The synthesis, crystal structure and optical limiting properties of ZnI2-pyrazine adduct polymer linked by iodine⋯iodine supramolecular soft-soft interaction

Yinglin Song; Yunyin Niu; Hongwei Hou; Yu Zhu

doi:10.1016/j.molstruc.2003.10.025

The synthesis, crystal structure and optical limiting properties of ZnI₂-pyrazine adduct polymer linked by iodine⋯iodine supramolecular soft-soft interaction

Yinglin Song
, Yunyin Niu
, Hongwei Hou^*
, Yu Zhu

^*Corresponding author for this work

School of Physics

Zhengzhou University

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The structure and molecular packing of a ZnI₂-pyrazine adduct are reported. Attractive zigzag II interactions dominate the molecular packing in the structure and link ZnI₂-pyz zigzag chains to result in the formation of three-dimensional network structure. The optical limiting property was studied by Z-scan technology with an 8ns-pulsed laser at 532 nm. The limiting threshold was determined to be 0.13 J cm^-2, which is comparable to those of many heterothiometallates.

Original language	English
Pages (from-to)	69-74
Number of pages	6
Journal	Journal of Molecular Structure
Volume	689
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molstruc.2003.10.025
State	Published - 3 Feb 2004

Keywords

Optical limiting properties
Soft-soft interaction
Supramolecular
Zinc iodide

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10.1016/j.molstruc.2003.10.025

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title = "The synthesis, crystal structure and optical limiting properties of ZnI2-pyrazine adduct polymer linked by iodine⋯iodine supramolecular soft-soft interaction",

abstract = "The structure and molecular packing of a ZnI2-pyrazine adduct are reported. Attractive zigzag II interactions dominate the molecular packing in the structure and link ZnI2-pyz zigzag chains to result in the formation of three-dimensional network structure. The optical limiting property was studied by Z-scan technology with an 8ns-pulsed laser at 532 nm. The limiting threshold was determined to be 0.13 J cm-2, which is comparable to those of many heterothiometallates.",

keywords = "Optical limiting properties, Soft-soft interaction, Supramolecular, Zinc iodide",

author = "Yinglin Song and Yunyin Niu and Hongwei Hou and Yu Zhu",

year = "2004",

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T1 - The synthesis, crystal structure and optical limiting properties of ZnI2-pyrazine adduct polymer linked by iodine⋯iodine supramolecular soft-soft interaction

AU - Song, Yinglin

AU - Niu, Yunyin

AU - Hou, Hongwei

AU - Zhu, Yu

PY - 2004/2/3

Y1 - 2004/2/3

N2 - The structure and molecular packing of a ZnI2-pyrazine adduct are reported. Attractive zigzag II interactions dominate the molecular packing in the structure and link ZnI2-pyz zigzag chains to result in the formation of three-dimensional network structure. The optical limiting property was studied by Z-scan technology with an 8ns-pulsed laser at 532 nm. The limiting threshold was determined to be 0.13 J cm-2, which is comparable to those of many heterothiometallates.

AB - The structure and molecular packing of a ZnI2-pyrazine adduct are reported. Attractive zigzag II interactions dominate the molecular packing in the structure and link ZnI2-pyz zigzag chains to result in the formation of three-dimensional network structure. The optical limiting property was studied by Z-scan technology with an 8ns-pulsed laser at 532 nm. The limiting threshold was determined to be 0.13 J cm-2, which is comparable to those of many heterothiometallates.

KW - Optical limiting properties

KW - Soft-soft interaction

KW - Supramolecular

KW - Zinc iodide

UR - https://www.scopus.com/pages/publications/1542362596

U2 - 10.1016/j.molstruc.2003.10.025

DO - 10.1016/j.molstruc.2003.10.025

M3 - 文章

AN - SCOPUS:1542362596

SN - 0022-2860

VL - 689

SP - 69

EP - 74

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-2

ER -

The synthesis, crystal structure and optical limiting properties of ZnI₂-pyrazine adduct polymer linked by iodine⋯iodine supramolecular soft-soft interaction

Abstract

Keywords

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