Synthesis, crystal structure, and optical limiting effect of a Cu(I) coordination polymeric cluster bridged by chiral-carbon skeleton bipyridyl ligand

Yunyin Niu; Yinglin Song; Qingli Wang; Xiaoling Guo; Yu Zhu; Hongwei Hou

doi:10.1246/cl.2006.650

Synthesis, crystal structure, and optical limiting effect of a Cu(I) coordination polymeric cluster bridged by chiral-carbon skeleton bipyridyl ligand

Yunyin Niu^*
, Yinglin Song
, Qingli Wang
, Xiaoling Guo
, Yu Zhu
, Hongwei Hou

^*Corresponding author for this work

School of Physics

Zhengzhou University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Solution reaction of Cu(I) iodide with chiral-carbon skeleton ligand 2,3-di(4-pyridyl)-2,3-butanediol (meso-dpb) in DMSO generated a novel 2D coordination polymeric cluster [(CuI)₄(dpb)₄(DMSO) ₄(CH₃OH)₄(H₂O)]_n (1), in which the dpb exhibits a TT conformation and the adaptable Cu₂I ₂ rhomboid cluster unit facilitates the formation of a final noninterpenetrating motif. The nonlinear optical limiting property of 1 was also studied at 532 nm. The limiting threshold was determined to be 0.42 J cm ^-2 and this value is three times better than 1.6 J cm^-2 of C₆₀.

Original language	English
Pages (from-to)	650-651
Number of pages	2
Journal	Chemistry Letters
Volume	35
Issue number	6
DOIs	https://doi.org/10.1246/cl.2006.650
State	Published - 5 Jun 2006

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title = "Synthesis, crystal structure, and optical limiting effect of a Cu(I) coordination polymeric cluster bridged by chiral-carbon skeleton bipyridyl ligand",

abstract = "Solution reaction of Cu(I) iodide with chiral-carbon skeleton ligand 2,3-di(4-pyridyl)-2,3-butanediol (meso-dpb) in DMSO generated a novel 2D coordination polymeric cluster [(CuI)4(dpb)4(DMSO) 4(CH3OH)4(H2O)]n (1), in which the dpb exhibits a TT conformation and the adaptable Cu2I 2 rhomboid cluster unit facilitates the formation of a final noninterpenetrating motif. The nonlinear optical limiting property of 1 was also studied at 532 nm. The limiting threshold was determined to be 0.42 J cm -2 and this value is three times better than 1.6 J cm-2 of C60.",

author = "Yunyin Niu and Yinglin Song and Qingli Wang and Xiaoling Guo and Yu Zhu and Hongwei Hou",

year = "2006",

month = jun,

day = "5",

doi = "10.1246/cl.2006.650",

language = "英语",

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journal = "Chemistry Letters",

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TY - JOUR

T1 - Synthesis, crystal structure, and optical limiting effect of a Cu(I) coordination polymeric cluster bridged by chiral-carbon skeleton bipyridyl ligand

AU - Niu, Yunyin

AU - Song, Yinglin

AU - Wang, Qingli

AU - Guo, Xiaoling

AU - Zhu, Yu

AU - Hou, Hongwei

PY - 2006/6/5

Y1 - 2006/6/5

N2 - Solution reaction of Cu(I) iodide with chiral-carbon skeleton ligand 2,3-di(4-pyridyl)-2,3-butanediol (meso-dpb) in DMSO generated a novel 2D coordination polymeric cluster [(CuI)4(dpb)4(DMSO) 4(CH3OH)4(H2O)]n (1), in which the dpb exhibits a TT conformation and the adaptable Cu2I 2 rhomboid cluster unit facilitates the formation of a final noninterpenetrating motif. The nonlinear optical limiting property of 1 was also studied at 532 nm. The limiting threshold was determined to be 0.42 J cm -2 and this value is three times better than 1.6 J cm-2 of C60.

AB - Solution reaction of Cu(I) iodide with chiral-carbon skeleton ligand 2,3-di(4-pyridyl)-2,3-butanediol (meso-dpb) in DMSO generated a novel 2D coordination polymeric cluster [(CuI)4(dpb)4(DMSO) 4(CH3OH)4(H2O)]n (1), in which the dpb exhibits a TT conformation and the adaptable Cu2I 2 rhomboid cluster unit facilitates the formation of a final noninterpenetrating motif. The nonlinear optical limiting property of 1 was also studied at 532 nm. The limiting threshold was determined to be 0.42 J cm -2 and this value is three times better than 1.6 J cm-2 of C60.

UR - https://www.scopus.com/pages/publications/33748105053

U2 - 10.1246/cl.2006.650

DO - 10.1246/cl.2006.650

M3 - 文章

AN - SCOPUS:33748105053

SN - 0366-7022

VL - 35

SP - 650

EP - 651

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

Synthesis, crystal structure, and optical limiting effect of a Cu(I) coordination polymeric cluster bridged by chiral-carbon skeleton bipyridyl ligand

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