Synthesis of 2-(2H-Chromenyl)-Oxazoles from 2H-Chromene Hemiacetals by Using a Modified Passerini-Type Reaction

Deng Ming Huang; Hui Jing Li; Quanfu Wang; Peisheng Yan; Yan Chao Wu

doi:10.1002/slct.201802363

Synthesis of 2-(2H-Chromenyl)-Oxazoles from 2H-Chromene Hemiacetals by Using a Modified Passerini-Type Reaction

Deng Ming Huang
, Hui Jing Li^*
, Quanfu Wang
, Peisheng Yan
, Yan Chao Wu

^*Corresponding author for this work

School of Marine Science and Technology, Harbin Institute of Technology Weihai
Peking University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A modified Passerini-type reaction has been developed for the facile synthesis of 2-(2H-chromenyl)-oxazoles, in which 2H-chromene hemiacetals instead of the usually used aldehydes were adopted as the key substrates. Derivation of a 2-(2H-chromenyl)-oxazole to the respective 2H-chromene peptide and 1-(2H-chromenyl)-furan was further accomplished.

Original language	English
Pages (from-to)	9658-9662
Number of pages	5
Journal	ChemistrySelect
Volume	3
Issue number	33
DOIs	https://doi.org/10.1002/slct.201802363
State	Published - 7 Sep 2018
Externally published	Yes

Keywords

Hemiacetals
Multicomponent reactions
Oxazoles
Stannum
Synthetic methods

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10.1002/slct.201802363

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title = "Synthesis of 2-(2H-Chromenyl)-Oxazoles from 2H-Chromene Hemiacetals by Using a Modified Passerini-Type Reaction",

abstract = "A modified Passerini-type reaction has been developed for the facile synthesis of 2-(2H-chromenyl)-oxazoles, in which 2H-chromene hemiacetals instead of the usually used aldehydes were adopted as the key substrates. Derivation of a 2-(2H-chromenyl)-oxazole to the respective 2H-chromene peptide and 1-(2H-chromenyl)-furan was further accomplished.",

keywords = "Hemiacetals, Multicomponent reactions, Oxazoles, Stannum, Synthetic methods",

author = "Huang, \{Deng Ming\} and Li, \{Hui Jing\} and Quanfu Wang and Peisheng Yan and Wu, \{Yan Chao\}",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = sep,

day = "7",

doi = "10.1002/slct.201802363",

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T1 - Synthesis of 2-(2H-Chromenyl)-Oxazoles from 2H-Chromene Hemiacetals by Using a Modified Passerini-Type Reaction

AU - Huang, Deng Ming

AU - Li, Hui Jing

AU - Wang, Quanfu

AU - Yan, Peisheng

AU - Wu, Yan Chao

PY - 2018/9/7

Y1 - 2018/9/7

N2 - A modified Passerini-type reaction has been developed for the facile synthesis of 2-(2H-chromenyl)-oxazoles, in which 2H-chromene hemiacetals instead of the usually used aldehydes were adopted as the key substrates. Derivation of a 2-(2H-chromenyl)-oxazole to the respective 2H-chromene peptide and 1-(2H-chromenyl)-furan was further accomplished.

AB - A modified Passerini-type reaction has been developed for the facile synthesis of 2-(2H-chromenyl)-oxazoles, in which 2H-chromene hemiacetals instead of the usually used aldehydes were adopted as the key substrates. Derivation of a 2-(2H-chromenyl)-oxazole to the respective 2H-chromene peptide and 1-(2H-chromenyl)-furan was further accomplished.

KW - Hemiacetals

KW - Multicomponent reactions

KW - Oxazoles

KW - Stannum

KW - Synthetic methods

UR - https://www.scopus.com/pages/publications/85052963972

U2 - 10.1002/slct.201802363

DO - 10.1002/slct.201802363

M3 - 文章

AN - SCOPUS:85052963972

SN - 2365-6549

VL - 3

SP - 9658

EP - 9662

JO - ChemistrySelect

JF - ChemistrySelect

IS - 33

ER -

Synthesis of 2-(2H-Chromenyl)-Oxazoles from 2H-Chromene Hemiacetals by Using a Modified Passerini-Type Reaction

Abstract

Keywords

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