Synthesis, crystal structure and optical nonlinearity study of Cu 2(μ-dppb)2(μ-Cl)2

Su Jing; Tao Yin; Yu Xiao Wang; Yin Lin Song; Yi Zhi Li; He Gen Zheng; Xin Quan Xin

Synthesis, crystal structure and optical nonlinearity study of Cu ₂(μ-dppb)₂(μ-Cl)₂

Su Jing
, Tao Yin
, Yu Xiao Wang
, Yin Lin Song
, Yi Zhi Li
, He Gen Zheng^*
, Xin Quan Xin

^*Corresponding author for this work

School of Physics

Nanjing University
Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The complex Cu₂(μ-dppb)₂(μ-Cl)₂ has been synthesized from the reaction of CuCl, dppb and (n-Bu)₄NCl. The crystal belongs to the triclinic with space group P1. The unit cell parameters are: a = 9. 939(4) Å, b = 10. 083 (6) Å, c = 14.104(5) Å, α = 76.46(3)°, β = 71.02(2)°, γ = 70.87(5)°. The single crystal X-ray diffraction analysis reveals that it has a bi-ring structure with a symmetry center at the middle of two Copper atoms. The outer ring is a 14-membered ring of Cu-dppb-Cu-dppb, and the inner ring is a 4-membered ring composed of two Cl^- and two Cu (I). Investigation of third-order optical nonlinearity shows that it exhibits considerable nonlinear absorptive and self-defocusing effect with α₂ = 1.75 × 10^-l3m · W^-1 and n₂ = 3.19 × 10^-18m² · W^-1. CCDC: 193113.

Original language	English
Pages (from-to)	1169-1172
Number of pages	4
Journal	Chinese Journal of Inorganic Chemistry
Volume	18
Issue number	11
State	Published - 2002

Keywords

Copper(I)complex
Crystal structure
Optical nonlinearity
dppb

Cite this

@article{78eec991603f40d69f533f982b572deb,

title = "Synthesis, crystal structure and optical nonlinearity study of Cu 2(μ-dppb)2(μ-Cl)2",

abstract = "The complex Cu2(μ-dppb)2(μ-Cl)2 has been synthesized from the reaction of CuCl, dppb and (n-Bu)4NCl. The crystal belongs to the triclinic with space group P1. The unit cell parameters are: a = 9. 939(4) {\AA}, b = 10. 083 (6) {\AA}, c = 14.104(5) {\AA}, α = 76.46(3)°, β = 71.02(2)°, γ = 70.87(5)°. The single crystal X-ray diffraction analysis reveals that it has a bi-ring structure with a symmetry center at the middle of two Copper atoms. The outer ring is a 14-membered ring of Cu-dppb-Cu-dppb, and the inner ring is a 4-membered ring composed of two Cl- and two Cu (I). Investigation of third-order optical nonlinearity shows that it exhibits considerable nonlinear absorptive and self-defocusing effect with α2 = 1.75 × 10-l3m · W-1 and n2 = 3.19 × 10-18m2 · W-1. CCDC: 193113.",

keywords = "Copper(I)complex, Crystal structure, Optical nonlinearity, dppb",

author = "Su Jing and Tao Yin and Wang, \{Yu Xiao\} and Song, \{Yin Lin\} and Li, \{Yi Zhi\} and Zheng, \{He Gen\} and Xin, \{Xin Quan\}",

year = "2002",

language = "英语",

volume = "18",

pages = "1169--1172",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "11",

}

TY - JOUR

T1 - Synthesis, crystal structure and optical nonlinearity study of Cu 2(μ-dppb)2(μ-Cl)2

AU - Jing, Su

AU - Yin, Tao

AU - Wang, Yu Xiao

AU - Song, Yin Lin

AU - Li, Yi Zhi

AU - Zheng, He Gen

AU - Xin, Xin Quan

PY - 2002

Y1 - 2002

N2 - The complex Cu2(μ-dppb)2(μ-Cl)2 has been synthesized from the reaction of CuCl, dppb and (n-Bu)4NCl. The crystal belongs to the triclinic with space group P1. The unit cell parameters are: a = 9. 939(4) Å, b = 10. 083 (6) Å, c = 14.104(5) Å, α = 76.46(3)°, β = 71.02(2)°, γ = 70.87(5)°. The single crystal X-ray diffraction analysis reveals that it has a bi-ring structure with a symmetry center at the middle of two Copper atoms. The outer ring is a 14-membered ring of Cu-dppb-Cu-dppb, and the inner ring is a 4-membered ring composed of two Cl- and two Cu (I). Investigation of third-order optical nonlinearity shows that it exhibits considerable nonlinear absorptive and self-defocusing effect with α2 = 1.75 × 10-l3m · W-1 and n2 = 3.19 × 10-18m2 · W-1. CCDC: 193113.

AB - The complex Cu2(μ-dppb)2(μ-Cl)2 has been synthesized from the reaction of CuCl, dppb and (n-Bu)4NCl. The crystal belongs to the triclinic with space group P1. The unit cell parameters are: a = 9. 939(4) Å, b = 10. 083 (6) Å, c = 14.104(5) Å, α = 76.46(3)°, β = 71.02(2)°, γ = 70.87(5)°. The single crystal X-ray diffraction analysis reveals that it has a bi-ring structure with a symmetry center at the middle of two Copper atoms. The outer ring is a 14-membered ring of Cu-dppb-Cu-dppb, and the inner ring is a 4-membered ring composed of two Cl- and two Cu (I). Investigation of third-order optical nonlinearity shows that it exhibits considerable nonlinear absorptive and self-defocusing effect with α2 = 1.75 × 10-l3m · W-1 and n2 = 3.19 × 10-18m2 · W-1. CCDC: 193113.

KW - Copper(I)complex

KW - Crystal structure

KW - Optical nonlinearity

KW - dppb

UR - https://www.scopus.com/pages/publications/0346388725

M3 - 文章

AN - SCOPUS:0346388725

SN - 1001-4861

VL - 18

SP - 1169

EP - 1172

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 11

ER -

Synthesis, crystal structure and optical nonlinearity study of Cu ₂(μ-dppb)₂(μ-Cl)₂

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Keywords

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