Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double incomplete cubane-like clusters [(η5-C5Me5)2Mo 2(μ3-S)3SCu2X(μ-X)] 2(X = Cl-, Br-, SCN-) and cubane-like clusters [...].

Zhi Gang Ren; Hong Xi Li; Ling Ling Li; Yong Zhang; Jian Ping Lang; Jun Yi Yang; Ying Lin Song

doi:10.1016/j.jorganchem.2007.01.040

Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double incomplete cubane-like clusters [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₃SCu₂X(μ-X)] ₂(X = Cl^-, Br^-, SCN^-) and cubane-like clusters [...].

Zhi Gang Ren
, Hong Xi Li
, Ling Ling Li
, Yong Zhang
, Jian Ping Lang^*
, Jun Yi Yang
, Ying Lin Song

^*Corresponding author for this work

Soochow University
CAS - Shanghai Institute of Organic Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Reactions of trans-[(η⁵-C₅Me₅)₂Mo ₂(μ-S)₂S₂] (1) with 2 equiv. of CuX (X = Cl^-, Br^-, SCN^-, CN^-) in refluxing acetonitrile resulted in a new set of Mo/Cu/S cluster compounds [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₃SCu₂Cl(μ-Cl)] ₂ (2), [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₄(CuBr)₂] (3) and [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₃SCu₂Br(μ-Br)] ₂ (4), [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₄(CuSCN)₂] (5) and [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₃SCu₂(SCN)(μ-SCN)] ₂ (6) and [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₄(CuCN)₂] (7). Compounds 2-7 were fully characterized by elemental analysis, IR, UV-Vis, ¹H NMR and single-crystal X-ray crystallography. Compounds 2, 4 and 6 consist of two incomplete cubane-like [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₃SCu₂X] species bridged by a pair of μ-X^- anions while 3, 5 and 7 contain a cubane-like [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₄Cu₂] core with each of two terminal X^- coordinated at each copper(I) center. The third-order nonlinear optical (NLO) properties of 2-5 and 7 along with [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₄(CuCl)₂] in CH₂Cl₂ were investigated by using Z-scan technique at 532 nm. All these clusters showed strong third-order NLO absorption effects and self-defocusing properties.

Original language	English
Pages (from-to)	2205-2215
Number of pages	11
Journal	Journal of Organometallic Chemistry
Volume	692
Issue number	11
DOIs	https://doi.org/10.1016/j.jorganchem.2007.01.040
State	Published - 1 May 2007
Externally published	Yes

Keywords

Cluster
Copper
Molecular structures
Molybdenum
Sulfide
Third-order nonlinear optical properties

Access to Document

10.1016/j.jorganchem.2007.01.040

Fingerprint

Dive into the research topics of 'Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double incomplete cubane-like clusters [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₃SCu₂X(μ-X)] ₂(X = Cl^-, Br^-, SCN^-) and cubane-like clusters [...].'. Together they form a unique fingerprint.

Cite this

Ren, Z. G., Li, H. X., Li, L. L., Zhang, Y., Lang, J. P., Yang, J. Y., & Song, Y. L. (2007). Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double incomplete cubane-like clusters [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₃SCu₂X(μ-X)] ₂(X = Cl^-, Br^-, SCN^-) and cubane-like clusters [...]. Journal of Organometallic Chemistry, 692(11), 2205-2215. https://doi.org/10.1016/j.jorganchem.2007.01.040

@article{b184d6dab7744825801b149486e1206e,

title = "Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double incomplete cubane-like clusters [(η5-C5Me5)2Mo 2(μ3-S)3SCu2X(μ-X)] 2(X = Cl-, Br-, SCN-) and cubane-like clusters [...].",

abstract = "Reactions of trans-[(η5-C5Me5)2Mo 2(μ-S)2S2] (1) with 2 equiv. of CuX (X = Cl-, Br-, SCN-, CN-) in refluxing acetonitrile resulted in a new set of Mo/Cu/S cluster compounds [(η5-C5Me5)2Mo 2(μ3-S)3SCu2Cl(μ-Cl)] 2 (2), [(η5-C5Me5)2Mo 2(μ3-S)4(CuBr)2] (3) and [(η5-C5Me5)2Mo 2(μ3-S)3SCu2Br(μ-Br)] 2 (4), [(η5-C5Me5)2Mo 2(μ3-S)4(CuSCN)2] (5) and [(η5-C5Me5)2Mo 2(μ3-S)3SCu2(SCN)(μ-SCN)] 2 (6) and [(η5-C5Me5)2Mo 2(μ3-S)4(CuCN)2] (7). Compounds 2-7 were fully characterized by elemental analysis, IR, UV-Vis, 1H NMR and single-crystal X-ray crystallography. Compounds 2, 4 and 6 consist of two incomplete cubane-like [(η5-C5Me5)2Mo 2(μ3-S)3SCu2X] species bridged by a pair of μ-X- anions while 3, 5 and 7 contain a cubane-like [(η5-C5Me5)2Mo 2(μ3-S)4Cu2] core with each of two terminal X- coordinated at each copper(I) center. The third-order nonlinear optical (NLO) properties of 2-5 and 7 along with [(η5-C5Me5)2Mo 2(μ3-S)4(CuCl)2] in CH2Cl2 were investigated by using Z-scan technique at 532 nm. All these clusters showed strong third-order NLO absorption effects and self-defocusing properties.",

keywords = "Cluster, Copper, Molecular structures, Molybdenum, Sulfide, Third-order nonlinear optical properties",

author = "Ren, \{Zhi Gang\} and Li, \{Hong Xi\} and Li, \{Ling Ling\} and Yong Zhang and Lang, \{Jian Ping\} and Yang, \{Jun Yi\} and Song, \{Ying Lin\}",

year = "2007",

month = may,

day = "1",

doi = "10.1016/j.jorganchem.2007.01.040",

language = "英语",

volume = "692",

pages = "2205--2215",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "11",

}

Ren, ZG, Li, HX, Li, LL, Zhang, Y, Lang, JP, Yang, JY & Song, YL 2007, 'Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double incomplete cubane-like clusters [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₃SCu₂X(μ-X)] ₂(X = Cl^-, Br^-, SCN^-) and cubane-like clusters [...].', Journal of Organometallic Chemistry, vol. 692, no. 11, pp. 2205-2215. https://doi.org/10.1016/j.jorganchem.2007.01.040

Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double incomplete cubane-like clusters [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₃SCu₂X(μ-X)] ₂(X = Cl^-, Br^-, SCN^-) and cubane-like clusters [...]. / Ren, Zhi Gang; Li, Hong Xi; Li, Ling Ling et al.
In: Journal of Organometallic Chemistry, Vol. 692, No. 11, 01.05.2007, p. 2205-2215.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double incomplete cubane-like clusters [(η5-C5Me5)2Mo 2(μ3-S)3SCu2X(μ-X)] 2(X = Cl-, Br-, SCN-) and cubane-like clusters [...].

AU - Ren, Zhi Gang

AU - Li, Hong Xi

AU - Li, Ling Ling

AU - Zhang, Yong

AU - Lang, Jian Ping

AU - Yang, Jun Yi

AU - Song, Ying Lin

PY - 2007/5/1

Y1 - 2007/5/1

N2 - Reactions of trans-[(η5-C5Me5)2Mo 2(μ-S)2S2] (1) with 2 equiv. of CuX (X = Cl-, Br-, SCN-, CN-) in refluxing acetonitrile resulted in a new set of Mo/Cu/S cluster compounds [(η5-C5Me5)2Mo 2(μ3-S)3SCu2Cl(μ-Cl)] 2 (2), [(η5-C5Me5)2Mo 2(μ3-S)4(CuBr)2] (3) and [(η5-C5Me5)2Mo 2(μ3-S)3SCu2Br(μ-Br)] 2 (4), [(η5-C5Me5)2Mo 2(μ3-S)4(CuSCN)2] (5) and [(η5-C5Me5)2Mo 2(μ3-S)3SCu2(SCN)(μ-SCN)] 2 (6) and [(η5-C5Me5)2Mo 2(μ3-S)4(CuCN)2] (7). Compounds 2-7 were fully characterized by elemental analysis, IR, UV-Vis, 1H NMR and single-crystal X-ray crystallography. Compounds 2, 4 and 6 consist of two incomplete cubane-like [(η5-C5Me5)2Mo 2(μ3-S)3SCu2X] species bridged by a pair of μ-X- anions while 3, 5 and 7 contain a cubane-like [(η5-C5Me5)2Mo 2(μ3-S)4Cu2] core with each of two terminal X- coordinated at each copper(I) center. The third-order nonlinear optical (NLO) properties of 2-5 and 7 along with [(η5-C5Me5)2Mo 2(μ3-S)4(CuCl)2] in CH2Cl2 were investigated by using Z-scan technique at 532 nm. All these clusters showed strong third-order NLO absorption effects and self-defocusing properties.

AB - Reactions of trans-[(η5-C5Me5)2Mo 2(μ-S)2S2] (1) with 2 equiv. of CuX (X = Cl-, Br-, SCN-, CN-) in refluxing acetonitrile resulted in a new set of Mo/Cu/S cluster compounds [(η5-C5Me5)2Mo 2(μ3-S)3SCu2Cl(μ-Cl)] 2 (2), [(η5-C5Me5)2Mo 2(μ3-S)4(CuBr)2] (3) and [(η5-C5Me5)2Mo 2(μ3-S)3SCu2Br(μ-Br)] 2 (4), [(η5-C5Me5)2Mo 2(μ3-S)4(CuSCN)2] (5) and [(η5-C5Me5)2Mo 2(μ3-S)3SCu2(SCN)(μ-SCN)] 2 (6) and [(η5-C5Me5)2Mo 2(μ3-S)4(CuCN)2] (7). Compounds 2-7 were fully characterized by elemental analysis, IR, UV-Vis, 1H NMR and single-crystal X-ray crystallography. Compounds 2, 4 and 6 consist of two incomplete cubane-like [(η5-C5Me5)2Mo 2(μ3-S)3SCu2X] species bridged by a pair of μ-X- anions while 3, 5 and 7 contain a cubane-like [(η5-C5Me5)2Mo 2(μ3-S)4Cu2] core with each of two terminal X- coordinated at each copper(I) center. The third-order nonlinear optical (NLO) properties of 2-5 and 7 along with [(η5-C5Me5)2Mo 2(μ3-S)4(CuCl)2] in CH2Cl2 were investigated by using Z-scan technique at 532 nm. All these clusters showed strong third-order NLO absorption effects and self-defocusing properties.

KW - Cluster

KW - Copper

KW - Molecular structures

KW - Molybdenum

KW - Sulfide

KW - Third-order nonlinear optical properties

UR - https://www.scopus.com/pages/publications/34047262996

U2 - 10.1016/j.jorganchem.2007.01.040

DO - 10.1016/j.jorganchem.2007.01.040

M3 - 文章

AN - SCOPUS:34047262996

SN - 0022-328X

VL - 692

SP - 2205

EP - 2215

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 11

ER -

Ren ZG, Li HX, Li LL, Zhang Y, Lang JP, Yang JY et al. Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double incomplete cubane-like clusters [(η⁵-C₅Me₅)₂Mo ₂(μ₃-S)₃SCu₂X(μ-X)] ₂(X = Cl^-, Br^-, SCN^-) and cubane-like clusters [...]. Journal of Organometallic Chemistry. 2007 May 1;692(11):2205-2215. doi: 10.1016/j.jorganchem.2007.01.040