Synthesis, crystal structure and third-order nonlinear optical properties of a hexanuclear cluster [WOS3Cu2(4-tBuPy)2]2 (4-tBuPy = 4-tert-butylpyridine)

Bing Wu; Wen Hua Zhang; Hong Xi Li; Zhi Gang Ren; Jian Ping Lang; Yong Zhang; Ying Lin Song

doi:10.1016/j.molstruc.2006.06.016

Synthesis, crystal structure and third-order nonlinear optical properties of a hexanuclear cluster [WOS₃Cu₂(4-^tBuPy)₂]₂ (4-^tBuPy = 4-tert-butylpyridine)

Bing Wu
, Wen Hua Zhang
, Hong Xi Li
, Zhi Gang Ren
, Jian Ping Lang^*
, Yong Zhang
, Ying Lin Song

^*Corresponding author for this work

Soochow University

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Reaction of (NH₄)₂[WOS₃] with 2 equiv. of CuI in 4-tert-butylpyridine (4-^tBuPy) and methanol afforded a hexanuclear neutral cluster [WOS₃Cu₂(4-^tBuPy)₂]₂. This compound was characterized by elementary analysis, IR, UV-vis, ¹H NMR, thermogravimetric analysis, and its crystal structure was determined by X-ray single crystal diffraction. The compound contains a hexagonal prismatic cage structure in which two butterfly-shaped [WOS₃Cu₂(4-^tBuPy)₂] cluster fragments are interlinked through four Cu{single bond}S bonds. The nonlinear optical properties were studied with a 30 ps pulsed laser at 532 nm. The compound exhibited strong nonlinear absorption effect with α₂ = 2.5 × 10^-10 mW^-1, χ⁽³⁾ = 8.5 × 10^-14 esu, and γ = 4.8 × 10^-30 esu.

Original language	English
Pages (from-to)	128-134
Number of pages	7
Journal	Journal of Molecular Structure
Volume	829
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2006.06.016
State	Published - 17 Mar 2007
Externally published	Yes

Keywords

4-tert-Butylpyridine
Copper cluster
Crystal structure
Nonlinear optical properties
Synthesis
Tungsten cluster

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10.1016/j.molstruc.2006.06.016

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@article{96e20a90605f4b50a2c29ebe9506f9a7,

title = "Synthesis, crystal structure and third-order nonlinear optical properties of a hexanuclear cluster [WOS3Cu2(4-tBuPy)2]2 (4-tBuPy = 4-tert-butylpyridine)",

abstract = "Reaction of (NH4)2[WOS3] with 2 equiv. of CuI in 4-tert-butylpyridine (4-tBuPy) and methanol afforded a hexanuclear neutral cluster [WOS3Cu2(4-tBuPy)2]2. This compound was characterized by elementary analysis, IR, UV-vis, 1H NMR, thermogravimetric analysis, and its crystal structure was determined by X-ray single crystal diffraction. The compound contains a hexagonal prismatic cage structure in which two butterfly-shaped [WOS3Cu2(4-tBuPy)2] cluster fragments are interlinked through four Cu\{single bond\}S bonds. The nonlinear optical properties were studied with a 30 ps pulsed laser at 532 nm. The compound exhibited strong nonlinear absorption effect with α2 = 2.5 × 10-10 mW-1, χ(3) = 8.5 × 10-14 esu, and γ = 4.8 × 10-30 esu.",

keywords = "4-tert-Butylpyridine, Copper cluster, Crystal structure, Nonlinear optical properties, Synthesis, Tungsten cluster",

author = "Bing Wu and Zhang, \{Wen Hua\} and Li, \{Hong Xi\} and Ren, \{Zhi Gang\} and Lang, \{Jian Ping\} and Yong Zhang and Song, \{Ying Lin\}",

year = "2007",

month = mar,

day = "17",

doi = "10.1016/j.molstruc.2006.06.016",

language = "英语",

volume = "829",

pages = "128--134",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Synthesis, crystal structure and third-order nonlinear optical properties of a hexanuclear cluster [WOS3Cu2(4-tBuPy)2]2 (4-tBuPy = 4-tert-butylpyridine)

AU - Wu, Bing

AU - Zhang, Wen Hua

AU - Li, Hong Xi

AU - Ren, Zhi Gang

AU - Lang, Jian Ping

AU - Zhang, Yong

AU - Song, Ying Lin

PY - 2007/3/17

Y1 - 2007/3/17

N2 - Reaction of (NH4)2[WOS3] with 2 equiv. of CuI in 4-tert-butylpyridine (4-tBuPy) and methanol afforded a hexanuclear neutral cluster [WOS3Cu2(4-tBuPy)2]2. This compound was characterized by elementary analysis, IR, UV-vis, 1H NMR, thermogravimetric analysis, and its crystal structure was determined by X-ray single crystal diffraction. The compound contains a hexagonal prismatic cage structure in which two butterfly-shaped [WOS3Cu2(4-tBuPy)2] cluster fragments are interlinked through four Cu{single bond}S bonds. The nonlinear optical properties were studied with a 30 ps pulsed laser at 532 nm. The compound exhibited strong nonlinear absorption effect with α2 = 2.5 × 10-10 mW-1, χ(3) = 8.5 × 10-14 esu, and γ = 4.8 × 10-30 esu.

AB - Reaction of (NH4)2[WOS3] with 2 equiv. of CuI in 4-tert-butylpyridine (4-tBuPy) and methanol afforded a hexanuclear neutral cluster [WOS3Cu2(4-tBuPy)2]2. This compound was characterized by elementary analysis, IR, UV-vis, 1H NMR, thermogravimetric analysis, and its crystal structure was determined by X-ray single crystal diffraction. The compound contains a hexagonal prismatic cage structure in which two butterfly-shaped [WOS3Cu2(4-tBuPy)2] cluster fragments are interlinked through four Cu{single bond}S bonds. The nonlinear optical properties were studied with a 30 ps pulsed laser at 532 nm. The compound exhibited strong nonlinear absorption effect with α2 = 2.5 × 10-10 mW-1, χ(3) = 8.5 × 10-14 esu, and γ = 4.8 × 10-30 esu.

KW - 4-tert-Butylpyridine

KW - Copper cluster

KW - Crystal structure

KW - Nonlinear optical properties

KW - Synthesis

KW - Tungsten cluster

UR - https://www.scopus.com/pages/publications/33846846367

U2 - 10.1016/j.molstruc.2006.06.016

DO - 10.1016/j.molstruc.2006.06.016

M3 - 文章

AN - SCOPUS:33846846367

SN - 0022-2860

VL - 829

SP - 128

EP - 134

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Synthesis, crystal structure and third-order nonlinear optical properties of a hexanuclear cluster [WOS₃Cu₂(4-^tBuPy)₂]₂ (4-^tBuPy = 4-tert-butylpyridine)

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