Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound

Hai Ying Bie; Jie Hui Yu; Ji Qing Xu; Jing Lu; Yong Li; Xiao Bing Cui; Xiao Zhang; Ying Hua Sun; Ling Yun Pan

doi:10.1016/j.molstruc.2003.08.011

Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound

Hai Ying Bie
, Jie Hui Yu
, Ji Qing Xu^*
, Jing Lu
, Yong Li
, Xiao Bing Cui
, Xiao Zhang
, Ying Hua Sun
, Ling Yun Pan

^*Corresponding author for this work

College of Chemistry
Chinese Academy of Sciences
College of Physics

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

A novel copper(II) thiocyanate complex [Cu(im)₂(NCS) ₂] 1(im = imidazole) has been prepared and characterized by spectroscopic analysis and crystallographic method. This supramolecular compound exhibits a three-dimensional solid state structure constituted by N-H‰S hydrogen bonds and π-π stacking interactions. The compound in DMF solutions has a very strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α₂ = 1.18 × 10^-11 m × w^-1, n₂ = - 9.00 × 10^-16 m² w^-1, respectively, and third-order NLO susceptibility χ⁽³⁾ of 7.00 × 10 ^-10 esu.

Original language	English
Pages (from-to)	107-112
Number of pages	6
Journal	Journal of Molecular Structure
Volume	660
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2003.08.011
State	Published - 12 Nov 2003
Externally published	Yes

Keywords

Copper(II) thiocyanate complex
Hydrogen bond
Supramolecular compound
Third-order non-linear optical behavior

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10.1016/j.molstruc.2003.08.011

Cite this

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title = "Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound",

abstract = "A novel copper(II) thiocyanate complex [Cu(im)2(NCS) 2] 1(im = imidazole) has been prepared and characterized by spectroscopic analysis and crystallographic method. This supramolecular compound exhibits a three-dimensional solid state structure constituted by N-H‰S hydrogen bonds and π-π stacking interactions. The compound in DMF solutions has a very strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α2 = 1.18 × 10-11 m × w-1, n2 = - 9.00 × 10-16 m2 w-1, respectively, and third-order NLO susceptibility χ(3) of 7.00 × 10 -10 esu.",

keywords = "Copper(II) thiocyanate complex, Hydrogen bond, Supramolecular compound, Third-order non-linear optical behavior",

author = "Bie, \{Hai Ying\} and Yu, \{Jie Hui\} and Xu, \{Ji Qing\} and Jing Lu and Yong Li and Cui, \{Xiao Bing\} and Xiao Zhang and Sun, \{Ying Hua\} and Pan, \{Ling Yun\}",

year = "2003",

month = nov,

day = "12",

doi = "10.1016/j.molstruc.2003.08.011",

language = "英语",

volume = "660",

pages = "107--112",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound

AU - Bie, Hai Ying

AU - Yu, Jie Hui

AU - Xu, Ji Qing

AU - Lu, Jing

AU - Li, Yong

AU - Cui, Xiao Bing

AU - Zhang, Xiao

AU - Sun, Ying Hua

AU - Pan, Ling Yun

PY - 2003/11/12

Y1 - 2003/11/12

N2 - A novel copper(II) thiocyanate complex [Cu(im)2(NCS) 2] 1(im = imidazole) has been prepared and characterized by spectroscopic analysis and crystallographic method. This supramolecular compound exhibits a three-dimensional solid state structure constituted by N-H‰S hydrogen bonds and π-π stacking interactions. The compound in DMF solutions has a very strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α2 = 1.18 × 10-11 m × w-1, n2 = - 9.00 × 10-16 m2 w-1, respectively, and third-order NLO susceptibility χ(3) of 7.00 × 10 -10 esu.

AB - A novel copper(II) thiocyanate complex [Cu(im)2(NCS) 2] 1(im = imidazole) has been prepared and characterized by spectroscopic analysis and crystallographic method. This supramolecular compound exhibits a three-dimensional solid state structure constituted by N-H‰S hydrogen bonds and π-π stacking interactions. The compound in DMF solutions has a very strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α2 = 1.18 × 10-11 m × w-1, n2 = - 9.00 × 10-16 m2 w-1, respectively, and third-order NLO susceptibility χ(3) of 7.00 × 10 -10 esu.

KW - Copper(II) thiocyanate complex

KW - Hydrogen bond

KW - Supramolecular compound

KW - Third-order non-linear optical behavior

UR - https://www.scopus.com/pages/publications/0142245642

U2 - 10.1016/j.molstruc.2003.08.011

DO - 10.1016/j.molstruc.2003.08.011

M3 - 文章

AN - SCOPUS:0142245642

SN - 0022-2860

VL - 660

SP - 107

EP - 112

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound

Abstract

Keywords

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