Thermodynamic assessments of the Er-Sb and Sb-Tm systems

S. L. Wang; Z. B. Hu; F. Gao; C. P. Wang; X. J. Liu

doi:10.1016/j.calphad.2011.08.001

Thermodynamic assessments of the Er-Sb and Sb-Tm systems

S. L. Wang
, Z. B. Hu
, F. Gao
, C. P. Wang
, X. J. Liu^*

^*Corresponding author for this work

Longyan University
Qingdao University of Science and Technology
Xiamen University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

By using the calculation of phase diagrams (CALPHAD) method, thermodynamic assessments of the Er-Sb and Sb-Tm systems were carried out based on the available experimental data including thermodynamic properties and phase equilibria. The Gibbs free energies of the liquid, hcp, and rhombohedral phases in the Er-Sb and Sb-Tm systems were modeled by the substitutional solution model with the RedlichKister formula, and the intermetallic compounds (Er ₅Sb₃, αEr-Sb, βEr-Sb, Er-Sb₂, Sb₂Tm, αSb-Tm, βSb-Tm, α Sb₃Tm ₅, and β Sb₃Tm₅ phases) in these two binary systems were described by the sublattice model. An agreement between the present calculated results and experimental data was obtained.

Original language	English
Pages (from-to)	473-478
Number of pages	6
Journal	Calphad: Computer Coupling of Phase Diagrams and Thermochemistry
Volume	35
Issue number	4
DOIs	https://doi.org/10.1016/j.calphad.2011.08.001
State	Published - Dec 2011
Externally published	Yes

Keywords

CALPHAD
Er-Sb system
Phase diagram
Sb-Tm system

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10.1016/j.calphad.2011.08.001

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title = "Thermodynamic assessments of the Er-Sb and Sb-Tm systems",

abstract = "By using the calculation of phase diagrams (CALPHAD) method, thermodynamic assessments of the Er-Sb and Sb-Tm systems were carried out based on the available experimental data including thermodynamic properties and phase equilibria. The Gibbs free energies of the liquid, hcp, and rhombohedral phases in the Er-Sb and Sb-Tm systems were modeled by the substitutional solution model with the RedlichKister formula, and the intermetallic compounds (Er 5Sb3, αEr-Sb, βEr-Sb, Er-Sb2, Sb2Tm, αSb-Tm, βSb-Tm, α Sb3Tm 5, and β Sb3Tm5 phases) in these two binary systems were described by the sublattice model. An agreement between the present calculated results and experimental data was obtained.",

keywords = "CALPHAD, Er-Sb system, Phase diagram, Sb-Tm system",

author = "Wang, \{S. L.\} and Hu, \{Z. B.\} and F. Gao and Wang, \{C. P.\} and Liu, \{X. J.\}",

year = "2011",

month = dec,

doi = "10.1016/j.calphad.2011.08.001",

language = "英语",

volume = "35",

pages = "473--478",

journal = "Calphad: Computer Coupling of Phase Diagrams and Thermochemistry",

issn = "0364-5916",

publisher = "Elsevier Ltd",

number = "4",

}

TY - JOUR

T1 - Thermodynamic assessments of the Er-Sb and Sb-Tm systems

AU - Wang, S. L.

AU - Hu, Z. B.

AU - Gao, F.

AU - Wang, C. P.

AU - Liu, X. J.

PY - 2011/12

Y1 - 2011/12

N2 - By using the calculation of phase diagrams (CALPHAD) method, thermodynamic assessments of the Er-Sb and Sb-Tm systems were carried out based on the available experimental data including thermodynamic properties and phase equilibria. The Gibbs free energies of the liquid, hcp, and rhombohedral phases in the Er-Sb and Sb-Tm systems were modeled by the substitutional solution model with the RedlichKister formula, and the intermetallic compounds (Er 5Sb3, αEr-Sb, βEr-Sb, Er-Sb2, Sb2Tm, αSb-Tm, βSb-Tm, α Sb3Tm 5, and β Sb3Tm5 phases) in these two binary systems were described by the sublattice model. An agreement between the present calculated results and experimental data was obtained.

AB - By using the calculation of phase diagrams (CALPHAD) method, thermodynamic assessments of the Er-Sb and Sb-Tm systems were carried out based on the available experimental data including thermodynamic properties and phase equilibria. The Gibbs free energies of the liquid, hcp, and rhombohedral phases in the Er-Sb and Sb-Tm systems were modeled by the substitutional solution model with the RedlichKister formula, and the intermetallic compounds (Er 5Sb3, αEr-Sb, βEr-Sb, Er-Sb2, Sb2Tm, αSb-Tm, βSb-Tm, α Sb3Tm 5, and β Sb3Tm5 phases) in these two binary systems were described by the sublattice model. An agreement between the present calculated results and experimental data was obtained.

KW - CALPHAD

KW - Er-Sb system

KW - Phase diagram

KW - Sb-Tm system

UR - https://www.scopus.com/pages/publications/80052713255

U2 - 10.1016/j.calphad.2011.08.001

DO - 10.1016/j.calphad.2011.08.001

M3 - 文章

AN - SCOPUS:80052713255

SN - 0364-5916

VL - 35

SP - 473

EP - 478

JO - Calphad: Computer Coupling of Phase Diagrams and Thermochemistry

JF - Calphad: Computer Coupling of Phase Diagrams and Thermochemistry

IS - 4

ER -

Thermodynamic assessments of the Er-Sb and Sb-Tm systems

Abstract

Keywords

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