) one-dimensional ribbon of rings polymers: Syntheses, structures and non-linear optical properties

Linke Li
, Haiyan Yang
, Yinglin Song
, Hongwei Hou^*
, Yaoting Fan

^*Corresponding author for this work

School of Physics

Zhengzhou University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Two cobalt(II) coordination polymers {[Co(SCN)₂(3-bpit)₂] · 2CH₃OH}_n (1) (3-bpit = N,N′-bis(3-pyridylformyl)imidazolidine-2-thione) and {[Co(SCN)₂(4-bpit)₂] · CH₃OH · CH₃CN}_n (2) (4-bpit = N,N′-bis(4-pyridylformyl)imidazolidine-2-thione) have been synthesized for study of the third-order non-linear properties. X-ray crystal structural analyses reveal that the two polymers show the same topological motif: a ribbon of rings. Their third-order non-linear optical (NLO) properties in DMF solution have been studied by Z-scan techniques with a linearly polarized laser light (λ = 532 nm; pulse widths = 7 ns). Both of them exhibit strong self-focusing effect. The third-order NLO susceptibility χ⁽³⁾ values are calculated to be 2.61 × 10^-11 esu (1) and 2.76 × 10^-11 esu (2), respectively. The values are comparable to those of the reported good NLO materials.

Original language	English
Pages (from-to)	2135-2140
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	359
Issue number	7
DOIs	https://doi.org/10.1016/j.ica.2006.01.031
State	Published - 25 Apr 2006

Keywords

Cobalt(II)
Coordination polymers
Non-linear optical properties
Ribbon of rings structure

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10.1016/j.ica.2006.01.031

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title = "Two cobalt(II) one-dimensional ribbon of rings polymers: Syntheses, structures and non-linear optical properties",

abstract = "Two cobalt(II) coordination polymers \{[Co(SCN)2(3-bpit)2] · 2CH3OH\}n (1) (3-bpit = N,N′-bis(3-pyridylformyl)imidazolidine-2-thione) and \{[Co(SCN)2(4-bpit)2] · CH3OH · CH3CN\}n (2) (4-bpit = N,N′-bis(4-pyridylformyl)imidazolidine-2-thione) have been synthesized for study of the third-order non-linear properties. X-ray crystal structural analyses reveal that the two polymers show the same topological motif: a ribbon of rings. Their third-order non-linear optical (NLO) properties in DMF solution have been studied by Z-scan techniques with a linearly polarized laser light (λ = 532 nm; pulse widths = 7 ns). Both of them exhibit strong self-focusing effect. The third-order NLO susceptibility χ(3) values are calculated to be 2.61 × 10-11 esu (1) and 2.76 × 10-11 esu (2), respectively. The values are comparable to those of the reported good NLO materials.",

keywords = "Cobalt(II), Coordination polymers, Non-linear optical properties, Ribbon of rings structure",

author = "Linke Li and Haiyan Yang and Yinglin Song and Hongwei Hou and Yaoting Fan",

year = "2006",

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doi = "10.1016/j.ica.2006.01.031",

language = "英语",

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pages = "2135--2140",

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TY - JOUR

T1 - Two cobalt(II) one-dimensional ribbon of rings polymers

T2 - Syntheses, structures and non-linear optical properties

AU - Li, Linke

AU - Yang, Haiyan

AU - Song, Yinglin

AU - Hou, Hongwei

AU - Fan, Yaoting

PY - 2006/4/25

Y1 - 2006/4/25

N2 - Two cobalt(II) coordination polymers {[Co(SCN)2(3-bpit)2] · 2CH3OH}n (1) (3-bpit = N,N′-bis(3-pyridylformyl)imidazolidine-2-thione) and {[Co(SCN)2(4-bpit)2] · CH3OH · CH3CN}n (2) (4-bpit = N,N′-bis(4-pyridylformyl)imidazolidine-2-thione) have been synthesized for study of the third-order non-linear properties. X-ray crystal structural analyses reveal that the two polymers show the same topological motif: a ribbon of rings. Their third-order non-linear optical (NLO) properties in DMF solution have been studied by Z-scan techniques with a linearly polarized laser light (λ = 532 nm; pulse widths = 7 ns). Both of them exhibit strong self-focusing effect. The third-order NLO susceptibility χ(3) values are calculated to be 2.61 × 10-11 esu (1) and 2.76 × 10-11 esu (2), respectively. The values are comparable to those of the reported good NLO materials.

AB - Two cobalt(II) coordination polymers {[Co(SCN)2(3-bpit)2] · 2CH3OH}n (1) (3-bpit = N,N′-bis(3-pyridylformyl)imidazolidine-2-thione) and {[Co(SCN)2(4-bpit)2] · CH3OH · CH3CN}n (2) (4-bpit = N,N′-bis(4-pyridylformyl)imidazolidine-2-thione) have been synthesized for study of the third-order non-linear properties. X-ray crystal structural analyses reveal that the two polymers show the same topological motif: a ribbon of rings. Their third-order non-linear optical (NLO) properties in DMF solution have been studied by Z-scan techniques with a linearly polarized laser light (λ = 532 nm; pulse widths = 7 ns). Both of them exhibit strong self-focusing effect. The third-order NLO susceptibility χ(3) values are calculated to be 2.61 × 10-11 esu (1) and 2.76 × 10-11 esu (2), respectively. The values are comparable to those of the reported good NLO materials.

KW - Cobalt(II)

KW - Coordination polymers

KW - Non-linear optical properties

KW - Ribbon of rings structure

UR - https://www.scopus.com/pages/publications/33645855619

U2 - 10.1016/j.ica.2006.01.031

DO - 10.1016/j.ica.2006.01.031

M3 - 文章

AN - SCOPUS:33645855619

SN - 0020-1693

VL - 359

SP - 2135

EP - 2140

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 7

ER -

Two cobalt(II) one-dimensional ribbon of rings polymers: Syntheses, structures and non-linear optical properties

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