Synthesis of 1, 2, 4-triarylbutane-1, 4-diones using UV light mediated

Hongli Huang; Guolin Gao; Chao Yang; Wujiong Xia; Xiaoming Chen

doi:10.7517/j.issn.1674-0475.2015.04.265

Synthesis of 1, 2, 4-triarylbutane-1, 4-diones using UV light mediated

Hongli Huang
, Guolin Gao
, Chao Yang
, Wujiong Xia
, Xiaoming Chen^*

^*Corresponding author for this work

Harbin Institute of Technology
Wenzhou Medical University

Research output: Contribution to journal › Article › peer-review

Abstract

Benzoyl radical could be generated from photochemical cleavage reaction of benzoin, which then might add to C=C double bond of α, α-diaryl allylic alcohols followed by 1, 2-aryl migration to realize the difunctionalization of alkenes. The reaction provided an efficient approach to synthesize 1, 2, 4-triarylbutane-1, 4-diones. The procedure is highlighted by its operational simplicity and mild reaction conditions.

Original language	English
Pages (from-to)	265-274
Number of pages	10
Journal	Yingxiang Kexue yu Guanghuaxue/Imaging Science and Photochemistry
Volume	33
Issue number	4
DOIs	https://doi.org/10.7517/j.issn.1674-0475.2015.04.265
State	Published - 1 Jul 2015

Keywords

1, 2, 4-triarylbutane-1, 4-dione
1, 2-aryl migration
Difunctionalization
UV light

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10.7517/j.issn.1674-0475.2015.04.265

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title = "Synthesis of 1, 2, 4-triarylbutane-1, 4-diones using UV light mediated",

abstract = "Benzoyl radical could be generated from photochemical cleavage reaction of benzoin, which then might add to C=C double bond of α, α-diaryl allylic alcohols followed by 1, 2-aryl migration to realize the difunctionalization of alkenes. The reaction provided an efficient approach to synthesize 1, 2, 4-triarylbutane-1, 4-diones. The procedure is highlighted by its operational simplicity and mild reaction conditions.",

keywords = "1, 2, 4-triarylbutane-1, 4-dione, 1, 2-aryl migration, Difunctionalization, UV light",

author = "Hongli Huang and Guolin Gao and Chao Yang and Wujiong Xia and Xiaoming Chen",

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doi = "10.7517/j.issn.1674-0475.2015.04.265",

language = "英语",

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T1 - Synthesis of 1, 2, 4-triarylbutane-1, 4-diones using UV light mediated

AU - Huang, Hongli

AU - Gao, Guolin

AU - Yang, Chao

AU - Xia, Wujiong

AU - Chen, Xiaoming

PY - 2015/7/1

Y1 - 2015/7/1

N2 - Benzoyl radical could be generated from photochemical cleavage reaction of benzoin, which then might add to C=C double bond of α, α-diaryl allylic alcohols followed by 1, 2-aryl migration to realize the difunctionalization of alkenes. The reaction provided an efficient approach to synthesize 1, 2, 4-triarylbutane-1, 4-diones. The procedure is highlighted by its operational simplicity and mild reaction conditions.

AB - Benzoyl radical could be generated from photochemical cleavage reaction of benzoin, which then might add to C=C double bond of α, α-diaryl allylic alcohols followed by 1, 2-aryl migration to realize the difunctionalization of alkenes. The reaction provided an efficient approach to synthesize 1, 2, 4-triarylbutane-1, 4-diones. The procedure is highlighted by its operational simplicity and mild reaction conditions.

KW - 1, 2, 4-triarylbutane-1, 4-dione

KW - 1, 2-aryl migration

KW - Difunctionalization

KW - UV light

UR - https://www.scopus.com/pages/publications/84938491619

U2 - 10.7517/j.issn.1674-0475.2015.04.265

DO - 10.7517/j.issn.1674-0475.2015.04.265

M3 - 文章

AN - SCOPUS:84938491619

SN - 1674-0475

VL - 33

SP - 265

EP - 274

JO - Yingxiang Kexue yu Guanghuaxue/Imaging Science and Photochemistry

JF - Yingxiang Kexue yu Guanghuaxue/Imaging Science and Photochemistry

IS - 4

ER -

Synthesis of 1, 2, 4-triarylbutane-1, 4-diones using UV light mediated

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