Synthesis of CuO by Cu-CPPs with the determination of Cu(II) coordination modes from a novel complex of [Cu(terpyOH)2]·(HBTC) ·2H2O

Yu Wang; Gang Chen; Li Han; Jian Pei

doi:10.1016/j.jssc.2013.08.023

Synthesis of CuO by Cu-CPPs with the determination of Cu(II) coordination modes from a novel complex of [Cu(terpyOH)₂]·(HBTC) ·2H₂O

Yu Wang^*
, Gang Chen
, Li Han
, Jian Pei

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

In this study, we investigated the synthesis of CuO microrods by simple calcination of copper-based coordination polymer particles (Cu-CPPs) at high temperature in air. The photocatalytic activity of the CuO microrods was tested by the decomposition of aqueous solution of RhB, which was completely decomposed by irradiation with light. To analyze the relationship of metal ions and ligands in the Cu-CPPs, the single crystal of [Cu(terpyOH)₂] ·(HBTC)·2H₂O (1) (terpyOH=4′-hydroxy-2,2′: 6′,2″-terpyridine, BTC=1,3,5-benzene tricarboxylate) was first prepared and characterized by X-ray single crystal structural analysis. A variety of hydrogen bonds constructing the 3D complex structure in [Cu(terpyOH)₂]·(HBTC)·2H₂O (1) were observed.

Original language	English
Pages (from-to)	251-256
Number of pages	6
Journal	Journal of Solid State Chemistry
Volume	206
DOIs	https://doi.org/10.1016/j.jssc.2013.08.023
State	Published - 2013

Keywords

Copper oxide
Crystal structure
Degradation performance
Magnetism
Photocatalytic activity

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10.1016/j.jssc.2013.08.023

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@article{35f27dba4d63429e9156ab74fe34b3da,

title = "Synthesis of CuO by Cu-CPPs with the determination of Cu(II) coordination modes from a novel complex of [Cu(terpyOH)2]·(HBTC) ·2H2O",

abstract = "In this study, we investigated the synthesis of CuO microrods by simple calcination of copper-based coordination polymer particles (Cu-CPPs) at high temperature in air. The photocatalytic activity of the CuO microrods was tested by the decomposition of aqueous solution of RhB, which was completely decomposed by irradiation with light. To analyze the relationship of metal ions and ligands in the Cu-CPPs, the single crystal of [Cu(terpyOH)2] ·(HBTC)·2H2O (1) (terpyOH=4′-hydroxy-2,2′: 6′,2″-terpyridine, BTC=1,3,5-benzene tricarboxylate) was first prepared and characterized by X-ray single crystal structural analysis. A variety of hydrogen bonds constructing the 3D complex structure in [Cu(terpyOH)2]·(HBTC)·2H2O (1) were observed.",

keywords = "Copper oxide, Crystal structure, Degradation performance, Magnetism, Photocatalytic activity",

author = "Yu Wang and Gang Chen and Li Han and Jian Pei",

year = "2013",

doi = "10.1016/j.jssc.2013.08.023",

language = "英语",

volume = "206",

pages = "251--256",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - Synthesis of CuO by Cu-CPPs with the determination of Cu(II) coordination modes from a novel complex of [Cu(terpyOH)2]·(HBTC) ·2H2O

AU - Wang, Yu

AU - Chen, Gang

AU - Han, Li

AU - Pei, Jian

PY - 2013

Y1 - 2013

N2 - In this study, we investigated the synthesis of CuO microrods by simple calcination of copper-based coordination polymer particles (Cu-CPPs) at high temperature in air. The photocatalytic activity of the CuO microrods was tested by the decomposition of aqueous solution of RhB, which was completely decomposed by irradiation with light. To analyze the relationship of metal ions and ligands in the Cu-CPPs, the single crystal of [Cu(terpyOH)2] ·(HBTC)·2H2O (1) (terpyOH=4′-hydroxy-2,2′: 6′,2″-terpyridine, BTC=1,3,5-benzene tricarboxylate) was first prepared and characterized by X-ray single crystal structural analysis. A variety of hydrogen bonds constructing the 3D complex structure in [Cu(terpyOH)2]·(HBTC)·2H2O (1) were observed.

AB - In this study, we investigated the synthesis of CuO microrods by simple calcination of copper-based coordination polymer particles (Cu-CPPs) at high temperature in air. The photocatalytic activity of the CuO microrods was tested by the decomposition of aqueous solution of RhB, which was completely decomposed by irradiation with light. To analyze the relationship of metal ions and ligands in the Cu-CPPs, the single crystal of [Cu(terpyOH)2] ·(HBTC)·2H2O (1) (terpyOH=4′-hydroxy-2,2′: 6′,2″-terpyridine, BTC=1,3,5-benzene tricarboxylate) was first prepared and characterized by X-ray single crystal structural analysis. A variety of hydrogen bonds constructing the 3D complex structure in [Cu(terpyOH)2]·(HBTC)·2H2O (1) were observed.

KW - Copper oxide

KW - Crystal structure

KW - Degradation performance

KW - Magnetism

KW - Photocatalytic activity

UR - https://www.scopus.com/pages/publications/84884276160

U2 - 10.1016/j.jssc.2013.08.023

DO - 10.1016/j.jssc.2013.08.023

M3 - 文章

AN - SCOPUS:84884276160

SN - 0022-4596

VL - 206

SP - 251

EP - 256

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Synthesis of CuO by Cu-CPPs with the determination of Cu(II) coordination modes from a novel complex of [Cu(terpyOH)₂]·(HBTC) ·2H₂O

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Keywords

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