Thermodynamic assessment of the Sb-Sm and Sm-Sn systems

X. J. Liu; M. H. Chen; Y. Lu; Y. X. Huang; D. Wang; Q. He; D. L. Zhao; C. P. Wang

doi:10.1016/j.calphad.2014.07.002

Thermodynamic assessment of the Sb-Sm and Sm-Sn systems

X. J. Liu
, M. H. Chen
, Y. Lu
, Y. X. Huang
, D. Wang
, Q. He
, D. L. Zhao
, C. P. Wang^*

^*Corresponding author for this work

Xiamen University
China Iron and Steel Research Institute Group

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The thermodynamic assessment of the Sb-Sm and Sm-Sn binary systems have been carried out by using the CALPHAD (CALculation of PHAse Diagrams) method on the basis of the experimental data including phase equilibria and thermodynamic properties. The Gibbs free energies of the solution phases (Liquid, Bcc, Bct, Hcp and Rhombohedral phase) were described by the subregular solution model with the Relich-Kister polynomial, and those of the intermetallic compounds were described by the two-sublattice model. A consistent set of thermodynamic parameters has been derived for describing the Gibbs free energies of each phase in the Sb-Sm and Sm-Sn systems. A reasonable agreement was obtained between the calculated results and experimental data.

Original language	English
Pages (from-to)	129-135
Number of pages	7
Journal	Calphad: Computer Coupling of Phase Diagrams and Thermochemistry
Volume	47
DOIs	https://doi.org/10.1016/j.calphad.2014.07.002
State	Published - Dec 2014
Externally published	Yes

Keywords

CALPHAD method
Rare earth alloys
Thermodynamic calculation

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10.1016/j.calphad.2014.07.002

Cite this

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title = "Thermodynamic assessment of the Sb-Sm and Sm-Sn systems",

abstract = "The thermodynamic assessment of the Sb-Sm and Sm-Sn binary systems have been carried out by using the CALPHAD (CALculation of PHAse Diagrams) method on the basis of the experimental data including phase equilibria and thermodynamic properties. The Gibbs free energies of the solution phases (Liquid, Bcc, Bct, Hcp and Rhombohedral phase) were described by the subregular solution model with the Relich-Kister polynomial, and those of the intermetallic compounds were described by the two-sublattice model. A consistent set of thermodynamic parameters has been derived for describing the Gibbs free energies of each phase in the Sb-Sm and Sm-Sn systems. A reasonable agreement was obtained between the calculated results and experimental data.",

keywords = "CALPHAD method, Rare earth alloys, Thermodynamic calculation",

author = "Liu, \{X. J.\} and Chen, \{M. H.\} and Y. Lu and Huang, \{Y. X.\} and D. Wang and Q. He and Zhao, \{D. L.\} and Wang, \{C. P.\}",

year = "2014",

month = dec,

doi = "10.1016/j.calphad.2014.07.002",

language = "英语",

volume = "47",

pages = "129--135",

journal = "Calphad: Computer Coupling of Phase Diagrams and Thermochemistry",

issn = "0364-5916",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Thermodynamic assessment of the Sb-Sm and Sm-Sn systems

AU - Liu, X. J.

AU - Chen, M. H.

AU - Lu, Y.

AU - Huang, Y. X.

AU - Wang, D.

AU - He, Q.

AU - Zhao, D. L.

AU - Wang, C. P.

PY - 2014/12

Y1 - 2014/12

N2 - The thermodynamic assessment of the Sb-Sm and Sm-Sn binary systems have been carried out by using the CALPHAD (CALculation of PHAse Diagrams) method on the basis of the experimental data including phase equilibria and thermodynamic properties. The Gibbs free energies of the solution phases (Liquid, Bcc, Bct, Hcp and Rhombohedral phase) were described by the subregular solution model with the Relich-Kister polynomial, and those of the intermetallic compounds were described by the two-sublattice model. A consistent set of thermodynamic parameters has been derived for describing the Gibbs free energies of each phase in the Sb-Sm and Sm-Sn systems. A reasonable agreement was obtained between the calculated results and experimental data.

AB - The thermodynamic assessment of the Sb-Sm and Sm-Sn binary systems have been carried out by using the CALPHAD (CALculation of PHAse Diagrams) method on the basis of the experimental data including phase equilibria and thermodynamic properties. The Gibbs free energies of the solution phases (Liquid, Bcc, Bct, Hcp and Rhombohedral phase) were described by the subregular solution model with the Relich-Kister polynomial, and those of the intermetallic compounds were described by the two-sublattice model. A consistent set of thermodynamic parameters has been derived for describing the Gibbs free energies of each phase in the Sb-Sm and Sm-Sn systems. A reasonable agreement was obtained between the calculated results and experimental data.

KW - CALPHAD method

KW - Rare earth alloys

KW - Thermodynamic calculation

UR - https://www.scopus.com/pages/publications/84907327425

U2 - 10.1016/j.calphad.2014.07.002

DO - 10.1016/j.calphad.2014.07.002

M3 - 文章

AN - SCOPUS:84907327425

SN - 0364-5916

VL - 47

SP - 129

EP - 135

JO - Calphad: Computer Coupling of Phase Diagrams and Thermochemistry

JF - Calphad: Computer Coupling of Phase Diagrams and Thermochemistry

ER -

Thermodynamic assessment of the Sb-Sm and Sm-Sn systems

Abstract

Keywords

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