Synthesis, crystal structure and nonlinear optical properties of cluster [WS4Ag3(PPh3)3{S 2P(OCH2Ph)2}]

Qing Chang; Yan Wang; Xiao Hua Li; Ying Lin Song; He Gen Zheng; Xin Quan Xin; S. Shanmuga Sundara Raj; Hoong Kun Fun

Synthesis, crystal structure and nonlinear optical properties of cluster [WS₄Ag₃(PPh₃)₃{S ₂P(OCH₂Ph)₂}]

Qing Chang^*
, Yan Wang
, Xiao Hua Li
, Ying Lin Song
, He Gen Zheng
, Xin Quan Xin
, S. Shanmuga Sundara Raj
, Hoong Kun Fun

^*Corresponding author for this work

School of Physics

Heilongjiang University
Nanjing University
Nanjing Xiaozhuang College
Universiti Sains Malaysia

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The cluster [WS₄Ag₃(PPh₃) ₃{S₂P(OCH₂Ph)₂}] had been synthesized from the reaction of (NH₄) ₂WS₄, Ag[S₂P(OCH₂Ph)₂] and PPh₃, and then it was characterized by IR and elemental analyses. The structure of [WS ₄Ag₃(PPh₃)₃{S₂P(OCH ₂Ph)₂}] was determined by single crystal X-ray diffraction revealing that the cluster consist of a nest-shaped core. The W atom is tetrahedrally coordinated by four S atoms. The dithiophosphate ligand adopts a triply bridging role, employing two sulfur atoms to coordinate to the three Ag atoms: one sulfur atom binds to one Ag atom, the other to the rest two. The nonlinear optical properties were studied with an 8ns pulsed laser at 532nm. Its optical responses to the incident light exhibited considerably optical absorptive and strong self-focusing effect with α₂ = 1.50 × 10^-10m · W^-1, n₂ = 2.45 × 10^-11esu. CCDC: 202239.

Original language	English
Pages (from-to)	574-578
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	19
Issue number	6
State	Published - 1 Jun 2003

Keywords

Cluster
Crystal structure
Nonlinear optics
Silver (I) complex

Cite this

@article{71d53a8e83a1476cb010b318db9c9d0c,

title = "Synthesis, crystal structure and nonlinear optical properties of cluster [WS4Ag3(PPh3)3\{S 2P(OCH2Ph)2\}]",

abstract = "The cluster [WS4Ag3(PPh3) 3\{S2P(OCH2Ph)2\}] had been synthesized from the reaction of (NH4) 2WS4, Ag[S2P(OCH2Ph)2] and PPh3, and then it was characterized by IR and elemental analyses. The structure of [WS 4Ag3(PPh3)3\{S2P(OCH 2Ph)2\}] was determined by single crystal X-ray diffraction revealing that the cluster consist of a nest-shaped core. The W atom is tetrahedrally coordinated by four S atoms. The dithiophosphate ligand adopts a triply bridging role, employing two sulfur atoms to coordinate to the three Ag atoms: one sulfur atom binds to one Ag atom, the other to the rest two. The nonlinear optical properties were studied with an 8ns pulsed laser at 532nm. Its optical responses to the incident light exhibited considerably optical absorptive and strong self-focusing effect with α2 = 1.50 × 10-10m · W-1, n2 = 2.45 × 10-11esu. CCDC: 202239.",

keywords = "Cluster, Crystal structure, Nonlinear optics, Silver (I) complex",

author = "Qing Chang and Yan Wang and Li, \{Xiao Hua\} and Song, \{Ying Lin\} and Zheng, \{He Gen\} and Xin, \{Xin Quan\} and \{Sundara Raj\}, \{S. Shanmuga\} and Fun, \{Hoong Kun\}",

year = "2003",

month = jun,

day = "1",

language = "英语",

volume = "19",

pages = "574--578",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "6",

}

TY - JOUR

T1 - Synthesis, crystal structure and nonlinear optical properties of cluster [WS4Ag3(PPh3)3{S 2P(OCH2Ph)2}]

AU - Chang, Qing

AU - Wang, Yan

AU - Li, Xiao Hua

AU - Song, Ying Lin

AU - Zheng, He Gen

AU - Xin, Xin Quan

AU - Sundara Raj, S. Shanmuga

AU - Fun, Hoong Kun

PY - 2003/6/1

Y1 - 2003/6/1

N2 - The cluster [WS4Ag3(PPh3) 3{S2P(OCH2Ph)2}] had been synthesized from the reaction of (NH4) 2WS4, Ag[S2P(OCH2Ph)2] and PPh3, and then it was characterized by IR and elemental analyses. The structure of [WS 4Ag3(PPh3)3{S2P(OCH 2Ph)2}] was determined by single crystal X-ray diffraction revealing that the cluster consist of a nest-shaped core. The W atom is tetrahedrally coordinated by four S atoms. The dithiophosphate ligand adopts a triply bridging role, employing two sulfur atoms to coordinate to the three Ag atoms: one sulfur atom binds to one Ag atom, the other to the rest two. The nonlinear optical properties were studied with an 8ns pulsed laser at 532nm. Its optical responses to the incident light exhibited considerably optical absorptive and strong self-focusing effect with α2 = 1.50 × 10-10m · W-1, n2 = 2.45 × 10-11esu. CCDC: 202239.

AB - The cluster [WS4Ag3(PPh3) 3{S2P(OCH2Ph)2}] had been synthesized from the reaction of (NH4) 2WS4, Ag[S2P(OCH2Ph)2] and PPh3, and then it was characterized by IR and elemental analyses. The structure of [WS 4Ag3(PPh3)3{S2P(OCH 2Ph)2}] was determined by single crystal X-ray diffraction revealing that the cluster consist of a nest-shaped core. The W atom is tetrahedrally coordinated by four S atoms. The dithiophosphate ligand adopts a triply bridging role, employing two sulfur atoms to coordinate to the three Ag atoms: one sulfur atom binds to one Ag atom, the other to the rest two. The nonlinear optical properties were studied with an 8ns pulsed laser at 532nm. Its optical responses to the incident light exhibited considerably optical absorptive and strong self-focusing effect with α2 = 1.50 × 10-10m · W-1, n2 = 2.45 × 10-11esu. CCDC: 202239.

KW - Cluster

KW - Crystal structure

KW - Nonlinear optics

KW - Silver (I) complex

UR - https://www.scopus.com/pages/publications/0141740602

M3 - 文章

AN - SCOPUS:0141740602

SN - 1001-4861

VL - 19

SP - 574

EP - 578

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 6

ER -

Synthesis, crystal structure and nonlinear optical properties of cluster [WS₄Ag₃(PPh₃)₃{S ₂P(OCH₂Ph)₂}]

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Keywords

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