Synthesis, crystal structures, and nonlinear optical properties of two cubane-like cluster compounds [(n-Bu)4N]3[MoS 4Ag3Cl4] and [Et4N] 3[WOS3Cu3I4]

Jian Liang Zhou; Ying Lin Song; Yi Zhi Li; He Gen Zheng; Xin Quan Xin

doi:10.1002/zaac.200300393

Synthesis, crystal structures, and nonlinear optical properties of two cubane-like cluster compounds [(n-Bu)₄N]₃[MoS ₄Ag₃Cl₄] and [Et₄N] ₃[WOS₃Cu₃I₄]

Jian Liang Zhou
, Ying Lin Song
, Yi Zhi Li
, He Gen Zheng^*
, Xin Quan Xin

^*Corresponding author for this work

School of Physics

Nanjing University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The compounds [(n-Bu)₄N]₃[MoS₄Ag ₃Cl₄] (1) and [Et₄N]₃[WOS ₃Cu₃I₄] (2) were synthesized and characterized. Compound 1 crystallizes in the rhombohedral system, space group R3c with a = 17.194(1), b = 17.194(1), c = 39.194(3) Å, Z = 6, V = 10034.7(11) Å³. Compound 2 crystallizes in the rhombohedral system, space group R3c with a = 14.461(2), b = 14.461(2), c = 34.952(2) Å, Z = 6, V= 6329.9(13) Å³. The X-ray crystallographic structure determinations show that these two cluster compounds consist of a slightly distorted cubic core. Nonlinear optical (NLO) properties of these two clusters were investigated by using Z-scan techniques with an 8 ns pulsed laser at 532 nm; both clusters exhibit strong nonlinear optical absorption effect (effective α2 = 1.18 × 10^-10 m·W^-1 for 1 and 1.0× 10^-10 m·W^-1 for 2).

Original language	English
Pages (from-to)	609-612
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	630
Issue number	4
DOIs	https://doi.org/10.1002/zaac.200300393
State	Published - Apr 2004

Keywords

Cluster compounds
Crystal structure
Nonlinear optical properties

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10.1002/zaac.200300393

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@article{c3f7abbdeaff4aeaa788a6b518902470,

title = "Synthesis, crystal structures, and nonlinear optical properties of two cubane-like cluster compounds [(n-Bu)4N]3[MoS 4Ag3Cl4] and [Et4N] 3[WOS3Cu3I4]",

abstract = "The compounds [(n-Bu)4N]3[MoS4Ag 3Cl4] (1) and [Et4N]3[WOS 3Cu3I4] (2) were synthesized and characterized. Compound 1 crystallizes in the rhombohedral system, space group R3c with a = 17.194(1), b = 17.194(1), c = 39.194(3) {\AA}, Z = 6, V = 10034.7(11) {\AA}3. Compound 2 crystallizes in the rhombohedral system, space group R3c with a = 14.461(2), b = 14.461(2), c = 34.952(2) {\AA}, Z = 6, V= 6329.9(13) {\AA}3. The X-ray crystallographic structure determinations show that these two cluster compounds consist of a slightly distorted cubic core. Nonlinear optical (NLO) properties of these two clusters were investigated by using Z-scan techniques with an 8 ns pulsed laser at 532 nm; both clusters exhibit strong nonlinear optical absorption effect (effective α2 = 1.18 × 10-10 m·W-1 for 1 and 1.0× 10-10 m·W-1 for 2).",

keywords = "Cluster compounds, Crystal structure, Nonlinear optical properties",

author = "Zhou, \{Jian Liang\} and Song, \{Ying Lin\} and Li, \{Yi Zhi\} and Zheng, \{He Gen\} and Xin, \{Xin Quan\}",

year = "2004",

month = apr,

doi = "10.1002/zaac.200300393",

language = "英语",

volume = "630",

pages = "609--612",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "4",

}

TY - JOUR

T1 - Synthesis, crystal structures, and nonlinear optical properties of two cubane-like cluster compounds [(n-Bu)4N]3[MoS 4Ag3Cl4] and [Et4N] 3[WOS3Cu3I4]

AU - Zhou, Jian Liang

AU - Song, Ying Lin

AU - Li, Yi Zhi

AU - Zheng, He Gen

AU - Xin, Xin Quan

PY - 2004/4

Y1 - 2004/4

N2 - The compounds [(n-Bu)4N]3[MoS4Ag 3Cl4] (1) and [Et4N]3[WOS 3Cu3I4] (2) were synthesized and characterized. Compound 1 crystallizes in the rhombohedral system, space group R3c with a = 17.194(1), b = 17.194(1), c = 39.194(3) Å, Z = 6, V = 10034.7(11) Å3. Compound 2 crystallizes in the rhombohedral system, space group R3c with a = 14.461(2), b = 14.461(2), c = 34.952(2) Å, Z = 6, V= 6329.9(13) Å3. The X-ray crystallographic structure determinations show that these two cluster compounds consist of a slightly distorted cubic core. Nonlinear optical (NLO) properties of these two clusters were investigated by using Z-scan techniques with an 8 ns pulsed laser at 532 nm; both clusters exhibit strong nonlinear optical absorption effect (effective α2 = 1.18 × 10-10 m·W-1 for 1 and 1.0× 10-10 m·W-1 for 2).

AB - The compounds [(n-Bu)4N]3[MoS4Ag 3Cl4] (1) and [Et4N]3[WOS 3Cu3I4] (2) were synthesized and characterized. Compound 1 crystallizes in the rhombohedral system, space group R3c with a = 17.194(1), b = 17.194(1), c = 39.194(3) Å, Z = 6, V = 10034.7(11) Å3. Compound 2 crystallizes in the rhombohedral system, space group R3c with a = 14.461(2), b = 14.461(2), c = 34.952(2) Å, Z = 6, V= 6329.9(13) Å3. The X-ray crystallographic structure determinations show that these two cluster compounds consist of a slightly distorted cubic core. Nonlinear optical (NLO) properties of these two clusters were investigated by using Z-scan techniques with an 8 ns pulsed laser at 532 nm; both clusters exhibit strong nonlinear optical absorption effect (effective α2 = 1.18 × 10-10 m·W-1 for 1 and 1.0× 10-10 m·W-1 for 2).

KW - Cluster compounds

KW - Crystal structure

KW - Nonlinear optical properties

UR - https://www.scopus.com/pages/publications/4644244297

U2 - 10.1002/zaac.200300393

DO - 10.1002/zaac.200300393

M3 - 文章

AN - SCOPUS:4644244297

SN - 0044-2313

VL - 630

SP - 609

EP - 612

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 4

ER -

Synthesis, crystal structures, and nonlinear optical properties of two cubane-like cluster compounds [(n-Bu)₄N]₃[MoS ₄Ag₃Cl₄] and [Et₄N] ₃[WOS₃Cu₃I₄]

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