Temperature stable, high‐quality factor li2tio3‐li4nbo4f microwave dielectric ceramics

In this work, (1‐x)Li2TiO3‐xLi4NbO4F ceramics were prepared by the conventional solid-state ceramic route. With the increase of Li4NbO4F content, the phase structure transformed from ordered monoclinic to disordered cubic. By increasing Li3NbO4F content, the temperature coeffi-cient of resonant frequency (τf) was successfully adjusted closer to zero, while the dielectric constant (εr) and microwave quality factor (Qf) decreased to some degree. Outstanding microwave dielectric properties with a εr = 18.7, Qf = 61,388 GHz (6.264 GHz), and τf = 0.9 ppm/°C were obtained for 0.9Li2TiO3‐0.1Li4NbO4F ceramics sintered at 1050 °C for 2 h, which indicated that these ceramics are suitable for practical applications in the field of microwave substrates and components.