Third- and fifth-order nonlinearities of heterobimetallic cluster [WOS3Cu3(4-pic)6]·ClO4

Yuming Chen; Jinfang Zhang; Yuxiao Wang; Xueru Zhang; Kun Yang; Chi Zhang; Yinglin Song

doi:10.1016/j.matchemphys.2009.05.012

Third- and fifth-order nonlinearities of heterobimetallic cluster [WOS₃Cu₃(4-pic)₆]·ClO₄

Yuming Chen
, Jinfang Zhang
, Yuxiao Wang
, Xueru Zhang
, Kun Yang
, Chi Zhang
, Yinglin Song^*

^*Corresponding author for this work

School of Physics

Harbin Institute of Technology
Scientific Research Academy

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

An interesting nest-shaped heterobimetallic cluster [WOS₃Cu₃(4-pic)₆]·ClO₄ was synthesized and its structure determined by X-ray diffraction method. The nonlinear optical properties were investigated by Z-scan technique with 4 ns laser pulse at 532 nm wavelength. It reveals that the nonlinear absorption can be attributed to effective three-photon absorption and the nonlinear refraction is derived from the combination of the third-order and effective fifth-order nonlinearity. The sign and magnitude of third- and effective fifth-order nonlinearity were also evaluated.

Original language	English
Pages (from-to)	66-69
Number of pages	4
Journal	Materials Chemistry and Physics
Volume	117
Issue number	1
DOIs	https://doi.org/10.1016/j.matchemphys.2009.05.012
State	Published - 15 Sep 2009

Keywords

Heterobimetallic cluster
Nonlinear optics
Three-photon absorption
Z-scan

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10.1016/j.matchemphys.2009.05.012

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title = "Third- and fifth-order nonlinearities of heterobimetallic cluster [WOS3Cu3(4-pic)6]·ClO4",

abstract = "An interesting nest-shaped heterobimetallic cluster [WOS3Cu3(4-pic)6]·ClO4 was synthesized and its structure determined by X-ray diffraction method. The nonlinear optical properties were investigated by Z-scan technique with 4 ns laser pulse at 532 nm wavelength. It reveals that the nonlinear absorption can be attributed to effective three-photon absorption and the nonlinear refraction is derived from the combination of the third-order and effective fifth-order nonlinearity. The sign and magnitude of third- and effective fifth-order nonlinearity were also evaluated.",

keywords = "Heterobimetallic cluster, Nonlinear optics, Three-photon absorption, Z-scan",

author = "Yuming Chen and Jinfang Zhang and Yuxiao Wang and Xueru Zhang and Kun Yang and Chi Zhang and Yinglin Song",

year = "2009",

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day = "15",

doi = "10.1016/j.matchemphys.2009.05.012",

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T1 - Third- and fifth-order nonlinearities of heterobimetallic cluster [WOS3Cu3(4-pic)6]·ClO4

AU - Chen, Yuming

AU - Zhang, Jinfang

AU - Wang, Yuxiao

AU - Zhang, Xueru

AU - Yang, Kun

AU - Zhang, Chi

AU - Song, Yinglin

PY - 2009/9/15

Y1 - 2009/9/15

N2 - An interesting nest-shaped heterobimetallic cluster [WOS3Cu3(4-pic)6]·ClO4 was synthesized and its structure determined by X-ray diffraction method. The nonlinear optical properties were investigated by Z-scan technique with 4 ns laser pulse at 532 nm wavelength. It reveals that the nonlinear absorption can be attributed to effective three-photon absorption and the nonlinear refraction is derived from the combination of the third-order and effective fifth-order nonlinearity. The sign and magnitude of third- and effective fifth-order nonlinearity were also evaluated.

AB - An interesting nest-shaped heterobimetallic cluster [WOS3Cu3(4-pic)6]·ClO4 was synthesized and its structure determined by X-ray diffraction method. The nonlinear optical properties were investigated by Z-scan technique with 4 ns laser pulse at 532 nm wavelength. It reveals that the nonlinear absorption can be attributed to effective three-photon absorption and the nonlinear refraction is derived from the combination of the third-order and effective fifth-order nonlinearity. The sign and magnitude of third- and effective fifth-order nonlinearity were also evaluated.

KW - Heterobimetallic cluster

KW - Nonlinear optics

KW - Three-photon absorption

KW - Z-scan

UR - https://www.scopus.com/pages/publications/67650088348

U2 - 10.1016/j.matchemphys.2009.05.012

DO - 10.1016/j.matchemphys.2009.05.012

M3 - 文章

AN - SCOPUS:67650088348

SN - 0254-0584

VL - 117

SP - 66

EP - 69

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

IS - 1

ER -

Third- and fifth-order nonlinearities of heterobimetallic cluster [WOS₃Cu₃(4-pic)₆]·ClO₄

Abstract

Keywords

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