Thermodynamic assessments of binary phase diagrams in organic and polymeric systems

Y. C. Li; C. P. Wang; X. J. Liu

doi:10.1016/j.calphad.2008.12.007

Thermodynamic assessments of binary phase diagrams in organic and polymeric systems

Y. C. Li
, C. P. Wang
, X. J. Liu^*

^*Corresponding author for this work

Xiamen University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The Sanchez-Lacombe (SL) model and the Flory-Huggins model were used for the calculation of binary phase diagrams in organic and polymer systems, respectively. The thermodynamic parameters of the liquid and gas phases in acetone-carbon disulfide (CS₂), butane-heptane, cyclohexane-aniline systems, and liquid phases in polystyrene-polybutadiene and polystyrene-bisphenol A poly-carbonate systems were optimized, based on the experimental data. The calculated results with various pressures are in good agreement with the experimental data. It is hoped that this method will be widely applied in the prediction of binary phase diagrams in organic and polymer systems.

Original language	English
Pages (from-to)	415-419
Number of pages	5
Journal	Calphad: Computer Coupling of Phase Diagrams and Thermochemistry
Volume	33
Issue number	2
DOIs	https://doi.org/10.1016/j.calphad.2008.12.007
State	Published - Jun 2009
Externally published	Yes

Keywords

Organic
Phase diagram
Polymer

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10.1016/j.calphad.2008.12.007

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title = "Thermodynamic assessments of binary phase diagrams in organic and polymeric systems",

abstract = "The Sanchez-Lacombe (SL) model and the Flory-Huggins model were used for the calculation of binary phase diagrams in organic and polymer systems, respectively. The thermodynamic parameters of the liquid and gas phases in acetone-carbon disulfide (CS2), butane-heptane, cyclohexane-aniline systems, and liquid phases in polystyrene-polybutadiene and polystyrene-bisphenol A poly-carbonate systems were optimized, based on the experimental data. The calculated results with various pressures are in good agreement with the experimental data. It is hoped that this method will be widely applied in the prediction of binary phase diagrams in organic and polymer systems.",

keywords = "Organic, Phase diagram, Polymer",

author = "Li, \{Y. C.\} and Wang, \{C. P.\} and Liu, \{X. J.\}",

year = "2009",

month = jun,

doi = "10.1016/j.calphad.2008.12.007",

language = "英语",

volume = "33",

pages = "415--419",

journal = "Calphad: Computer Coupling of Phase Diagrams and Thermochemistry",

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number = "2",

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T1 - Thermodynamic assessments of binary phase diagrams in organic and polymeric systems

AU - Li, Y. C.

AU - Wang, C. P.

AU - Liu, X. J.

PY - 2009/6

Y1 - 2009/6

N2 - The Sanchez-Lacombe (SL) model and the Flory-Huggins model were used for the calculation of binary phase diagrams in organic and polymer systems, respectively. The thermodynamic parameters of the liquid and gas phases in acetone-carbon disulfide (CS2), butane-heptane, cyclohexane-aniline systems, and liquid phases in polystyrene-polybutadiene and polystyrene-bisphenol A poly-carbonate systems were optimized, based on the experimental data. The calculated results with various pressures are in good agreement with the experimental data. It is hoped that this method will be widely applied in the prediction of binary phase diagrams in organic and polymer systems.

AB - The Sanchez-Lacombe (SL) model and the Flory-Huggins model were used for the calculation of binary phase diagrams in organic and polymer systems, respectively. The thermodynamic parameters of the liquid and gas phases in acetone-carbon disulfide (CS2), butane-heptane, cyclohexane-aniline systems, and liquid phases in polystyrene-polybutadiene and polystyrene-bisphenol A poly-carbonate systems were optimized, based on the experimental data. The calculated results with various pressures are in good agreement with the experimental data. It is hoped that this method will be widely applied in the prediction of binary phase diagrams in organic and polymer systems.

KW - Organic

KW - Phase diagram

KW - Polymer

UR - https://www.scopus.com/pages/publications/67349087943

U2 - 10.1016/j.calphad.2008.12.007

DO - 10.1016/j.calphad.2008.12.007

M3 - 文章

AN - SCOPUS:67349087943

SN - 0364-5916

VL - 33

SP - 415

EP - 419

JO - Calphad: Computer Coupling of Phase Diagrams and Thermochemistry

JF - Calphad: Computer Coupling of Phase Diagrams and Thermochemistry

IS - 2

ER -

Thermodynamic assessments of binary phase diagrams in organic and polymeric systems

Abstract

Keywords

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