Synthesis, structure, and properties of the noncentrosymmetric hydrated borate Na2B5O8(OH)·2H2O

Yongjiang Wang; Shilie Pan; Xuelin Tian; Zhongxiang Zhou; Gang Liu; Jide Wang; Dianzeng Jia

doi:10.1021/ic900700u

Synthesis, structure, and properties of the noncentrosymmetric hydrated borate Na₂B₅O₈(OH)·2H₂O

Yongjiang Wang
, Shilie Pan^*
, Xuelin Tian
, Zhongxiang Zhou
, Gang Liu
, Jide Wang
, Dianzeng Jia

^*Corresponding author for this work

Xinjiang Technical Institute of Physics and Chemistry
University of Chinese Academy of Sciences
Xinjiang University

Research output: Contribution to journal › Article › peer-review

76 Scopus citations

Abstract

Single crystal of hydrated sodium borate Na₂B₅O ₈(OH)·2H₂O has been grown with sizes up to 5 × 5 × 3 mm³ under mild hydrothermal conditions at 180 °C. The structure is determined by single-crystal X-ray diffraction and further characterized by IR and TG analyses. It crystallizes in the orthorhombic space group Pna2₁ with a = 11.967(2) Å, b = 6.5320(13) Å, c = 11.126(2) Å, Z = 4, R1 = 0.0183, and wR2 = 0.0483. The crystal structure of Na₂B₅O₈(OH)·2H ₂O is made up of Na - O polyhedra, and [B₅O ₈(OH)]^2- polyborate anions. Transmittance spectrum is performed on the Na₂B₅O₈(OH)·2H ₂O crystal, which shows an absorption edge less than 190 nm in the UV region. The powder second-harmonic generation intensity measured by the Kurtz - Perry method indicates that Na₂B₅O₈-(OH) ·2H₂O is about half that of KH₂PO₄ (KDP).

Original language	English
Pages (from-to)	7800-7804
Number of pages	5
Journal	Inorganic Chemistry
Volume	48
Issue number	16
DOIs	https://doi.org/10.1021/ic900700u
State	Published - 17 Aug 2009
Externally published	Yes

Access to Document

10.1021/ic900700u

Cite this

@article{9d531717fb324aba97debba73c70cae5,

title = "Synthesis, structure, and properties of the noncentrosymmetric hydrated borate Na2B5O8(OH)·2H2O",

abstract = "Single crystal of hydrated sodium borate Na2B5O 8(OH)·2H2O has been grown with sizes up to 5 × 5 × 3 mm3 under mild hydrothermal conditions at 180 °C. The structure is determined by single-crystal X-ray diffraction and further characterized by IR and TG analyses. It crystallizes in the orthorhombic space group Pna21 with a = 11.967(2) {\AA}, b = 6.5320(13) {\AA}, c = 11.126(2) {\AA}, Z = 4, R1 = 0.0183, and wR2 = 0.0483. The crystal structure of Na2B5O8(OH)·2H 2O is made up of Na - O polyhedra, and [B5O 8(OH)]2- polyborate anions. Transmittance spectrum is performed on the Na2B5O8(OH)·2H 2O crystal, which shows an absorption edge less than 190 nm in the UV region. The powder second-harmonic generation intensity measured by the Kurtz - Perry method indicates that Na2B5O8-(OH) ·2H2O is about half that of KH2PO4 (KDP).",

author = "Yongjiang Wang and Shilie Pan and Xuelin Tian and Zhongxiang Zhou and Gang Liu and Jide Wang and Dianzeng Jia",

year = "2009",

month = aug,

day = "17",

doi = "10.1021/ic900700u",

language = "英语",

volume = "48",

pages = "7800--7804",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "16",

}

TY - JOUR

T1 - Synthesis, structure, and properties of the noncentrosymmetric hydrated borate Na2B5O8(OH)·2H2O

AU - Wang, Yongjiang

AU - Pan, Shilie

AU - Tian, Xuelin

AU - Zhou, Zhongxiang

AU - Liu, Gang

AU - Wang, Jide

AU - Jia, Dianzeng

PY - 2009/8/17

Y1 - 2009/8/17

N2 - Single crystal of hydrated sodium borate Na2B5O 8(OH)·2H2O has been grown with sizes up to 5 × 5 × 3 mm3 under mild hydrothermal conditions at 180 °C. The structure is determined by single-crystal X-ray diffraction and further characterized by IR and TG analyses. It crystallizes in the orthorhombic space group Pna21 with a = 11.967(2) Å, b = 6.5320(13) Å, c = 11.126(2) Å, Z = 4, R1 = 0.0183, and wR2 = 0.0483. The crystal structure of Na2B5O8(OH)·2H 2O is made up of Na - O polyhedra, and [B5O 8(OH)]2- polyborate anions. Transmittance spectrum is performed on the Na2B5O8(OH)·2H 2O crystal, which shows an absorption edge less than 190 nm in the UV region. The powder second-harmonic generation intensity measured by the Kurtz - Perry method indicates that Na2B5O8-(OH) ·2H2O is about half that of KH2PO4 (KDP).

AB - Single crystal of hydrated sodium borate Na2B5O 8(OH)·2H2O has been grown with sizes up to 5 × 5 × 3 mm3 under mild hydrothermal conditions at 180 °C. The structure is determined by single-crystal X-ray diffraction and further characterized by IR and TG analyses. It crystallizes in the orthorhombic space group Pna21 with a = 11.967(2) Å, b = 6.5320(13) Å, c = 11.126(2) Å, Z = 4, R1 = 0.0183, and wR2 = 0.0483. The crystal structure of Na2B5O8(OH)·2H 2O is made up of Na - O polyhedra, and [B5O 8(OH)]2- polyborate anions. Transmittance spectrum is performed on the Na2B5O8(OH)·2H 2O crystal, which shows an absorption edge less than 190 nm in the UV region. The powder second-harmonic generation intensity measured by the Kurtz - Perry method indicates that Na2B5O8-(OH) ·2H2O is about half that of KH2PO4 (KDP).

UR - https://www.scopus.com/pages/publications/68949161565

U2 - 10.1021/ic900700u

DO - 10.1021/ic900700u

M3 - 文章

AN - SCOPUS:68949161565

SN - 0020-1669

VL - 48

SP - 7800

EP - 7804

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 16

ER -

Synthesis, structure, and properties of the noncentrosymmetric hydrated borate Na₂B₅O₈(OH)·2H₂O

Abstract

Access to Document

Other files and links

Fingerprint

Cite this