Tetra- and Octapyrroles Synthesized from Confusion and Fusion Approaches

Jiahui Kong; Qiong Zhang; Mathew Savage; Minzhi Li; Xin Li; Sihai Yang; Xu Liang; Weihua Zhu; Hans Ågren; Yongshu Xie

doi:10.1021/acs.orglett.6b02495

Tetra- and Octapyrroles Synthesized from Confusion and Fusion Approaches

Jiahui Kong
, Qiong Zhang
, Mathew Savage
, Minzhi Li
, Xin Li
, Sihai Yang
, Xu Liang
, Weihua Zhu
, Hans Ågren
, Yongshu Xie^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

By oxidation of an alternately N-confused bilane in CH₂Cl₂, a C-N fused tetrapyrrin was synthesized that bears a 5.5.5-tricyclic ring generated from an intramolecular C-N linkage. When CH₃CN was used as the reaction medium, a multiply C-N-fused octapyrrolic dimer was also obtained that contained two 5.5.5.7.5-pentacyclic moieties and a bipyrrole unit generated from the intramolecular C-N linkage and intermolecular C-C linkage, respectively. This could be coordinated with Ni(acac)₂ to afford a mixed-ligand complex.

Original language	English
Pages (from-to)	5046-5049
Number of pages	4
Journal	Organic Letters
Volume	18
Issue number	19
DOIs	https://doi.org/10.1021/acs.orglett.6b02495
State	Published - 7 Oct 2016
Externally published	Yes

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title = "Tetra- and Octapyrroles Synthesized from Confusion and Fusion Approaches",

abstract = "By oxidation of an alternately N-confused bilane in CH2Cl2, a C-N fused tetrapyrrin was synthesized that bears a 5.5.5-tricyclic ring generated from an intramolecular C-N linkage. When CH3CN was used as the reaction medium, a multiply C-N-fused octapyrrolic dimer was also obtained that contained two 5.5.5.7.5-pentacyclic moieties and a bipyrrole unit generated from the intramolecular C-N linkage and intermolecular C-C linkage, respectively. This could be coordinated with Ni(acac)2 to afford a mixed-ligand complex.",

author = "Jiahui Kong and Qiong Zhang and Mathew Savage and Minzhi Li and Xin Li and Sihai Yang and Xu Liang and Weihua Zhu and Hans {\AA}gren and Yongshu Xie",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = oct,

day = "7",

doi = "10.1021/acs.orglett.6b02495",

language = "英语",

volume = "18",

pages = "5046--5049",

journal = "Organic Letters",

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publisher = "American Chemical Society",

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}

TY - JOUR

T1 - Tetra- and Octapyrroles Synthesized from Confusion and Fusion Approaches

AU - Kong, Jiahui

AU - Zhang, Qiong

AU - Savage, Mathew

AU - Li, Minzhi

AU - Li, Xin

AU - Yang, Sihai

AU - Liang, Xu

AU - Zhu, Weihua

AU - Ågren, Hans

AU - Xie, Yongshu

PY - 2016/10/7

Y1 - 2016/10/7

N2 - By oxidation of an alternately N-confused bilane in CH2Cl2, a C-N fused tetrapyrrin was synthesized that bears a 5.5.5-tricyclic ring generated from an intramolecular C-N linkage. When CH3CN was used as the reaction medium, a multiply C-N-fused octapyrrolic dimer was also obtained that contained two 5.5.5.7.5-pentacyclic moieties and a bipyrrole unit generated from the intramolecular C-N linkage and intermolecular C-C linkage, respectively. This could be coordinated with Ni(acac)2 to afford a mixed-ligand complex.

AB - By oxidation of an alternately N-confused bilane in CH2Cl2, a C-N fused tetrapyrrin was synthesized that bears a 5.5.5-tricyclic ring generated from an intramolecular C-N linkage. When CH3CN was used as the reaction medium, a multiply C-N-fused octapyrrolic dimer was also obtained that contained two 5.5.5.7.5-pentacyclic moieties and a bipyrrole unit generated from the intramolecular C-N linkage and intermolecular C-C linkage, respectively. This could be coordinated with Ni(acac)2 to afford a mixed-ligand complex.

UR - https://www.scopus.com/pages/publications/84990818624

U2 - 10.1021/acs.orglett.6b02495

DO - 10.1021/acs.orglett.6b02495

M3 - 文章

AN - SCOPUS:84990818624

SN - 1523-7060

VL - 18

SP - 5046

EP - 5049

JO - Organic Letters

JF - Organic Letters

IS - 19

ER -

Tetra- and Octapyrroles Synthesized from Confusion and Fusion Approaches

Abstract

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