Synthesis, structure and nonlinear optical properties of a novel cluster compound containing 1,1′-bis(diphenylphosphino)ferrocene(dppf)

Ya Cai; Yinglin Song; Hegen Zheng; Yunyin Niu; Chenxia Du; Xinquan Xin

doi:10.1246/cl.2002.508

Synthesis, structure and nonlinear optical properties of a novel cluster compound containing 1,1′-bis(diphenylphosphino)ferrocene(dppf)

Ya Cai
, Yinglin Song
, Hegen Zheng^*
, Yunyin Niu
, Chenxia Du
, Xinquan Xin

^*Corresponding author for this work

School of Physics

Nanjing University
Zhengzhou University

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

A novel cluster WCu₂S₄(dppf)₂·4DMF was synthesized by the reaction of (NH₄)₂WS₄ with CuCl and 1,1′-bis(diphenylphosphino)ferrocene (dppf) in the solid state, and its crystal structure has been characterized by X-ray diffraction. The cluster has a novel new skeletal structure with five metal atoms nearly in a line. Investigation of third-order optical nonlinear z-scan shows that it exhibits good nonlinear optical properties in a 1.2×10^-4 mol·dm^-3 DMF solution.

Original language	English
Pages (from-to)	508-509
Number of pages	2
Journal	Chemistry Letters
Issue number	5
DOIs	https://doi.org/10.1246/cl.2002.508
State	Published - 5 May 2002

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title = "Synthesis, structure and nonlinear optical properties of a novel cluster compound containing 1,1′-bis(diphenylphosphino)ferrocene(dppf)",

abstract = "A novel cluster WCu2S4(dppf)2·4DMF was synthesized by the reaction of (NH4)2WS4 with CuCl and 1,1′-bis(diphenylphosphino)ferrocene (dppf) in the solid state, and its crystal structure has been characterized by X-ray diffraction. The cluster has a novel new skeletal structure with five metal atoms nearly in a line. Investigation of third-order optical nonlinear z-scan shows that it exhibits good nonlinear optical properties in a 1.2×10-4 mol·dm-3 DMF solution.",

author = "Ya Cai and Yinglin Song and Hegen Zheng and Yunyin Niu and Chenxia Du and Xinquan Xin",

year = "2002",

month = may,

day = "5",

doi = "10.1246/cl.2002.508",

language = "英语",

pages = "508--509",

journal = "Chemistry Letters",

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publisher = "Oxford University Press",

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T1 - Synthesis, structure and nonlinear optical properties of a novel cluster compound containing 1,1′-bis(diphenylphosphino)ferrocene(dppf)

AU - Cai, Ya

AU - Song, Yinglin

AU - Zheng, Hegen

AU - Niu, Yunyin

AU - Du, Chenxia

AU - Xin, Xinquan

PY - 2002/5/5

Y1 - 2002/5/5

N2 - A novel cluster WCu2S4(dppf)2·4DMF was synthesized by the reaction of (NH4)2WS4 with CuCl and 1,1′-bis(diphenylphosphino)ferrocene (dppf) in the solid state, and its crystal structure has been characterized by X-ray diffraction. The cluster has a novel new skeletal structure with five metal atoms nearly in a line. Investigation of third-order optical nonlinear z-scan shows that it exhibits good nonlinear optical properties in a 1.2×10-4 mol·dm-3 DMF solution.

AB - A novel cluster WCu2S4(dppf)2·4DMF was synthesized by the reaction of (NH4)2WS4 with CuCl and 1,1′-bis(diphenylphosphino)ferrocene (dppf) in the solid state, and its crystal structure has been characterized by X-ray diffraction. The cluster has a novel new skeletal structure with five metal atoms nearly in a line. Investigation of third-order optical nonlinear z-scan shows that it exhibits good nonlinear optical properties in a 1.2×10-4 mol·dm-3 DMF solution.

UR - https://www.scopus.com/pages/publications/0036307287

U2 - 10.1246/cl.2002.508

DO - 10.1246/cl.2002.508

M3 - 文章

AN - SCOPUS:0036307287

SN - 0366-7022

SP - 508

EP - 509

JO - Chemistry Letters

JF - Chemistry Letters

IS - 5

ER -

Synthesis, structure and nonlinear optical properties of a novel cluster compound containing 1,1′-bis(diphenylphosphino)ferrocene(dppf)

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