Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10

Hongwei Yu; Shilie Pan; Hongping Wu; Jian Han; Xiaoyu Dong; Zhongxiang Zhou

doi:10.1016/j.jssc.2011.05.007

Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K₃CdB₅O₁₀

Hongwei Yu
, Shilie Pan^*
, Hongping Wu
, Jian Han
, Xiaoyu Dong
, Zhongxiang Zhou

^*Corresponding author for this work

Xinjiang Technical Institute of Physics and Chemistry
University of Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

A new ternary borate oxide, K₃CdB₅O₁₀, has been synthesized by solid-state reaction at 580 °C. The compound crystallizes in the monoclinic space group P2₁/n with a=7.6707 (7) Å, b=19.1765 (17) Å, c=7.8784 (6) Å, β=115.6083 (49)°, and Z=4. The crystal structure consists of a two-dimensional infinite [CdB₅O₁₀] layer, which forms by connecting isolated double ring [B₅O₁₀] groups and CdO₄ tetrahedra. K atoms filling in the interlayer and intralayer link the layers together and balance charge. The IR spectrum has been studied and confirmed the presence of both BO₃ and BO₄ groups, and the UVvis-IR diffuse reflectance spectrum exhibits a band gap of about 3.4 eV. The DSC analysis proves that K₃CdB₅O₁₀ is a congruent melting compound.

Original language	English
Pages (from-to)	1644-1648
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	184
Issue number	7
DOIs	https://doi.org/10.1016/j.jssc.2011.05.007
State	Published - Jul 2011
Externally published	Yes

Keywords

Crystal structure
KCdBO
Optical property
Pentaborate
Synthesis

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10.1016/j.jssc.2011.05.007

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@article{4a2b1ace25094d9e9f8dab43f803a781,

title = "Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10",

abstract = "A new ternary borate oxide, K3CdB5O10, has been synthesized by solid-state reaction at 580 °C. The compound crystallizes in the monoclinic space group P21/n with a=7.6707 (7) {\AA}, b=19.1765 (17) {\AA}, c=7.8784 (6) {\AA}, β=115.6083 (49)°, and Z=4. The crystal structure consists of a two-dimensional infinite [CdB5O10] layer, which forms by connecting isolated double ring [B5O10] groups and CdO4 tetrahedra. K atoms filling in the interlayer and intralayer link the layers together and balance charge. The IR spectrum has been studied and confirmed the presence of both BO3 and BO4 groups, and the UVvis-IR diffuse reflectance spectrum exhibits a band gap of about 3.4 eV. The DSC analysis proves that K3CdB5O10 is a congruent melting compound.",

keywords = "Crystal structure, KCdBO, Optical property, Pentaborate, Synthesis",

author = "Hongwei Yu and Shilie Pan and Hongping Wu and Jian Han and Xiaoyu Dong and Zhongxiang Zhou",

year = "2011",

month = jul,

doi = "10.1016/j.jssc.2011.05.007",

language = "英语",

volume = "184",

pages = "1644--1648",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "7",

}

TY - JOUR

T1 - Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10

AU - Yu, Hongwei

AU - Pan, Shilie

AU - Wu, Hongping

AU - Han, Jian

AU - Dong, Xiaoyu

AU - Zhou, Zhongxiang

PY - 2011/7

Y1 - 2011/7

N2 - A new ternary borate oxide, K3CdB5O10, has been synthesized by solid-state reaction at 580 °C. The compound crystallizes in the monoclinic space group P21/n with a=7.6707 (7) Å, b=19.1765 (17) Å, c=7.8784 (6) Å, β=115.6083 (49)°, and Z=4. The crystal structure consists of a two-dimensional infinite [CdB5O10] layer, which forms by connecting isolated double ring [B5O10] groups and CdO4 tetrahedra. K atoms filling in the interlayer and intralayer link the layers together and balance charge. The IR spectrum has been studied and confirmed the presence of both BO3 and BO4 groups, and the UVvis-IR diffuse reflectance spectrum exhibits a band gap of about 3.4 eV. The DSC analysis proves that K3CdB5O10 is a congruent melting compound.

AB - A new ternary borate oxide, K3CdB5O10, has been synthesized by solid-state reaction at 580 °C. The compound crystallizes in the monoclinic space group P21/n with a=7.6707 (7) Å, b=19.1765 (17) Å, c=7.8784 (6) Å, β=115.6083 (49)°, and Z=4. The crystal structure consists of a two-dimensional infinite [CdB5O10] layer, which forms by connecting isolated double ring [B5O10] groups and CdO4 tetrahedra. K atoms filling in the interlayer and intralayer link the layers together and balance charge. The IR spectrum has been studied and confirmed the presence of both BO3 and BO4 groups, and the UVvis-IR diffuse reflectance spectrum exhibits a band gap of about 3.4 eV. The DSC analysis proves that K3CdB5O10 is a congruent melting compound.

KW - Crystal structure

KW - KCdBO

KW - Optical property

KW - Pentaborate

KW - Synthesis

UR - https://www.scopus.com/pages/publications/79959791270

U2 - 10.1016/j.jssc.2011.05.007

DO - 10.1016/j.jssc.2011.05.007

M3 - 文章

AN - SCOPUS:79959791270

SN - 0022-4596

VL - 184

SP - 1644

EP - 1648

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 7

ER -

Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K₃CdB₅O₁₀

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Keywords

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