Tetradecylphosphonic acid modified BaTiO3 nanoparticles and its nanocomposite

Hui Jian Ye; Wen Zhu Shao; Liang Zhen

doi:10.1016/j.colsurfa.2013.02.068

Tetradecylphosphonic acid modified BaTiO₃ nanoparticles and its nanocomposite

Hui Jian Ye
, Wen Zhu Shao
, Liang Zhen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Surface-functionalization of BaTiO₃ nanoparticles and subsequent utilization of simple solution casting to yield the good compatible PVDF nanocomposites were investigated. 1-Tetradecylphosphonic acid (TDPA) was synthesized and then used to functionalize the surface of BaTiO₃ nanoparticles. The prepared TDPA-BaTiO₃ nanoparticles were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). These results indicated that the surface of nanoparticles was grafted successfully with such phosphonic acid. Also, the existing ligands of surface were examined, and the coverage onto surface of BaTiO₃ nanoparticles evaluated by thermogravimetric analysis (TGA) was 25.1%. The dispersion of modified nanoparticles in ethanol and dichloromethane was significantly improved. Besides of good flexibility, PVDF nanocomposite film with volume fraction of 40vol.% modified nanofillers exhibited high dielectric constant and low dielectric loss.

Original language	English
Pages (from-to)	19-25
Number of pages	7
Journal	Colloids and Surfaces A: Physicochemical and Engineering Aspects
Volume	427
DOIs	https://doi.org/10.1016/j.colsurfa.2013.02.068
State	Published - Jun 2013
Externally published	Yes

Keywords

Barium titanate
Dielectric nanocomposite
Phosphonic acid
Surface functionalization

Access to Document

10.1016/j.colsurfa.2013.02.068

Cite this

@article{8aa2df278efd4244a2e1554e5a986416,

title = "Tetradecylphosphonic acid modified BaTiO3 nanoparticles and its nanocomposite",

abstract = "Surface-functionalization of BaTiO3 nanoparticles and subsequent utilization of simple solution casting to yield the good compatible PVDF nanocomposites were investigated. 1-Tetradecylphosphonic acid (TDPA) was synthesized and then used to functionalize the surface of BaTiO3 nanoparticles. The prepared TDPA-BaTiO3 nanoparticles were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). These results indicated that the surface of nanoparticles was grafted successfully with such phosphonic acid. Also, the existing ligands of surface were examined, and the coverage onto surface of BaTiO3 nanoparticles evaluated by thermogravimetric analysis (TGA) was 25.1\%. The dispersion of modified nanoparticles in ethanol and dichloromethane was significantly improved. Besides of good flexibility, PVDF nanocomposite film with volume fraction of 40vol.\% modified nanofillers exhibited high dielectric constant and low dielectric loss.",

keywords = "Barium titanate, Dielectric nanocomposite, Phosphonic acid, Surface functionalization",

author = "Ye, \{Hui Jian\} and Shao, \{Wen Zhu\} and Liang Zhen",

year = "2013",

month = jun,

doi = "10.1016/j.colsurfa.2013.02.068",

language = "英语",

volume = "427",

pages = "19--25",

journal = "Colloids and Surfaces A: Physicochemical and Engineering Aspects",

issn = "0927-7757",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Tetradecylphosphonic acid modified BaTiO3 nanoparticles and its nanocomposite

AU - Ye, Hui Jian

AU - Shao, Wen Zhu

AU - Zhen, Liang

PY - 2013/6

Y1 - 2013/6

N2 - Surface-functionalization of BaTiO3 nanoparticles and subsequent utilization of simple solution casting to yield the good compatible PVDF nanocomposites were investigated. 1-Tetradecylphosphonic acid (TDPA) was synthesized and then used to functionalize the surface of BaTiO3 nanoparticles. The prepared TDPA-BaTiO3 nanoparticles were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). These results indicated that the surface of nanoparticles was grafted successfully with such phosphonic acid. Also, the existing ligands of surface were examined, and the coverage onto surface of BaTiO3 nanoparticles evaluated by thermogravimetric analysis (TGA) was 25.1%. The dispersion of modified nanoparticles in ethanol and dichloromethane was significantly improved. Besides of good flexibility, PVDF nanocomposite film with volume fraction of 40vol.% modified nanofillers exhibited high dielectric constant and low dielectric loss.

AB - Surface-functionalization of BaTiO3 nanoparticles and subsequent utilization of simple solution casting to yield the good compatible PVDF nanocomposites were investigated. 1-Tetradecylphosphonic acid (TDPA) was synthesized and then used to functionalize the surface of BaTiO3 nanoparticles. The prepared TDPA-BaTiO3 nanoparticles were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). These results indicated that the surface of nanoparticles was grafted successfully with such phosphonic acid. Also, the existing ligands of surface were examined, and the coverage onto surface of BaTiO3 nanoparticles evaluated by thermogravimetric analysis (TGA) was 25.1%. The dispersion of modified nanoparticles in ethanol and dichloromethane was significantly improved. Besides of good flexibility, PVDF nanocomposite film with volume fraction of 40vol.% modified nanofillers exhibited high dielectric constant and low dielectric loss.

KW - Barium titanate

KW - Dielectric nanocomposite

KW - Phosphonic acid

KW - Surface functionalization

UR - https://www.scopus.com/pages/publications/84876343466

U2 - 10.1016/j.colsurfa.2013.02.068

DO - 10.1016/j.colsurfa.2013.02.068

M3 - 文章

AN - SCOPUS:84876343466

SN - 0927-7757

VL - 427

SP - 19

EP - 25

JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects

JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects

ER -

Tetradecylphosphonic acid modified BaTiO₃ nanoparticles and its nanocomposite

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this