The syntheses, crystal structures and optical limiting effects of transition metal adducts bridged by bipyridyl-based ligands

Yunyin Niu; Ning Zhang; Yinglin Song; Hongwei Hou; Yaoting Fan; Yu Zhu

doi:10.1016/j.inoche.2005.02.012

The syntheses, crystal structures and optical limiting effects of transition metal adducts bridged by bipyridyl-based ligands

Yunyin Niu
, Ning Zhang
, Yinglin Song
, Hongwei Hou^*
, Yaoting Fan
, Yu Zhu

^*Corresponding author for this work

School of Physics

Zhengzhou University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Two novel compounds [HgI₂(bpt)]₂ (1) and [MnCl ₂(bpt)₂]_n • 2CH₃OH (2) (bpt = N,N′-bis(3-pyridylmethyl)thiourea), have been synthesized via the self-assembly reaction in solution. Complex 1 possesses a two-dimensional supramolecular network formed by hydrogen bonds among repeating [HgI ₂(bpt)]₂ dimeric units. Complex 2 is a one-dimensional coordination polymer containing uniform -MnCl₂-(bpt) ₂-MnCl₂-(bpt)₂- double chain. Their limiting thresholds were determined to be 1.0 J cm^-2 for 1 and 0.7 J cm ^-2 for 2 and the results testified that the skeletal structure and constituted metal nuclearity have a strong impact on the NLO properties of the complexes.

Original language	English
Pages (from-to)	495-499
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	8
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2005.02.012
State	Published - Jun 2005

Keywords

Bipyridyl-based ligand
Coordination polymer
Double chain structure
Optical limiting effects

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10.1016/j.inoche.2005.02.012

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@article{7c60415cda9041e2bcc309552ccedd89,

title = "The syntheses, crystal structures and optical limiting effects of transition metal adducts bridged by bipyridyl-based ligands",

abstract = "Two novel compounds [HgI2(bpt)]2 (1) and [MnCl 2(bpt)2]n • 2CH3OH (2) (bpt = N,N′-bis(3-pyridylmethyl)thiourea), have been synthesized via the self-assembly reaction in solution. Complex 1 possesses a two-dimensional supramolecular network formed by hydrogen bonds among repeating [HgI 2(bpt)]2 dimeric units. Complex 2 is a one-dimensional coordination polymer containing uniform -MnCl2-(bpt) 2-MnCl2-(bpt)2- double chain. Their limiting thresholds were determined to be 1.0 J cm-2 for 1 and 0.7 J cm -2 for 2 and the results testified that the skeletal structure and constituted metal nuclearity have a strong impact on the NLO properties of the complexes.",

keywords = "Bipyridyl-based ligand, Coordination polymer, Double chain structure, Optical limiting effects",

author = "Yunyin Niu and Ning Zhang and Yinglin Song and Hongwei Hou and Yaoting Fan and Yu Zhu",

year = "2005",

month = jun,

doi = "10.1016/j.inoche.2005.02.012",

language = "英语",

volume = "8",

pages = "495--499",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "6",

}

TY - JOUR

T1 - The syntheses, crystal structures and optical limiting effects of transition metal adducts bridged by bipyridyl-based ligands

AU - Niu, Yunyin

AU - Zhang, Ning

AU - Song, Yinglin

AU - Hou, Hongwei

AU - Fan, Yaoting

AU - Zhu, Yu

PY - 2005/6

Y1 - 2005/6

N2 - Two novel compounds [HgI2(bpt)]2 (1) and [MnCl 2(bpt)2]n • 2CH3OH (2) (bpt = N,N′-bis(3-pyridylmethyl)thiourea), have been synthesized via the self-assembly reaction in solution. Complex 1 possesses a two-dimensional supramolecular network formed by hydrogen bonds among repeating [HgI 2(bpt)]2 dimeric units. Complex 2 is a one-dimensional coordination polymer containing uniform -MnCl2-(bpt) 2-MnCl2-(bpt)2- double chain. Their limiting thresholds were determined to be 1.0 J cm-2 for 1 and 0.7 J cm -2 for 2 and the results testified that the skeletal structure and constituted metal nuclearity have a strong impact on the NLO properties of the complexes.

AB - Two novel compounds [HgI2(bpt)]2 (1) and [MnCl 2(bpt)2]n • 2CH3OH (2) (bpt = N,N′-bis(3-pyridylmethyl)thiourea), have been synthesized via the self-assembly reaction in solution. Complex 1 possesses a two-dimensional supramolecular network formed by hydrogen bonds among repeating [HgI 2(bpt)]2 dimeric units. Complex 2 is a one-dimensional coordination polymer containing uniform -MnCl2-(bpt) 2-MnCl2-(bpt)2- double chain. Their limiting thresholds were determined to be 1.0 J cm-2 for 1 and 0.7 J cm -2 for 2 and the results testified that the skeletal structure and constituted metal nuclearity have a strong impact on the NLO properties of the complexes.

KW - Bipyridyl-based ligand

KW - Coordination polymer

KW - Double chain structure

KW - Optical limiting effects

UR - https://www.scopus.com/pages/publications/18844447207

U2 - 10.1016/j.inoche.2005.02.012

DO - 10.1016/j.inoche.2005.02.012

M3 - 文章

AN - SCOPUS:18844447207

SN - 1387-7003

VL - 8

SP - 495

EP - 499

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

The syntheses, crystal structures and optical limiting effects of transition metal adducts bridged by bipyridyl-based ligands

Abstract

Keywords

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