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TEM study of SrIrO 3 thin films with various thicknesses grown on (0 0 1) SrTiO 3 substrates synthesized by pulsed laser deposition

  • Lunyong Zhang
  • , Hong Yan Wu
  • , Jian Zhou
  • , Fei Xiang Wu
  • , Y. B. Chen*
  • , Shu Hua Yao
  • , Shan Tao Zhang
  • , Yan Feng Chen
  • *Corresponding author for this work
  • Nanjing University

Research output: Contribution to journalArticlepeer-review

Abstract

The microstructure of SrIrO 3 thin films with various thicknesses is characterized by transmission electron microscopy. We observed that the SrIrO 3 thin films are formed in meta-stable orthorhombic structure and demonstrate the single-crystalline quality when the thickness is thinner than 30 nm; in contrast, SrIrO 3 thin films with thickness thicker than 30 nm are composed of both meta-stable orthorhombic and stable monoclinic SrIrO 3 phases, and show polycrystalline quality. The interfacial structure and crystalline domain structure of orthorhombic SrIrO 3 thin films are characterized. The formation of meta-stable orthorhombic SrIrO 3 thin films is discussed by strain between substrates and thin films on the basis of the Gibbs formation energy difference between monoclinic and orthorhombic SrIrO 3 phases. Stabilization of meta-stable orthorhombic SrIrO 3 with single crystalline quality provides an ideal system to elucidate the intrinsic physical property of SrIrO 3 . Crown

Original languageEnglish
Pages (from-to)282-286
Number of pages5
JournalApplied Surface Science
Volume280
DOIs
StatePublished - 1 Sep 2013
Externally publishedYes

Keywords

  • Thermodynamics
  • Thin films
  • Transmission electron microscopy

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