Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate

Cai Ming Liu; De Qing Zhang; Ying Lin Song; Chuan Lang Zhan; Yu Liang Li; Dao Ben Zhu

doi:10.1002/1099-0682(200207)2002:7<1591::AID-EJIC1591>3.0.CO;2-T

Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate

Cai Ming Liu
, De Qing Zhang^*
, Ying Lin Song
, Chuan Lang Zhan
, Yu Liang Li
, Dao Ben Zhu

^*Corresponding author for this work

School of Physics

CAS - Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

The first dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate (dmit) [Zn(dmit)(2,2′-bpy)]₂ (2,2′-bpy = 2,2′-bipyridine) (1), which exhibits a good third-order nonlinear refraction effect, was synthesized by a ligand exchange reaction between [(Et₄N)₂Zn(dmit)₂] and [Cu(2,2′-bpy)(NO₃)₂]·2H₂O. A Z-scanning measurement of complex 1 gives the third-order nonlinear refraction index n₂ = 3.72 × 10^-18 m²/W and the real part ReΧ⁽³⁾ = 1.01 × 10^-12 esu. Crystal data for 1: monoclinic, P2₁/c (No.14), a = 11.556(2) Å, b = 9.141(2) Å, c = 15.020(3) Å, β = 109.55(3)°, Z = 4.

Original language	English
Pages (from-to)	1591-1594
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	7
DOIs	https://doi.org/10.1002/1099-0682(200207)2002:7<1591::AID-EJIC1591>3.0.CO;2-T
State	Published - 2002

Keywords

Crystal structure
N ligands
Nonlinear optics
S ligands
Zinc

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10.1002/1099-0682(200207)2002:7<1591::AID-EJIC1591>3.0.CO;2-T

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Liu, C. M., Zhang, D. Q., Song, Y. L., Zhan, C. L., Li, Y. L., & Zhu, D. B. (2002). Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate. European Journal of Inorganic Chemistry, (7), 1591-1594. https://doi.org/10.1002/1099-0682(200207)2002:7<1591::AID-EJIC1591>3.0.CO;2-T

@article{ffe51fe2cb6f4bfe9c3fe8f041df2a74,

title = "Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate",

abstract = "The first dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate (dmit) [Zn(dmit)(2,2′-bpy)]2 (2,2′-bpy = 2,2′-bipyridine) (1), which exhibits a good third-order nonlinear refraction effect, was synthesized by a ligand exchange reaction between [(Et4N)2Zn(dmit)2] and [Cu(2,2′-bpy)(NO3)2]·2H2O. A Z-scanning measurement of complex 1 gives the third-order nonlinear refraction index n2 = 3.72 × 10-18 m2/W and the real part ReΧ(3) = 1.01 × 10-12 esu. Crystal data for 1: monoclinic, P21/c (No.14), a = 11.556(2) {\AA}, b = 9.141(2) {\AA}, c = 15.020(3) {\AA}, β = 109.55(3)°, Z = 4.",

keywords = "Crystal structure, N ligands, Nonlinear optics, S ligands, Zinc",

author = "Liu, \{Cai Ming\} and Zhang, \{De Qing\} and Song, \{Ying Lin\} and Zhan, \{Chuan Lang\} and Li, \{Yu Liang\} and Zhu, \{Dao Ben\}",

year = "2002",

doi = "10.1002/1099-0682(200207)2002:7<1591::AID-EJIC1591>3.0.CO;2-T",

language = "英语",

pages = "1591--1594",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "7",

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TY - JOUR

T1 - Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate

AU - Liu, Cai Ming

AU - Zhang, De Qing

AU - Song, Ying Lin

AU - Zhan, Chuan Lang

AU - Li, Yu Liang

AU - Zhu, Dao Ben

PY - 2002

Y1 - 2002

N2 - The first dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate (dmit) [Zn(dmit)(2,2′-bpy)]2 (2,2′-bpy = 2,2′-bipyridine) (1), which exhibits a good third-order nonlinear refraction effect, was synthesized by a ligand exchange reaction between [(Et4N)2Zn(dmit)2] and [Cu(2,2′-bpy)(NO3)2]·2H2O. A Z-scanning measurement of complex 1 gives the third-order nonlinear refraction index n2 = 3.72 × 10-18 m2/W and the real part ReΧ(3) = 1.01 × 10-12 esu. Crystal data for 1: monoclinic, P21/c (No.14), a = 11.556(2) Å, b = 9.141(2) Å, c = 15.020(3) Å, β = 109.55(3)°, Z = 4.

AB - The first dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate (dmit) [Zn(dmit)(2,2′-bpy)]2 (2,2′-bpy = 2,2′-bipyridine) (1), which exhibits a good third-order nonlinear refraction effect, was synthesized by a ligand exchange reaction between [(Et4N)2Zn(dmit)2] and [Cu(2,2′-bpy)(NO3)2]·2H2O. A Z-scanning measurement of complex 1 gives the third-order nonlinear refraction index n2 = 3.72 × 10-18 m2/W and the real part ReΧ(3) = 1.01 × 10-12 esu. Crystal data for 1: monoclinic, P21/c (No.14), a = 11.556(2) Å, b = 9.141(2) Å, c = 15.020(3) Å, β = 109.55(3)°, Z = 4.

KW - Crystal structure

KW - N ligands

KW - Nonlinear optics

KW - S ligands

KW - Zinc

UR - https://www.scopus.com/pages/publications/0036304638

U2 - 10.1002/1099-0682(200207)2002:7<1591::AID-EJIC1591>3.0.CO;2-T

DO - 10.1002/1099-0682(200207)2002:7<1591::AID-EJIC1591>3.0.CO;2-T

M3 - 文章

AN - SCOPUS:0036304638

SN - 1434-1948

SP - 1591

EP - 1594

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 7

ER -

Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate

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