Synthesis, Structure and Nonlinear Optical Properties of Layered Coordination Polymer Pb(NCS) 2(bpea) n(bpea = 1,2-bis(4-pyridyl)ethane)

Yun Yin Niu; Hong Wei Hou; Feng Li; He Gen Zheng; Ying Lin Song; Hoong Kun Fun; Xin Quan Xin

Synthesis, Structure and Nonlinear Optical Properties of Layered Coordination Polymer Pb(NCS) ₂(bpea) _n(bpea = 1,2-bis(4-pyridyl)ethane)

Yun Yin Niu
, Hong Wei Hou
, Feng Li
, He Gen Zheng
, Ying Lin Song
, Hoong Kun Fun
, Xin Quan Xin

School of Physics

Nanjing University
Zhengzhou University
Universiti Sains Malaysia

Research output: Contribution to journal › Article › peer-review

Abstract

Under room temperature reaction of Pb(OAc) ₂ · 3 H ₂O with KNCS, 1, 2-bis(4-pyridyl)ethane in CH ₃OH afforded a novel layered coordinated polymer [Pb(NCS) ₂(bpea)] _n sustained by eight-numbered ring units. Investigation of third-order optical nonlinearity Z-Scan shows that it exhibit considerably nonlinear refractive properties with α ₂ values of 1. 1 × 10 ^-11m · W ^-1 and n ₂ values of 6. 055 × 10 ^-18m ² · W ^-1 respectively.

Original language	English
Pages (from-to)	x13-537
Journal	Chinese Journal of Inorganic Chemistry
Volume	17
Issue number	4
State	Published - 2001

Keywords

Coordination polymer
Lead adduct
Nonlinear optical properties
Z-scan

Cite this

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title = "Synthesis, Structure and Nonlinear Optical Properties of Layered Coordination Polymer Pb(NCS) 2(bpea) n(bpea = 1,2-bis(4-pyridyl)ethane)",

abstract = "Under room temperature reaction of Pb(OAc) 2 · 3 H 2O with KNCS, 1, 2-bis(4-pyridyl)ethane in CH 3OH afforded a novel layered coordinated polymer [Pb(NCS) 2(bpea)] n sustained by eight-numbered ring units. Investigation of third-order optical nonlinearity Z-Scan shows that it exhibit considerably nonlinear refractive properties with α 2 values of 1. 1 {\texttimes} 10 -11m · W -1 and n 2 values of 6. 055 {\texttimes} 10 -18m 2 · W -1 respectively.",

keywords = "Coordination polymer, Lead adduct, Nonlinear optical properties, Z-scan",

author = "Niu, \{Yun Yin\} and Hou, \{Hong Wei\} and Feng Li and Zheng, \{He Gen\} and Song, \{Ying Lin\} and Fun, \{Hoong Kun\} and Xin, \{Xin Quan\}",

year = "2001",

language = "英语",

volume = "17",

pages = "x13--537",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "4",

}

TY - JOUR

T1 - Synthesis, Structure and Nonlinear Optical Properties of Layered Coordination Polymer Pb(NCS) 2(bpea) n(bpea = 1,2-bis(4-pyridyl)ethane)

AU - Niu, Yun Yin

AU - Hou, Hong Wei

AU - Li, Feng

AU - Zheng, He Gen

AU - Song, Ying Lin

AU - Fun, Hoong Kun

AU - Xin, Xin Quan

PY - 2001

Y1 - 2001

N2 - Under room temperature reaction of Pb(OAc) 2 · 3 H 2O with KNCS, 1, 2-bis(4-pyridyl)ethane in CH 3OH afforded a novel layered coordinated polymer [Pb(NCS) 2(bpea)] n sustained by eight-numbered ring units. Investigation of third-order optical nonlinearity Z-Scan shows that it exhibit considerably nonlinear refractive properties with α 2 values of 1. 1 × 10 -11m · W -1 and n 2 values of 6. 055 × 10 -18m 2 · W -1 respectively.

AB - Under room temperature reaction of Pb(OAc) 2 · 3 H 2O with KNCS, 1, 2-bis(4-pyridyl)ethane in CH 3OH afforded a novel layered coordinated polymer [Pb(NCS) 2(bpea)] n sustained by eight-numbered ring units. Investigation of third-order optical nonlinearity Z-Scan shows that it exhibit considerably nonlinear refractive properties with α 2 values of 1. 1 × 10 -11m · W -1 and n 2 values of 6. 055 × 10 -18m 2 · W -1 respectively.

KW - Coordination polymer

KW - Lead adduct

KW - Nonlinear optical properties

KW - Z-scan

UR - https://www.scopus.com/pages/publications/0346487473

M3 - 文章

AN - SCOPUS:0346487473

SN - 1001-4861

VL - 17

SP - x13-537

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 4

ER -

Synthesis, Structure and Nonlinear Optical Properties of Layered Coordination Polymer Pb(NCS) ₂(bpea) _n(bpea = 1,2-bis(4-pyridyl)ethane)

Abstract

Keywords

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