Abstract
By using the calculation of phase diagrams (CALPHAD) method, the thermodynamic assessments of the Bi-Tb and Bi-Y systems were carried out based on the available experimental data including thermodynamic properties and phase equilibria. Gibbs free energies of the liquid, hcp, bcc, and rhombohedral phases in the Bi-Tb and Bi-Y systems were modeled by the substitutional solution model, and the intermetallic compounds (BiTb, Bi 3Tb 4, αBi 3Tb 5, βBi 3Tb 5, BiY, and Bi 3Y 5 phases) in these two binary systems were described by the sublattice model. An agreement between the present calculated results and experimental data was obtained.
| Original language | English |
|---|---|
| Pages (from-to) | 441-446 |
| Number of pages | 6 |
| Journal | Journal of Phase Equilibria and Diffusion |
| Volume | 32 |
| Issue number | 5 |
| DOIs | |
| State | Published - Oct 2011 |
| Externally published | Yes |
Keywords
- CALPHAD
- phase diagram
- thermodynamic assessment
- thermodynamic properties
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