Synthesis, crystal structure and nonlinear optical properties of cluster compound containing 2, 2′-bipyridine as ligand

Yue Hua Hu; Yu Xiao Wang; Jian Liang Zhou; Ying Lin Song; Yi Zhi Li; He Gen Zheng; Xin Quan Xin

Synthesis, crystal structure and nonlinear optical properties of cluster compound containing 2, 2′-bipyridine as ligand

Yue Hua Hu
, Yu Xiao Wang
, Jian Liang Zhou
, Ying Lin Song
, Yi Zhi Li
, He Gen Zheng^*
, Xin Quan Xin

^*Corresponding author for this work

School of Physics

Huangshan College
Nanjing University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The Cluster compound [Cu₃BrWOS₃(bipy)₂] was synthesized by reaction of (NH₄)₂WOS₃, CuBr, 2, 2′-bipyridine and n-Bu₄NBr at room temperature and characterized by IR, UV and elemental analyses. The structure of [Cu ₃BrWOS₃(bipy)₂] was determined by single crystal X-ray diffraction revealing that the cluster consist of a nest-shaped core. The W atom is tetrahedrally coordinated by three S atoms and one O atom. There are two types of copper atoms in the WOS₃Cu₃ aggregate: two copper atoms are tetrahedrally coordinated and another copper atom is trigonally coordinated. The nonlinear optical properties were studied with an 8ns pulsed laser at 532nm. Its optical responses to the incident light exhibit considerably optical absorptive and strong self-focusing effect with α₂=0.90×10^-10m·W^-1, n ₂=2.72×10^-18m²·W^-1. CCDC: 196348.

Original language	English
Pages (from-to)	215-218
Number of pages	4
Journal	Chinese Journal of Inorganic Chemistry
Volume	19
Issue number	2
State	Published - 1 Feb 2003

Keywords

Crystal structure
Nonlinear optics
Synthesis metal cluster
Z-scan

Cite this

@article{c381fdc7c11d4696848ebc92b4538b9b,

title = "Synthesis, crystal structure and nonlinear optical properties of cluster compound containing 2, 2′-bipyridine as ligand",

abstract = "The Cluster compound [Cu3BrWOS3(bipy)2] was synthesized by reaction of (NH4)2WOS3, CuBr, 2, 2′-bipyridine and n-Bu4NBr at room temperature and characterized by IR, UV and elemental analyses. The structure of [Cu 3BrWOS3(bipy)2] was determined by single crystal X-ray diffraction revealing that the cluster consist of a nest-shaped core. The W atom is tetrahedrally coordinated by three S atoms and one O atom. There are two types of copper atoms in the WOS3Cu3 aggregate: two copper atoms are tetrahedrally coordinated and another copper atom is trigonally coordinated. The nonlinear optical properties were studied with an 8ns pulsed laser at 532nm. Its optical responses to the incident light exhibit considerably optical absorptive and strong self-focusing effect with α2=0.90×10-10m·W-1, n 2=2.72×10-18m2·W-1. CCDC: 196348.",

keywords = "Crystal structure, Nonlinear optics, Synthesis metal cluster, Z-scan",

author = "Hu, \{Yue Hua\} and Wang, \{Yu Xiao\} and Zhou, \{Jian Liang\} and Song, \{Ying Lin\} and Li, \{Yi Zhi\} and Zheng, \{He Gen\} and Xin, \{Xin Quan\}",

year = "2003",

month = feb,

day = "1",

language = "英语",

volume = "19",

pages = "215--218",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "2",

}

TY - JOUR

T1 - Synthesis, crystal structure and nonlinear optical properties of cluster compound containing 2, 2′-bipyridine as ligand

AU - Hu, Yue Hua

AU - Wang, Yu Xiao

AU - Zhou, Jian Liang

AU - Song, Ying Lin

AU - Li, Yi Zhi

AU - Zheng, He Gen

AU - Xin, Xin Quan

PY - 2003/2/1

Y1 - 2003/2/1

N2 - The Cluster compound [Cu3BrWOS3(bipy)2] was synthesized by reaction of (NH4)2WOS3, CuBr, 2, 2′-bipyridine and n-Bu4NBr at room temperature and characterized by IR, UV and elemental analyses. The structure of [Cu 3BrWOS3(bipy)2] was determined by single crystal X-ray diffraction revealing that the cluster consist of a nest-shaped core. The W atom is tetrahedrally coordinated by three S atoms and one O atom. There are two types of copper atoms in the WOS3Cu3 aggregate: two copper atoms are tetrahedrally coordinated and another copper atom is trigonally coordinated. The nonlinear optical properties were studied with an 8ns pulsed laser at 532nm. Its optical responses to the incident light exhibit considerably optical absorptive and strong self-focusing effect with α2=0.90×10-10m·W-1, n 2=2.72×10-18m2·W-1. CCDC: 196348.

AB - The Cluster compound [Cu3BrWOS3(bipy)2] was synthesized by reaction of (NH4)2WOS3, CuBr, 2, 2′-bipyridine and n-Bu4NBr at room temperature and characterized by IR, UV and elemental analyses. The structure of [Cu 3BrWOS3(bipy)2] was determined by single crystal X-ray diffraction revealing that the cluster consist of a nest-shaped core. The W atom is tetrahedrally coordinated by three S atoms and one O atom. There are two types of copper atoms in the WOS3Cu3 aggregate: two copper atoms are tetrahedrally coordinated and another copper atom is trigonally coordinated. The nonlinear optical properties were studied with an 8ns pulsed laser at 532nm. Its optical responses to the incident light exhibit considerably optical absorptive and strong self-focusing effect with α2=0.90×10-10m·W-1, n 2=2.72×10-18m2·W-1. CCDC: 196348.

KW - Crystal structure

KW - Nonlinear optics

KW - Synthesis metal cluster

KW - Z-scan

UR - https://www.scopus.com/pages/publications/0141740475

M3 - 文章

AN - SCOPUS:0141740475

SN - 1001-4861

VL - 19

SP - 215

EP - 218

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 2

ER -

Synthesis, crystal structure and nonlinear optical properties of cluster compound containing 2, 2′-bipyridine as ligand

Abstract

Keywords

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