Synthesis, structure, and properties of a novel hydrated borate Rb 4[B4O5(OH)4]2· 3H2O

Yi Zhao; Shilie Pan; Feng Li; Yongjiang Wang; Xiaoyun Fan; Xiaoyu Dong; Dianzeng Jia; Jixi Guo; Zhongxiang Zhou

doi:10.1016/j.solidstatesciences.2010.10.013

Synthesis, structure, and properties of a novel hydrated borate Rb ₄[B₄O₅(OH)₄]₂· 3H₂O

Yi Zhao
, Shilie Pan^*
, Feng Li
, Yongjiang Wang
, Xiaoyun Fan
, Xiaoyu Dong
, Dianzeng Jia
, Jixi Guo
, Zhongxiang Zhou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Rb₄[B₄O₅(OH)₄] ₂·3H₂O has been grown by slow evaporation method with crystal sizes up to 11 mm × 7 mm × 4 mm. Its crystal structure has been determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (XRD), IR, and TGA. It crystallizes in the orthorhombic space group Pbcn, with a = 16.3984(14) , b = 7.7850(7) , c = 16.0763(16) , and Z = 4. It contains isolated [B₄O ₅(OH)₄]^2- polyanions, free water molecules and Rb cations. The Rb(1) and Rb(2) atoms are coordinated by nine and ten oxygen atoms, respectively. Connections between isolated [B₄O ₅(OH)₄]^2- polyanions are provided by Rb polyhedra and the hydrogen-bonding to form a three-dimensional network.

Original language	English
Pages (from-to)	82-87
Number of pages	6
Journal	Solid State Sciences
Volume	13
Issue number	1
DOIs	https://doi.org/10.1016/j.solidstatesciences.2010.10.013
State	Published - Jan 2011
Externally published	Yes

Keywords

Borate
Crystal growth
Crystal structure
Rb[BO(OH)] ·3HO

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10.1016/j.solidstatesciences.2010.10.013

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@article{e055f1073d1d488eaa8aaa936cc9e429,

title = "Synthesis, structure, and properties of a novel hydrated borate Rb 4[B4O5(OH)4]2· 3H2O",

abstract = "Rb4[B4O5(OH)4] 2·3H2O has been grown by slow evaporation method with crystal sizes up to 11 mm × 7 mm × 4 mm. Its crystal structure has been determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (XRD), IR, and TGA. It crystallizes in the orthorhombic space group Pbcn, with a = 16.3984(14) , b = 7.7850(7) , c = 16.0763(16) , and Z = 4. It contains isolated [B4O 5(OH)4]2- polyanions, free water molecules and Rb cations. The Rb(1) and Rb(2) atoms are coordinated by nine and ten oxygen atoms, respectively. Connections between isolated [B4O 5(OH)4]2- polyanions are provided by Rb polyhedra and the hydrogen-bonding to form a three-dimensional network.",

keywords = "Borate, Crystal growth, Crystal structure, Rb[BO(OH)] ·3HO",

author = "Yi Zhao and Shilie Pan and Feng Li and Yongjiang Wang and Xiaoyun Fan and Xiaoyu Dong and Dianzeng Jia and Jixi Guo and Zhongxiang Zhou",

year = "2011",

month = jan,

doi = "10.1016/j.solidstatesciences.2010.10.013",

language = "英语",

volume = "13",

pages = "82--87",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson s.r.l.",

number = "1",

}

TY - JOUR

T1 - Synthesis, structure, and properties of a novel hydrated borate Rb 4[B4O5(OH)4]2· 3H2O

AU - Zhao, Yi

AU - Pan, Shilie

AU - Li, Feng

AU - Wang, Yongjiang

AU - Fan, Xiaoyun

AU - Dong, Xiaoyu

AU - Jia, Dianzeng

AU - Guo, Jixi

AU - Zhou, Zhongxiang

PY - 2011/1

Y1 - 2011/1

N2 - Rb4[B4O5(OH)4] 2·3H2O has been grown by slow evaporation method with crystal sizes up to 11 mm × 7 mm × 4 mm. Its crystal structure has been determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (XRD), IR, and TGA. It crystallizes in the orthorhombic space group Pbcn, with a = 16.3984(14) , b = 7.7850(7) , c = 16.0763(16) , and Z = 4. It contains isolated [B4O 5(OH)4]2- polyanions, free water molecules and Rb cations. The Rb(1) and Rb(2) atoms are coordinated by nine and ten oxygen atoms, respectively. Connections between isolated [B4O 5(OH)4]2- polyanions are provided by Rb polyhedra and the hydrogen-bonding to form a three-dimensional network.

AB - Rb4[B4O5(OH)4] 2·3H2O has been grown by slow evaporation method with crystal sizes up to 11 mm × 7 mm × 4 mm. Its crystal structure has been determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (XRD), IR, and TGA. It crystallizes in the orthorhombic space group Pbcn, with a = 16.3984(14) , b = 7.7850(7) , c = 16.0763(16) , and Z = 4. It contains isolated [B4O 5(OH)4]2- polyanions, free water molecules and Rb cations. The Rb(1) and Rb(2) atoms are coordinated by nine and ten oxygen atoms, respectively. Connections between isolated [B4O 5(OH)4]2- polyanions are provided by Rb polyhedra and the hydrogen-bonding to form a three-dimensional network.

KW - Borate

KW - Crystal growth

KW - Crystal structure

KW - Rb[BO(OH)] ·3HO

UR - https://www.scopus.com/pages/publications/78650596382

U2 - 10.1016/j.solidstatesciences.2010.10.013

DO - 10.1016/j.solidstatesciences.2010.10.013

M3 - 文章

AN - SCOPUS:78650596382

SN - 1293-2558

VL - 13

SP - 82

EP - 87

JO - Solid State Sciences

JF - Solid State Sciences

IS - 1

ER -

Synthesis, structure, and properties of a novel hydrated borate Rb ₄[B₄O₅(OH)₄]₂· 3H₂O

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Keywords

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