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Two catalytic protocols for Achmatowicz rearrangement using cyclic diacyl peroxides as oxidants

  • Congyin Wei
  • , Rong Zhao
  • , Zhihong Shen
  • , Denghu Chang
  • , Lei Shi*
  • *Corresponding author for this work
  • School of Chemistry and Chemical Engineering, Harbin Institute of Technology
  • Harbin Institute of Technology Shenzhen

Research output: Contribution to journalArticlepeer-review

Abstract

In situ generated bromonium-catalyzed and visible-light photocatalytic Achmatowicz rearrangements of furfuryl alcohols using cyclic diacyl peroxides as oxidants are described. Both protocols feature broad substrate scope, excellent functional group tolerance, and mild reaction conditions, affording the synthetically useful dihydropyranone derivatives in good yields.

Original languageEnglish
Pages (from-to)5566-5569
Number of pages4
JournalOrganic and Biomolecular Chemistry
Volume16
Issue number31
DOIs
StatePublished - 2018
Externally publishedYes

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