Synthesis, structure and non-linear optical properties of a copper(II) ethyl bisulfate two-dimensional supramolecular compound [Cu(Him) 4(CH3CH2OSO3H)2]

Y. Li; J. Lu; X. B. Cui; J. Q. Xu; Y. H. Sun; L. Y. Pan; H. Y. Bie; X. Zhang

Synthesis, structure and non-linear optical properties of a copper(II) ethyl bisulfate two-dimensional supramolecular compound [Cu(Him) ₄(CH₃CH₂OSO₃H)₂]

Y. Li
, J. Lu
, X. B. Cui
, J. Q. Xu^*
, Y. H. Sun
, L. Y. Pan
, H. Y. Bie
, X. Zhang

^*Corresponding author for this work

College of Chemistry
CAS - Fujian Institute of Research on the Structure of Matter
College of Physics

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A novel copper(II) ethyl bisulfate complex [Cu(Him)₄(Eb) ₂] 1 (Him = imidazole, Eb = ethyl bisulfate) has been prepared and characterized by means of elemental analysis, IR and ESR. The structure was determined by single crystal X-ray diffraction analysis, which suggests that compound 1 exhibits a two-dimensional supramolecular structure through hydrogen bonds. Compound 1 displays strong third-order non-linear optical (NLO) absorption and refraction with absorption coefficient α₂ 1.10×10^-11 m·w^-1 and refractive index n ₂-5.60×10^-16 m²·w^-1. The third-order non-linear optical susceptibility χ⁽³⁾ of compound 1 is 3.07×10^-10 esu.

Original language	English
Pages (from-to)	779-787
Number of pages	9
Journal	Polish Journal of Chemistry
Volume	78
Issue number	6
State	Published - Jun 2004
Externally published	Yes

Keywords

Copper(II) ethyl bisulfate compound
Hydrogen bond
Supramolecular structure
Third-order non-linear optical property

Cite this

@article{b6696bbf303b4a15981e747f52eae942,

title = "Synthesis, structure and non-linear optical properties of a copper(II) ethyl bisulfate two-dimensional supramolecular compound [Cu(Him) 4(CH3CH2OSO3H)2]",

abstract = "A novel copper(II) ethyl bisulfate complex [Cu(Him)4(Eb) 2] 1 (Him = imidazole, Eb = ethyl bisulfate) has been prepared and characterized by means of elemental analysis, IR and ESR. The structure was determined by single crystal X-ray diffraction analysis, which suggests that compound 1 exhibits a two-dimensional supramolecular structure through hydrogen bonds. Compound 1 displays strong third-order non-linear optical (NLO) absorption and refraction with absorption coefficient α2 1.10×10-11 m·w-1 and refractive index n 2-5.60×10-16 m2·w-1. The third-order non-linear optical susceptibility χ(3) of compound 1 is 3.07×10-10 esu.",

keywords = "Copper(II) ethyl bisulfate compound, Hydrogen bond, Supramolecular structure, Third-order non-linear optical property",

author = "Y. Li and J. Lu and Cui, \{X. B.\} and Xu, \{J. Q.\} and Sun, \{Y. H.\} and Pan, \{L. Y.\} and Bie, \{H. Y.\} and X. Zhang",

year = "2004",

month = jun,

language = "英语",

volume = "78",

pages = "779--787",

journal = "Polish Journal of Chemistry",

issn = "0137-5083",

publisher = "Polish Chemical Society",

number = "6",

}

TY - JOUR

T1 - Synthesis, structure and non-linear optical properties of a copper(II) ethyl bisulfate two-dimensional supramolecular compound [Cu(Him) 4(CH3CH2OSO3H)2]

AU - Li, Y.

AU - Lu, J.

AU - Cui, X. B.

AU - Xu, J. Q.

AU - Sun, Y. H.

AU - Pan, L. Y.

AU - Bie, H. Y.

AU - Zhang, X.

PY - 2004/6

Y1 - 2004/6

N2 - A novel copper(II) ethyl bisulfate complex [Cu(Him)4(Eb) 2] 1 (Him = imidazole, Eb = ethyl bisulfate) has been prepared and characterized by means of elemental analysis, IR and ESR. The structure was determined by single crystal X-ray diffraction analysis, which suggests that compound 1 exhibits a two-dimensional supramolecular structure through hydrogen bonds. Compound 1 displays strong third-order non-linear optical (NLO) absorption and refraction with absorption coefficient α2 1.10×10-11 m·w-1 and refractive index n 2-5.60×10-16 m2·w-1. The third-order non-linear optical susceptibility χ(3) of compound 1 is 3.07×10-10 esu.

AB - A novel copper(II) ethyl bisulfate complex [Cu(Him)4(Eb) 2] 1 (Him = imidazole, Eb = ethyl bisulfate) has been prepared and characterized by means of elemental analysis, IR and ESR. The structure was determined by single crystal X-ray diffraction analysis, which suggests that compound 1 exhibits a two-dimensional supramolecular structure through hydrogen bonds. Compound 1 displays strong third-order non-linear optical (NLO) absorption and refraction with absorption coefficient α2 1.10×10-11 m·w-1 and refractive index n 2-5.60×10-16 m2·w-1. The third-order non-linear optical susceptibility χ(3) of compound 1 is 3.07×10-10 esu.

KW - Copper(II) ethyl bisulfate compound

KW - Hydrogen bond

KW - Supramolecular structure

KW - Third-order non-linear optical property

UR - https://www.scopus.com/pages/publications/3142776213

M3 - 文章

AN - SCOPUS:3142776213

SN - 0137-5083

VL - 78

SP - 779

EP - 787

JO - Polish Journal of Chemistry

JF - Polish Journal of Chemistry

IS - 6

ER -

Synthesis, structure and non-linear optical properties of a copper(II) ethyl bisulfate two-dimensional supramolecular compound [Cu(Him) ₄(CH₃CH₂OSO₃H)₂]

Abstract

Keywords

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