Synthesis, structure and properties of two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid

Yanan Luo; Xianzhu Xu; Fuxing Sun; Xiaoyang Yu; Xiao Zhang; Ting Zhang; Liying Yu

doi:10.1007/s40242-013-3236-y

Synthesis, structure and properties of two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid

Yanan Luo
, Xianzhu Xu^*
, Fuxing Sun
, Xiaoyang Yu
, Xiao Zhang
, Ting Zhang
, Liying Yu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology
Jilin Institute of Chemical Technology
Jilin University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid(H₂L), {[CdL(H₂O)₂]·H₂O}_n(1) and {[CdL(en)]·EtOH}_n(2)(en=ethylenediamine), were solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compounds 1 and 2 exhibit infinite 1D ladder-shaped chain structures, which are isostructural except that the two coordinating water molecules in compound 1 were replaced by one en molecule in compound 2 due to the use of different organic base. Compounds 1 and 2 were constructed into different supramolecular frameworks by hydrogen bonding and π...π stacking interactions. In addition, the fluorescent properties of compounds 1 and 2 were investigated. Furthermore, they were also investigated via IR spectral analysis, elemental analysis, powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA).

Original language	English
Pages (from-to)	27-31
Number of pages	5
Journal	Chemical Research in Chinese Universities
Volume	30
Issue number	1
DOIs	https://doi.org/10.1007/s40242-013-3236-y
State	Published - Feb 2014

Keywords

4-[(8-Hydroxy-5-quinolinyl)azo]-benzenesulfonic acid
Coordination polymer
Fluorescent property
Solvothermal synthesis

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@article{7af6b86ce2174d588fb2826961abb630,

title = "Synthesis, structure and properties of two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid",

abstract = "Two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid(H2L), \{[CdL(H2O)2]·H2O\}n(1) and \{[CdL(en)]·EtOH\}n(2)(en=ethylenediamine), were solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compounds 1 and 2 exhibit infinite 1D ladder-shaped chain structures, which are isostructural except that the two coordinating water molecules in compound 1 were replaced by one en molecule in compound 2 due to the use of different organic base. Compounds 1 and 2 were constructed into different supramolecular frameworks by hydrogen bonding and π...π stacking interactions. In addition, the fluorescent properties of compounds 1 and 2 were investigated. Furthermore, they were also investigated via IR spectral analysis, elemental analysis, powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA).",

keywords = "4-[(8-Hydroxy-5-quinolinyl)azo]-benzenesulfonic acid, Coordination polymer, Fluorescent property, Solvothermal synthesis",

author = "Yanan Luo and Xianzhu Xu and Fuxing Sun and Xiaoyang Yu and Xiao Zhang and Ting Zhang and Liying Yu",

year = "2014",

month = feb,

doi = "10.1007/s40242-013-3236-y",

language = "英语",

volume = "30",

pages = "27--31",

journal = "Chemical Research in Chinese Universities",

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number = "1",

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TY - JOUR

T1 - Synthesis, structure and properties of two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid

AU - Luo, Yanan

AU - Xu, Xianzhu

AU - Sun, Fuxing

AU - Yu, Xiaoyang

AU - Zhang, Xiao

AU - Zhang, Ting

AU - Yu, Liying

PY - 2014/2

Y1 - 2014/2

N2 - Two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid(H2L), {[CdL(H2O)2]·H2O}n(1) and {[CdL(en)]·EtOH}n(2)(en=ethylenediamine), were solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compounds 1 and 2 exhibit infinite 1D ladder-shaped chain structures, which are isostructural except that the two coordinating water molecules in compound 1 were replaced by one en molecule in compound 2 due to the use of different organic base. Compounds 1 and 2 were constructed into different supramolecular frameworks by hydrogen bonding and π...π stacking interactions. In addition, the fluorescent properties of compounds 1 and 2 were investigated. Furthermore, they were also investigated via IR spectral analysis, elemental analysis, powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA).

AB - Two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid(H2L), {[CdL(H2O)2]·H2O}n(1) and {[CdL(en)]·EtOH}n(2)(en=ethylenediamine), were solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compounds 1 and 2 exhibit infinite 1D ladder-shaped chain structures, which are isostructural except that the two coordinating water molecules in compound 1 were replaced by one en molecule in compound 2 due to the use of different organic base. Compounds 1 and 2 were constructed into different supramolecular frameworks by hydrogen bonding and π...π stacking interactions. In addition, the fluorescent properties of compounds 1 and 2 were investigated. Furthermore, they were also investigated via IR spectral analysis, elemental analysis, powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA).

KW - 4-[(8-Hydroxy-5-quinolinyl)azo]-benzenesulfonic acid

KW - Coordination polymer

KW - Fluorescent property

KW - Solvothermal synthesis

UR - https://www.scopus.com/pages/publications/84893284161

U2 - 10.1007/s40242-013-3236-y

DO - 10.1007/s40242-013-3236-y

M3 - 文章

AN - SCOPUS:84893284161

SN - 1005-9040

VL - 30

SP - 27

EP - 31

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 1

ER -

Synthesis, structure and properties of two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid

Abstract

Keywords

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