Thermodynamic calculation and experimental investigation of glass formation in Zr-Ni-Ti alloy system

X. J. Liu; X. D. Hui; G. L. Chen

doi:10.1016/j.intermet.2007.10.007

Thermodynamic calculation and experimental investigation of glass formation in Zr-Ni-Ti alloy system

X. J. Liu
, X. D. Hui^*
, G. L. Chen

^*Corresponding author for this work

University of Science and Technology Beijing

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Based on the undercooling theory resulting from the existence of multicomponent chemical short-range order domains, the glass forming range (GFR) in Zr-Ni-Ti alloy system was predicted by thermodynamic calculation. In order to verify the calculated results, a series of alloys Zr_90-xNi_xTi₁₀ (x = 25, 30, 35, 40, 45, 50, 55 at.%) were designed to conduct melt-spinning experiments. The X-ray diffraction (XRD) results show that a fully amorphous structure can be obtained in as-quenched Zr_90-xNi_xTi₁₀ (x = 25, 30, 35, 40, 45 at.%) alloys, while Zr₄₀Ni₅₀Ti₁₀ and Zr₃₅Ni₅₅Ti₁₀ alloys are partially amorphous and fully crystalline, respectively. These experimental results are consistent with the predicted GFR. In addition, the glass forming ability (GFA) was investigated by differential scanning calorimetry (DSC) experiments and evaluated by a thermodynamic parameter, the reduced undercooling ΔT_r.

Original language	English
Pages (from-to)	262-266
Number of pages	5
Journal	Intermetallics
Volume	16
Issue number	2
DOIs	https://doi.org/10.1016/j.intermet.2007.10.007
State	Published - Feb 2008
Externally published	Yes

Keywords

B. Glasses, metallic
C. Rapid solidification processing
E. Phase stability, prediction
F. Diffraction

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10.1016/j.intermet.2007.10.007

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title = "Thermodynamic calculation and experimental investigation of glass formation in Zr-Ni-Ti alloy system",

abstract = "Based on the undercooling theory resulting from the existence of multicomponent chemical short-range order domains, the glass forming range (GFR) in Zr-Ni-Ti alloy system was predicted by thermodynamic calculation. In order to verify the calculated results, a series of alloys Zr90-xNixTi10 (x = 25, 30, 35, 40, 45, 50, 55 at.\%) were designed to conduct melt-spinning experiments. The X-ray diffraction (XRD) results show that a fully amorphous structure can be obtained in as-quenched Zr90-xNixTi10 (x = 25, 30, 35, 40, 45 at.\%) alloys, while Zr40Ni50Ti10 and Zr35Ni55Ti10 alloys are partially amorphous and fully crystalline, respectively. These experimental results are consistent with the predicted GFR. In addition, the glass forming ability (GFA) was investigated by differential scanning calorimetry (DSC) experiments and evaluated by a thermodynamic parameter, the reduced undercooling ΔTr.",

keywords = "B. Glasses, metallic, C. Rapid solidification processing, E. Phase stability, prediction, F. Diffraction",

author = "Liu, \{X. J.\} and Hui, \{X. D.\} and Chen, \{G. L.\}",

year = "2008",

month = feb,

doi = "10.1016/j.intermet.2007.10.007",

language = "英语",

volume = "16",

pages = "262--266",

journal = "Intermetallics",

issn = "0966-9795",

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T1 - Thermodynamic calculation and experimental investigation of glass formation in Zr-Ni-Ti alloy system

AU - Liu, X. J.

AU - Hui, X. D.

AU - Chen, G. L.

PY - 2008/2

Y1 - 2008/2

N2 - Based on the undercooling theory resulting from the existence of multicomponent chemical short-range order domains, the glass forming range (GFR) in Zr-Ni-Ti alloy system was predicted by thermodynamic calculation. In order to verify the calculated results, a series of alloys Zr90-xNixTi10 (x = 25, 30, 35, 40, 45, 50, 55 at.%) were designed to conduct melt-spinning experiments. The X-ray diffraction (XRD) results show that a fully amorphous structure can be obtained in as-quenched Zr90-xNixTi10 (x = 25, 30, 35, 40, 45 at.%) alloys, while Zr40Ni50Ti10 and Zr35Ni55Ti10 alloys are partially amorphous and fully crystalline, respectively. These experimental results are consistent with the predicted GFR. In addition, the glass forming ability (GFA) was investigated by differential scanning calorimetry (DSC) experiments and evaluated by a thermodynamic parameter, the reduced undercooling ΔTr.

AB - Based on the undercooling theory resulting from the existence of multicomponent chemical short-range order domains, the glass forming range (GFR) in Zr-Ni-Ti alloy system was predicted by thermodynamic calculation. In order to verify the calculated results, a series of alloys Zr90-xNixTi10 (x = 25, 30, 35, 40, 45, 50, 55 at.%) were designed to conduct melt-spinning experiments. The X-ray diffraction (XRD) results show that a fully amorphous structure can be obtained in as-quenched Zr90-xNixTi10 (x = 25, 30, 35, 40, 45 at.%) alloys, while Zr40Ni50Ti10 and Zr35Ni55Ti10 alloys are partially amorphous and fully crystalline, respectively. These experimental results are consistent with the predicted GFR. In addition, the glass forming ability (GFA) was investigated by differential scanning calorimetry (DSC) experiments and evaluated by a thermodynamic parameter, the reduced undercooling ΔTr.

KW - B. Glasses, metallic

KW - C. Rapid solidification processing

KW - E. Phase stability, prediction

KW - F. Diffraction

UR - https://www.scopus.com/pages/publications/38349079818

U2 - 10.1016/j.intermet.2007.10.007

DO - 10.1016/j.intermet.2007.10.007

M3 - 文章

AN - SCOPUS:38349079818

SN - 0966-9795

VL - 16

SP - 262

EP - 266

JO - Intermetallics

JF - Intermetallics

IS - 2

ER -

Thermodynamic calculation and experimental investigation of glass formation in Zr-Ni-Ti alloy system

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Keywords

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