Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9

Min Zhang; Shilie Pan; Jian Han; Zhongxiang Zhou

doi:10.1016/j.jssc.2011.01.039

Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB₅O₉

Min Zhang
, Shilie Pan^*
, Jian Han
, Zhongxiang Zhou

^*Corresponding author for this work

Xinjiang Technical Institute of Physics and Chemistry
University of Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

A novel sodium lead pentaborate, NaPbB₅O₉, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB₅O₉ crystallizes in the monoclinic space group P2₁/c with a=6.5324(10) Å, b=13.0234(2) Å, c=8.5838(10) Å, β=104.971(10)°, and Z=4. The crystal structure is composed of double ring [B₅O ₉]^3- units, [PbO₇] and [NaO₇] polyhedra. [B₅O₉]^3- groups connect with each other forming two-dimensional infinite _∞[B₅O ₉]^3- layers, while [PbO₇] and [NaO₇] polyhedra are located between the layers. [PbO₇] polyhedra linked together via corner-sharing O atom forming novel infinite _∞[PbO₆] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB ₅O₉ were reported.

Original language	English
Pages (from-to)	825-829
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	184
Issue number	4
DOIs	https://doi.org/10.1016/j.jssc.2011.01.039
State	Published - Apr 2011
Externally published	Yes

Keywords

Borate
Crystal structure
NaPbBO
Synthesis

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10.1016/j.jssc.2011.01.039

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@article{6b24c28d524749af87321b7abf3b2efc,

title = "Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9",

abstract = "A novel sodium lead pentaborate, NaPbB5O9, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB5O9 crystallizes in the monoclinic space group P21/c with a=6.5324(10) {\AA}, b=13.0234(2) {\AA}, c=8.5838(10) {\AA}, β=104.971(10)°, and Z=4. The crystal structure is composed of double ring [B5O 9]3- units, [PbO7] and [NaO7] polyhedra. [B5O9]3- groups connect with each other forming two-dimensional infinite ∞[B5O 9]3- layers, while [PbO7] and [NaO7] polyhedra are located between the layers. [PbO7] polyhedra linked together via corner-sharing O atom forming novel infinite ∞[PbO6] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB 5O9 were reported.",

keywords = "Borate, Crystal structure, NaPbBO, Synthesis",

author = "Min Zhang and Shilie Pan and Jian Han and Zhongxiang Zhou",

year = "2011",

month = apr,

doi = "10.1016/j.jssc.2011.01.039",

language = "英语",

volume = "184",

pages = "825--829",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "4",

}

TY - JOUR

T1 - Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9

AU - Zhang, Min

AU - Pan, Shilie

AU - Han, Jian

AU - Zhou, Zhongxiang

PY - 2011/4

Y1 - 2011/4

N2 - A novel sodium lead pentaborate, NaPbB5O9, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB5O9 crystallizes in the monoclinic space group P21/c with a=6.5324(10) Å, b=13.0234(2) Å, c=8.5838(10) Å, β=104.971(10)°, and Z=4. The crystal structure is composed of double ring [B5O 9]3- units, [PbO7] and [NaO7] polyhedra. [B5O9]3- groups connect with each other forming two-dimensional infinite ∞[B5O 9]3- layers, while [PbO7] and [NaO7] polyhedra are located between the layers. [PbO7] polyhedra linked together via corner-sharing O atom forming novel infinite ∞[PbO6] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB 5O9 were reported.

AB - A novel sodium lead pentaborate, NaPbB5O9, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB5O9 crystallizes in the monoclinic space group P21/c with a=6.5324(10) Å, b=13.0234(2) Å, c=8.5838(10) Å, β=104.971(10)°, and Z=4. The crystal structure is composed of double ring [B5O 9]3- units, [PbO7] and [NaO7] polyhedra. [B5O9]3- groups connect with each other forming two-dimensional infinite ∞[B5O 9]3- layers, while [PbO7] and [NaO7] polyhedra are located between the layers. [PbO7] polyhedra linked together via corner-sharing O atom forming novel infinite ∞[PbO6] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB 5O9 were reported.

KW - Borate

KW - Crystal structure

KW - NaPbBO

KW - Synthesis

UR - https://www.scopus.com/pages/publications/79953669988

U2 - 10.1016/j.jssc.2011.01.039

DO - 10.1016/j.jssc.2011.01.039

M3 - 文章

AN - SCOPUS:79953669988

SN - 0022-4596

VL - 184

SP - 825

EP - 829

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 4

ER -

Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB₅O₉

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Keywords

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