The preparation and optical limiting properties of POSS-based molecular hybrid functional materials

Xinyan Su; Shanyi Guang; Hongyao Xu; Junyi Yang; Yinglin Song

doi:10.1016/j.dyepig.2010.02.006

The preparation and optical limiting properties of POSS-based molecular hybrid functional materials

Xinyan Su
, Shanyi Guang
, Hongyao Xu^*
, Junyi Yang
, Yinglin Song

^*Corresponding author for this work

Donghua University
Shandong University
Soochow University

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

A series of organic/inorganic molecular hybrid nonlinear optical materials were prepared by incorporating azobenzene nonlinear optical chromophores into nanosized, inorganic, polyhedral oligomeric silsesquioxane. Each of the hybrids was soluble in common solvents such as CHCl₃, THF, toluene and C₂H₄Cl₂, and exhibited good film-forming properties. Their structures and properties were characterized using FTIR, ¹H NMR, ¹³C NMR, ²⁹Si NMR, UV, TGA, DSC and nonlinear optical analyses, respectively. All hybrid compounds displayed good optical limiting properties, large nonlinear optical response and high thermal stability. The optical limiting mechanism was investigated.

Original language	English
Pages (from-to)	69-75
Number of pages	7
Journal	Dyes and Pigments
Volume	87
Issue number	1
DOIs	https://doi.org/10.1016/j.dyepig.2010.02.006
State	Published - Sep 2010
Externally published	Yes

Keywords

Azobenzene
NLO
Optical limiting
Organic/inorganic hybrid
POSS
Thermal stability

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10.1016/j.dyepig.2010.02.006

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title = "The preparation and optical limiting properties of POSS-based molecular hybrid functional materials",

abstract = "A series of organic/inorganic molecular hybrid nonlinear optical materials were prepared by incorporating azobenzene nonlinear optical chromophores into nanosized, inorganic, polyhedral oligomeric silsesquioxane. Each of the hybrids was soluble in common solvents such as CHCl3, THF, toluene and C2H4Cl2, and exhibited good film-forming properties. Their structures and properties were characterized using FTIR, 1H NMR, 13C NMR, 29Si NMR, UV, TGA, DSC and nonlinear optical analyses, respectively. All hybrid compounds displayed good optical limiting properties, large nonlinear optical response and high thermal stability. The optical limiting mechanism was investigated.",

keywords = "Azobenzene, NLO, Optical limiting, Organic/inorganic hybrid, POSS, Thermal stability",

author = "Xinyan Su and Shanyi Guang and Hongyao Xu and Junyi Yang and Yinglin Song",

year = "2010",

month = sep,

doi = "10.1016/j.dyepig.2010.02.006",

language = "英语",

volume = "87",

pages = "69--75",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - The preparation and optical limiting properties of POSS-based molecular hybrid functional materials

AU - Su, Xinyan

AU - Guang, Shanyi

AU - Xu, Hongyao

AU - Yang, Junyi

AU - Song, Yinglin

PY - 2010/9

Y1 - 2010/9

N2 - A series of organic/inorganic molecular hybrid nonlinear optical materials were prepared by incorporating azobenzene nonlinear optical chromophores into nanosized, inorganic, polyhedral oligomeric silsesquioxane. Each of the hybrids was soluble in common solvents such as CHCl3, THF, toluene and C2H4Cl2, and exhibited good film-forming properties. Their structures and properties were characterized using FTIR, 1H NMR, 13C NMR, 29Si NMR, UV, TGA, DSC and nonlinear optical analyses, respectively. All hybrid compounds displayed good optical limiting properties, large nonlinear optical response and high thermal stability. The optical limiting mechanism was investigated.

AB - A series of organic/inorganic molecular hybrid nonlinear optical materials were prepared by incorporating azobenzene nonlinear optical chromophores into nanosized, inorganic, polyhedral oligomeric silsesquioxane. Each of the hybrids was soluble in common solvents such as CHCl3, THF, toluene and C2H4Cl2, and exhibited good film-forming properties. Their structures and properties were characterized using FTIR, 1H NMR, 13C NMR, 29Si NMR, UV, TGA, DSC and nonlinear optical analyses, respectively. All hybrid compounds displayed good optical limiting properties, large nonlinear optical response and high thermal stability. The optical limiting mechanism was investigated.

KW - Azobenzene

KW - NLO

KW - Optical limiting

KW - Organic/inorganic hybrid

KW - POSS

KW - Thermal stability

UR - https://www.scopus.com/pages/publications/77951667780

U2 - 10.1016/j.dyepig.2010.02.006

DO - 10.1016/j.dyepig.2010.02.006

M3 - 文章

AN - SCOPUS:77951667780

SN - 0143-7208

VL - 87

SP - 69

EP - 75

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 1

ER -

The preparation and optical limiting properties of POSS-based molecular hybrid functional materials

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Keywords

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