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Thermodynamic assessments of the bi-tb and bi-Y systems

  • S. L. Wang*
  • , Z. B. Hu
  • , F. Gao
  • , C. P. Wang
  • , X. J. Liu
  • *Corresponding author for this work
  • Longyan University
  • Qingdao University of Science and Technology
  • Xiamen University

Research output: Contribution to journalArticlepeer-review

Abstract

By using the calculation of phase diagrams (CALPHAD) method, the thermodynamic assessments of the Bi-Tb and Bi-Y systems were carried out based on the available experimental data including thermodynamic properties and phase equilibria. Gibbs free energies of the liquid, hcp, bcc, and rhombohedral phases in the Bi-Tb and Bi-Y systems were modeled by the substitutional solution model, and the intermetallic compounds (BiTb, Bi 3Tb 4, αBi 3Tb 5, βBi 3Tb 5, BiY, and Bi 3Y 5 phases) in these two binary systems were described by the sublattice model. An agreement between the present calculated results and experimental data was obtained.

Original languageEnglish
Pages (from-to)441-446
Number of pages6
JournalJournal of Phase Equilibria and Diffusion
Volume32
Issue number5
DOIs
StatePublished - Oct 2011
Externally publishedYes

Keywords

  • CALPHAD
  • phase diagram
  • thermodynamic assessment
  • thermodynamic properties

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