Thermodynamics and kinetics of lithiation-induced phase transitions in nanoporous antimony

Shichen Wang; Zeyu Jin; Chaojie Yang; Jie Lu; Yao Gao; Hua Jun Qiu; Kaikai Li

doi:10.1039/d5cc00094g

Thermodynamics and kinetics of lithiation-induced phase transitions in nanoporous antimony

Shichen Wang
, Zeyu Jin
, Chaojie Yang
, Jie Lu
, Yao Gao
, Hua Jun Qiu^*
, Kaikai Li^*

^*Corresponding author for this work

Harbin Institute of Technology
Chinese University of Hong Kong
Harbin Institute of Technology Shenzhen

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The impact of nanosizing on the phase transition mechanisms of electrode materials is still not well understood. In this study, we reveal that nanosizing can lower the energy barrier and entropy changes associated with phase transformations, ultimately improving the electrochemical performance of nanoporous antimony electrodes in comparison to microsized antimony.

Original language	English
Pages (from-to)	5118-5121
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	27
DOIs	https://doi.org/10.1039/d5cc00094g
State	Published - 4 Mar 2025
Externally published	Yes

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title = "Thermodynamics and kinetics of lithiation-induced phase transitions in nanoporous antimony",

abstract = "The impact of nanosizing on the phase transition mechanisms of electrode materials is still not well understood. In this study, we reveal that nanosizing can lower the energy barrier and entropy changes associated with phase transformations, ultimately improving the electrochemical performance of nanoporous antimony electrodes in comparison to microsized antimony.",

author = "Shichen Wang and Zeyu Jin and Chaojie Yang and Jie Lu and Yao Gao and Qiu, \{Hua Jun\} and Kaikai Li",

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doi = "10.1039/d5cc00094g",

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T1 - Thermodynamics and kinetics of lithiation-induced phase transitions in nanoporous antimony

AU - Wang, Shichen

AU - Jin, Zeyu

AU - Yang, Chaojie

AU - Lu, Jie

AU - Gao, Yao

AU - Qiu, Hua Jun

AU - Li, Kaikai

PY - 2025/3/4

Y1 - 2025/3/4

N2 - The impact of nanosizing on the phase transition mechanisms of electrode materials is still not well understood. In this study, we reveal that nanosizing can lower the energy barrier and entropy changes associated with phase transformations, ultimately improving the electrochemical performance of nanoporous antimony electrodes in comparison to microsized antimony.

AB - The impact of nanosizing on the phase transition mechanisms of electrode materials is still not well understood. In this study, we reveal that nanosizing can lower the energy barrier and entropy changes associated with phase transformations, ultimately improving the electrochemical performance of nanoporous antimony electrodes in comparison to microsized antimony.

UR - https://www.scopus.com/pages/publications/86000564910

U2 - 10.1039/d5cc00094g

DO - 10.1039/d5cc00094g

M3 - 文章

C2 - 40066619

AN - SCOPUS:86000564910

SN - 1359-7345

VL - 61

SP - 5118

EP - 5121

JO - Chemical Communications

JF - Chemical Communications

IS - 27

ER -

Thermodynamics and kinetics of lithiation-induced phase transitions in nanoporous antimony

Abstract

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