Synthesis, structure and fluorescent property of coordination polymer from 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid

Ya nan Luo; Xian zhu Xu; Xiao Zhang; Xiao yang Yu; Xiao shu Qu; Yan yan Yang; Qi hui Shen

doi:10.1007/s40242-013-3100-0

Synthesis, structure and fluorescent property of coordination polymer from 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid

Ya nan Luo
, Xian zhu Xu^*
, Xiao Zhang
, Xiao yang Yu
, Xiao shu Qu
, Yan yan Yang
, Qi hui Shen

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology
Jilin Institute of Chemical Technology

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

One new coordination polymer based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid(H₂L), {[CdL(H₂O)]·H₂O}n (1) was solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared spectrometry, elemental analysis, powder X-ray diffraction(PXRD) and thermogravimetric analysis (TGA). In compound 1, L^2- ligands link Cd(II) to form a sinusoidal ruffling layer, in which the carboxylic groups connect Cd(II) into an infinite Cd-O chain. And the layers are further stabilized by hydrogen bonding and π...π interactions, forming a three-dimensional(3D) supramolecular network. In addition, the fluorescent property of compound 1 was also investigated.

Original language	English
Pages (from-to)	1045-1049
Number of pages	5
Journal	Chemical Research in Chinese Universities
Volume	29
Issue number	6
DOIs	https://doi.org/10.1007/s40242-013-3100-0
State	Published - Dec 2013

Keywords

4-[(8-Hydroxy-5-quinolinyl)azo]-benzoic acid
Fluorescent property
Three-dimensional supramolecular network

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10.1007/s40242-013-3100-0

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title = "Synthesis, structure and fluorescent property of coordination polymer from 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid",

abstract = "One new coordination polymer based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid(H2L), \{[CdL(H2O)]·H2O\}n (1) was solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared spectrometry, elemental analysis, powder X-ray diffraction(PXRD) and thermogravimetric analysis (TGA). In compound 1, L2- ligands link Cd(II) to form a sinusoidal ruffling layer, in which the carboxylic groups connect Cd(II) into an infinite Cd-O chain. And the layers are further stabilized by hydrogen bonding and π...π interactions, forming a three-dimensional(3D) supramolecular network. In addition, the fluorescent property of compound 1 was also investigated.",

keywords = "4-[(8-Hydroxy-5-quinolinyl)azo]-benzoic acid, Fluorescent property, Three-dimensional supramolecular network",

author = "Luo, \{Ya nan\} and Xu, \{Xian zhu\} and Xiao Zhang and Yu, \{Xiao yang\} and Qu, \{Xiao shu\} and Yang, \{Yan yan\} and Shen, \{Qi hui\}",

year = "2013",

month = dec,

doi = "10.1007/s40242-013-3100-0",

language = "英语",

volume = "29",

pages = "1045--1049",

journal = "Chemical Research in Chinese Universities",

issn = "1005-9040",

publisher = "Springer Science and Business Media Deutschland GmbH",

number = "6",

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TY - JOUR

T1 - Synthesis, structure and fluorescent property of coordination polymer from 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid

AU - Luo, Ya nan

AU - Xu, Xian zhu

AU - Zhang, Xiao

AU - Yu, Xiao yang

AU - Qu, Xiao shu

AU - Yang, Yan yan

AU - Shen, Qi hui

PY - 2013/12

Y1 - 2013/12

N2 - One new coordination polymer based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid(H2L), {[CdL(H2O)]·H2O}n (1) was solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared spectrometry, elemental analysis, powder X-ray diffraction(PXRD) and thermogravimetric analysis (TGA). In compound 1, L2- ligands link Cd(II) to form a sinusoidal ruffling layer, in which the carboxylic groups connect Cd(II) into an infinite Cd-O chain. And the layers are further stabilized by hydrogen bonding and π...π interactions, forming a three-dimensional(3D) supramolecular network. In addition, the fluorescent property of compound 1 was also investigated.

AB - One new coordination polymer based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid(H2L), {[CdL(H2O)]·H2O}n (1) was solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared spectrometry, elemental analysis, powder X-ray diffraction(PXRD) and thermogravimetric analysis (TGA). In compound 1, L2- ligands link Cd(II) to form a sinusoidal ruffling layer, in which the carboxylic groups connect Cd(II) into an infinite Cd-O chain. And the layers are further stabilized by hydrogen bonding and π...π interactions, forming a three-dimensional(3D) supramolecular network. In addition, the fluorescent property of compound 1 was also investigated.

KW - 4-[(8-Hydroxy-5-quinolinyl)azo]-benzoic acid

KW - Fluorescent property

KW - Three-dimensional supramolecular network

UR - https://www.scopus.com/pages/publications/84891501641

U2 - 10.1007/s40242-013-3100-0

DO - 10.1007/s40242-013-3100-0

M3 - 文章

AN - SCOPUS:84891501641

SN - 1005-9040

VL - 29

SP - 1045

EP - 1049

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 6

ER -

Synthesis, structure and fluorescent property of coordination polymer from 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid

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Keywords

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