Synthesis, structure and third-order non-linear optical properties of tungsten dioxo complex with 8-hydroxyquinoline ligand WO2 (C9H6NO)2

Yong Li; Jing Lu; Ji Qing Xu; Xiao Bing Cui; Ying Hua Sun; Ke Chang Li; Qing Xin Yang; Ling Yun Pan; Hai Ying Bie

Synthesis, structure and third-order non-linear optical properties of tungsten dioxo complex with 8-hydroxyquinoline ligand WO₂ (C₉H₆NO)₂

Yong Li
, Jing Lu
, Ji Qing Xu^*
, Xiao Bing Cui
, Ying Hua Sun
, Ke Chang Li
, Qing Xin Yang
, Ling Yun Pan
, Hai Ying Bie

^*Corresponding author for this work

School of Physics

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Tungsten dioxo complex WO₂(C₉H₆NO)₂ was obtained via the low temperature solid-state reaction of (NH₄)₂WS₄, 8-hydroxyquinoline (8-hq) and (CH_e)₄NI, and it was characterized by means of elemental analyses, IR spectroscopy and X-ray diffraction analysis. The crystal of the title compound belongs to monoclinic, space group C2/c, with the crystal cell parameters: a = 1.3316(3) nm, 6 = 0.94444(19) nm, c = l.3485(3) nm, β = 109.66(3)°, V = l.5970(6) nm³, Z = 6. The title compound possesses a supramolecular structure formed through hydrogen bonds and π-π stacking interactions. The third-order non-linear optical (NLO) properties of the title compound were also investigated. The third-order non-linear absorption coefficient α₂ and refractive index n₂ are 0.85 × 10^-11 m/W^-1 and -1.5 ×10^-19m^-2/W, respectively. The third-order nonlinear susceptibility X⁽³⁾ is 3.03 × 10^-13 esu for 3.8 × 10^-5 mol/L sample concentration.

Original language	English
Pages (from-to)	681-684
Number of pages	4
Journal	Chemical Research in Chinese Universities
Volume	20
Issue number	6
State	Published - Nov 2004

Keywords

Solid state reaction
Supramolecular structure
Third-order non-linear optical property
Tungsten dioxo complex

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@article{fa02eb1d0e6140aa94ac1b1b09e90681,

title = "Synthesis, structure and third-order non-linear optical properties of tungsten dioxo complex with 8-hydroxyquinoline ligand WO2 (C9H6NO)2",

abstract = "Tungsten dioxo complex WO2(C9H6NO)2 was obtained via the low temperature solid-state reaction of (NH4)2WS4, 8-hydroxyquinoline (8-hq) and (CHe)4NI, and it was characterized by means of elemental analyses, IR spectroscopy and X-ray diffraction analysis. The crystal of the title compound belongs to monoclinic, space group C2/c, with the crystal cell parameters: a = 1.3316(3) nm, 6 = 0.94444(19) nm, c = l.3485(3) nm, β = 109.66(3)°, V = l.5970(6) nm3, Z = 6. The title compound possesses a supramolecular structure formed through hydrogen bonds and π-π stacking interactions. The third-order non-linear optical (NLO) properties of the title compound were also investigated. The third-order non-linear absorption coefficient α2 and refractive index n2 are 0.85 × 10-11 m/W-1 and -1.5 ×10-19m-2/W, respectively. The third-order nonlinear susceptibility X(3) is 3.03 × 10-13 esu for 3.8 × 10-5 mol/L sample concentration.",

keywords = "Solid state reaction, Supramolecular structure, Third-order non-linear optical property, Tungsten dioxo complex",

author = "Yong Li and Jing Lu and Xu, \{Ji Qing\} and Cui, \{Xiao Bing\} and Sun, \{Ying Hua\} and Li, \{Ke Chang\} and Yang, \{Qing Xin\} and Pan, \{Ling Yun\} and Bie, \{Hai Ying\}",

year = "2004",

month = nov,

language = "英语",

volume = "20",

pages = "681--684",

journal = "Chemical Research in Chinese Universities",

issn = "1005-9040",

publisher = "Springer Science and Business Media Deutschland GmbH",

number = "6",

}

TY - JOUR

T1 - Synthesis, structure and third-order non-linear optical properties of tungsten dioxo complex with 8-hydroxyquinoline ligand WO2 (C9H6NO)2

AU - Li, Yong

AU - Lu, Jing

AU - Xu, Ji Qing

AU - Cui, Xiao Bing

AU - Sun, Ying Hua

AU - Li, Ke Chang

AU - Yang, Qing Xin

AU - Pan, Ling Yun

AU - Bie, Hai Ying

PY - 2004/11

Y1 - 2004/11

N2 - Tungsten dioxo complex WO2(C9H6NO)2 was obtained via the low temperature solid-state reaction of (NH4)2WS4, 8-hydroxyquinoline (8-hq) and (CHe)4NI, and it was characterized by means of elemental analyses, IR spectroscopy and X-ray diffraction analysis. The crystal of the title compound belongs to monoclinic, space group C2/c, with the crystal cell parameters: a = 1.3316(3) nm, 6 = 0.94444(19) nm, c = l.3485(3) nm, β = 109.66(3)°, V = l.5970(6) nm3, Z = 6. The title compound possesses a supramolecular structure formed through hydrogen bonds and π-π stacking interactions. The third-order non-linear optical (NLO) properties of the title compound were also investigated. The third-order non-linear absorption coefficient α2 and refractive index n2 are 0.85 × 10-11 m/W-1 and -1.5 ×10-19m-2/W, respectively. The third-order nonlinear susceptibility X(3) is 3.03 × 10-13 esu for 3.8 × 10-5 mol/L sample concentration.

AB - Tungsten dioxo complex WO2(C9H6NO)2 was obtained via the low temperature solid-state reaction of (NH4)2WS4, 8-hydroxyquinoline (8-hq) and (CHe)4NI, and it was characterized by means of elemental analyses, IR spectroscopy and X-ray diffraction analysis. The crystal of the title compound belongs to monoclinic, space group C2/c, with the crystal cell parameters: a = 1.3316(3) nm, 6 = 0.94444(19) nm, c = l.3485(3) nm, β = 109.66(3)°, V = l.5970(6) nm3, Z = 6. The title compound possesses a supramolecular structure formed through hydrogen bonds and π-π stacking interactions. The third-order non-linear optical (NLO) properties of the title compound were also investigated. The third-order non-linear absorption coefficient α2 and refractive index n2 are 0.85 × 10-11 m/W-1 and -1.5 ×10-19m-2/W, respectively. The third-order nonlinear susceptibility X(3) is 3.03 × 10-13 esu for 3.8 × 10-5 mol/L sample concentration.

KW - Solid state reaction

KW - Supramolecular structure

KW - Third-order non-linear optical property

KW - Tungsten dioxo complex

UR - https://www.scopus.com/pages/publications/13944278173

M3 - 文章

AN - SCOPUS:13944278173

SN - 1005-9040

VL - 20

SP - 681

EP - 684

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 6

ER -

Synthesis, structure and third-order non-linear optical properties of tungsten dioxo complex with 8-hydroxyquinoline ligand WO₂ (C₉H₆NO)₂

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