The Synthesis and Characterization of Carborane-Terminated Polymethyl Methacrylate via ATRP

Dezhi Qu; Yongping Bai; Ning Li

doi:10.1007/s10904-019-01113-3

The Synthesis and Characterization of Carborane-Terminated Polymethyl Methacrylate via ATRP

Dezhi Qu
, Yongping Bai^*
, Ning Li

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Wuxi HIT Limited Corporation & Research Institute of New Materials
Changzhou University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The atom transfer radical polymerization (ATRP) of methyl methacrylate using CuCl and various ligands catalytic system with 1-bromomethyl-carborane was investigated. Due to the aromaticity of carborane casued by the electron delocalization boron cage, carborane can be used as initiator. To determined the optimal conditions for this ATRP reaction, we studied the influences of different solvents, ratios of monomer to initiator and ratios of catalyst to ligand for polymerization, and finally determined the optimal condition for this ATRP reaction. Under the optimal condition, the polymer will show a very narrow molecular weight distribution (polydispersity index (PDI) = 1.17, measured by GPC). The apparent reaction rates of polymerization were well controlled with a linear increase and monomer conversion reached up to 94%.

Original language	English
Pages (from-to)	1496-1502
Number of pages	7
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume	29
Issue number	5
DOIs	https://doi.org/10.1007/s10904-019-01113-3
State	Published - 1 Sep 2019
Externally published	Yes

Keywords

1-Bromomethyl-carborane
Atom transfer radical polymerization (ATRP)
Living controlled radical polymerization

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10.1007/s10904-019-01113-3

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title = "The Synthesis and Characterization of Carborane-Terminated Polymethyl Methacrylate via ATRP",

abstract = "The atom transfer radical polymerization (ATRP) of methyl methacrylate using CuCl and various ligands catalytic system with 1-bromomethyl-carborane was investigated. Due to the aromaticity of carborane casued by the electron delocalization boron cage, carborane can be used as initiator. To determined the optimal conditions for this ATRP reaction, we studied the influences of different solvents, ratios of monomer to initiator and ratios of catalyst to ligand for polymerization, and finally determined the optimal condition for this ATRP reaction. Under the optimal condition, the polymer will show a very narrow molecular weight distribution (polydispersity index (PDI) = 1.17, measured by GPC). The apparent reaction rates of polymerization were well controlled with a linear increase and monomer conversion reached up to 94\%.",

keywords = "1-Bromomethyl-carborane, Atom transfer radical polymerization (ATRP), Living controlled radical polymerization",

author = "Dezhi Qu and Yongping Bai and Ning Li",

note = "Publisher Copyright: {\textcopyright} 2019, Springer Science+Business Media, LLC, part of Springer Nature.",

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doi = "10.1007/s10904-019-01113-3",

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AU - Qu, Dezhi

AU - Bai, Yongping

AU - Li, Ning

PY - 2019/9/1

Y1 - 2019/9/1

N2 - The atom transfer radical polymerization (ATRP) of methyl methacrylate using CuCl and various ligands catalytic system with 1-bromomethyl-carborane was investigated. Due to the aromaticity of carborane casued by the electron delocalization boron cage, carborane can be used as initiator. To determined the optimal conditions for this ATRP reaction, we studied the influences of different solvents, ratios of monomer to initiator and ratios of catalyst to ligand for polymerization, and finally determined the optimal condition for this ATRP reaction. Under the optimal condition, the polymer will show a very narrow molecular weight distribution (polydispersity index (PDI) = 1.17, measured by GPC). The apparent reaction rates of polymerization were well controlled with a linear increase and monomer conversion reached up to 94%.

AB - The atom transfer radical polymerization (ATRP) of methyl methacrylate using CuCl and various ligands catalytic system with 1-bromomethyl-carborane was investigated. Due to the aromaticity of carborane casued by the electron delocalization boron cage, carborane can be used as initiator. To determined the optimal conditions for this ATRP reaction, we studied the influences of different solvents, ratios of monomer to initiator and ratios of catalyst to ligand for polymerization, and finally determined the optimal condition for this ATRP reaction. Under the optimal condition, the polymer will show a very narrow molecular weight distribution (polydispersity index (PDI) = 1.17, measured by GPC). The apparent reaction rates of polymerization were well controlled with a linear increase and monomer conversion reached up to 94%.

KW - 1-Bromomethyl-carborane

KW - Atom transfer radical polymerization (ATRP)

KW - Living controlled radical polymerization

UR - https://www.scopus.com/pages/publications/85062641861

U2 - 10.1007/s10904-019-01113-3

DO - 10.1007/s10904-019-01113-3

M3 - 文章

AN - SCOPUS:85062641861

SN - 1574-1443

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JO - Journal of Inorganic and Organometallic Polymers and Materials

JF - Journal of Inorganic and Organometallic Polymers and Materials

IS - 5

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The Synthesis and Characterization of Carborane-Terminated Polymethyl Methacrylate via ATRP

Abstract

Keywords

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