Synthesis, crystal structure and optical properties of Li 2Cu5(PO4)4

Liang Cui; Shilie Pan; Jian Han; Xiaoyu Dong; Zhongxiang Zhou

doi:10.1016/j.solidstatesciences.2011.03.026

Synthesis, crystal structure and optical properties of Li ₂Cu₅(PO₄)₄

Liang Cui
, Shilie Pan^*
, Jian Han
, Xiaoyu Dong
, Zhongxiang Zhou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The single crystals of Li₂Cu₅(PO₄) ₄ have been grown in the Li₂CO₃-H ₃BO₃ borate fluxes. Li₂Cu₅(PO ₄)₄ crystallizes in the centrosymmetric triclinic space group P-1 with a = 6.03580(10) , b = 9.2211(2) , c = 11.4138(2) , α = 75.5750(10)°, β = 80.2540(10)°, γ= 74.1590(10)°, Z = 2. The three-dimensional framework is built up of LiO₅, CuO₄, Cu/LiO₅ polyhedra and isolated PO₄ tetrahedra. The IR spectrum and UV-Vis-NIR diffuse reflectance spectrum of Li₂Cu ₅(PO₄)₄ have been studied.

Original language	English
Pages (from-to)	1304-1308
Number of pages	5
Journal	Solid State Sciences
Volume	13
Issue number	6
DOIs	https://doi.org/10.1016/j.solidstatesciences.2011.03.026
State	Published - Jun 2011
Externally published	Yes

Keywords

IR spectrum
Lithium copper phosphate
Single crystal structure
Three-dimensional framework

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10.1016/j.solidstatesciences.2011.03.026

Cite this

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title = "Synthesis, crystal structure and optical properties of Li 2Cu5(PO4)4",

abstract = "The single crystals of Li2Cu5(PO4) 4 have been grown in the Li2CO3-H 3BO3 borate fluxes. Li2Cu5(PO 4)4 crystallizes in the centrosymmetric triclinic space group P-1 with a = 6.03580(10) , b = 9.2211(2) , c = 11.4138(2) , α = 75.5750(10)°, β = 80.2540(10)°, γ= 74.1590(10)°, Z = 2. The three-dimensional framework is built up of LiO5, CuO4, Cu/LiO5 polyhedra and isolated PO4 tetrahedra. The IR spectrum and UV-Vis-NIR diffuse reflectance spectrum of Li2Cu 5(PO4)4 have been studied.",

keywords = "IR spectrum, Lithium copper phosphate, Single crystal structure, Three-dimensional framework",

author = "Liang Cui and Shilie Pan and Jian Han and Xiaoyu Dong and Zhongxiang Zhou",

year = "2011",

month = jun,

doi = "10.1016/j.solidstatesciences.2011.03.026",

language = "英语",

volume = "13",

pages = "1304--1308",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson s.r.l.",

number = "6",

}

TY - JOUR

T1 - Synthesis, crystal structure and optical properties of Li 2Cu5(PO4)4

AU - Cui, Liang

AU - Pan, Shilie

AU - Han, Jian

AU - Dong, Xiaoyu

AU - Zhou, Zhongxiang

PY - 2011/6

Y1 - 2011/6

N2 - The single crystals of Li2Cu5(PO4) 4 have been grown in the Li2CO3-H 3BO3 borate fluxes. Li2Cu5(PO 4)4 crystallizes in the centrosymmetric triclinic space group P-1 with a = 6.03580(10) , b = 9.2211(2) , c = 11.4138(2) , α = 75.5750(10)°, β = 80.2540(10)°, γ= 74.1590(10)°, Z = 2. The three-dimensional framework is built up of LiO5, CuO4, Cu/LiO5 polyhedra and isolated PO4 tetrahedra. The IR spectrum and UV-Vis-NIR diffuse reflectance spectrum of Li2Cu 5(PO4)4 have been studied.

AB - The single crystals of Li2Cu5(PO4) 4 have been grown in the Li2CO3-H 3BO3 borate fluxes. Li2Cu5(PO 4)4 crystallizes in the centrosymmetric triclinic space group P-1 with a = 6.03580(10) , b = 9.2211(2) , c = 11.4138(2) , α = 75.5750(10)°, β = 80.2540(10)°, γ= 74.1590(10)°, Z = 2. The three-dimensional framework is built up of LiO5, CuO4, Cu/LiO5 polyhedra and isolated PO4 tetrahedra. The IR spectrum and UV-Vis-NIR diffuse reflectance spectrum of Li2Cu 5(PO4)4 have been studied.

KW - IR spectrum

KW - Lithium copper phosphate

KW - Single crystal structure

KW - Three-dimensional framework

UR - https://www.scopus.com/pages/publications/79957576094

U2 - 10.1016/j.solidstatesciences.2011.03.026

DO - 10.1016/j.solidstatesciences.2011.03.026

M3 - 文章

AN - SCOPUS:79957576094

SN - 1293-2558

VL - 13

SP - 1304

EP - 1308

JO - Solid State Sciences

JF - Solid State Sciences

IS - 6

ER -

Synthesis, crystal structure and optical properties of Li ₂Cu₅(PO₄)₄

Abstract

Keywords

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